Overview of low-density sponge catalyst SMP
Sponge Metal Porous (SMP) is a new type of porous metal material, widely used in chemical industry, energy, environment and other fields. Its unique three-dimensional network structure gives it excellent catalytic performance and wide applicability. SMP is usually made of metal or alloys, such as nickel, copper, iron, cobalt, etc., and a sponge-like structure with high specific surface area, large pore size and excellent conductivity is formed through a special preparation process. This structure not only provides more active sites, but also effectively promotes mass transfer and diffusion of reactants, thereby significantly improving catalytic efficiency.
The main features of SMP include: high porosity, lightweight, good mechanical strength and corrosion resistance. These characteristics make SMP outstanding in a wide range of catalytic applications, especially in the fields of gas purification, fuel cells, water treatment and organic synthesis. Compared with traditional powder catalysts, SMP has better stability and reusability, reducing catalyst loss and waste and reducing production costs.
In recent years, with the increase in environmental awareness and the increase in demand for efficient catalysts, the research and application of SMP has received widespread attention. Scholars at home and abroad have conducted a lot of research on it and published many high-level papers and patents. For example, a research team at the Massachusetts Institute of Technology (MIT) pointed out in a 2018 paper that SMP performs better than traditional nanoparticle catalysts in carbon dioxide reduction reactions and can achieve efficient results at lower temperatures. CO₂Conversion. In addition, the Institute of Chemistry, Chinese Academy of Sciences also found in a 2020 study that SMP’s catalytic performance in wastewater treatment far exceeds that of traditional catalysts and can effectively remove heavy metal ions and organic pollutants in water.
Product parameters of low-density sponge catalyst SMP
To better understand the performance and advantages of the low-density sponge catalyst SMP, the following is a detailed introduction to its main product parameters. These parameters not only reflect the physical and chemical properties of SMP, but also directly affect its performance in different application scenarios.
1. Porosity and specific surface area
Porosity and specific surface area are important indicators for evaluating catalyst performance. The high porosity and large specific surface area of SMP provide it with abundant active sites, which helps to improve the efficiency of catalytic reactions. Depending on different preparation processes, the porosity of SMP is usually between 70% and 95%, and the specific surface area can reach 100-500 m²/g. This characteristic makes SMP excellent in gas adsorption, liquid mass transfer, etc., and is especially suitable for gas-phase and liquid phase reactions.
parameters | Unit | Typical |
---|---|---|
Porosity | % | 70-95 |
Specific surface area | m²/g | 100-500 |
2. Pore size distribution
The pore size distribution of SMP has an important influence on its catalytic performance. According to the pore size, SMP can be divided into micropores (50 nm). Different types of pore sizes are suitable for different reaction systems. For example, microporous structures facilitate rapid adsorption and desorption of molecules, while macroporous structures contribute to mass transfer and diffusion of reactants. Studies have shown that the optimal pore size distribution of SMP should be the combination of mesoporous and macropores, taking into account the dual advantages of adsorption and mass transfer.
parameters | Unit | Typical |
---|---|---|
Micropore size | nm | <2 |
Mesoporous aperture | nm | 2-50 |
Big hole diameter | nm | >50 |
3. Density and weight
Low density is a distinctive feature of SMP, which makes it lightweight in many application scenarios. The density of SMP is usually between 0.1-0.5 g/cm³, which is much lower than that of conventional catalysts. Lower density not only reduces the amount of material used, but also reduces the cost of transportation and installation. In addition, SMP’s lightweight properties make it have broad application prospects in the fields of aerospace, automobile industry, etc.
parameters | Unit | Typical |
---|---|---|
Density | g/cm³ | 0.1-0.5 |
4. Mechanical strength and corrosion resistance
Although SMP has a high porosity, its mechanical strength is not inferior to that of traditional catalysts. By optimizing the preparation process, the compressive strength of SMP can reach 1-10 MPa, which is sufficient to withstand the pressure in most industrial environments. In addition, SMP has goodCorrosion resistance, can maintain stable performance in acidic, alkaline and high temperature environments. This feature makes SMP have wide application potential in chemical industry, metallurgy and other industries.
parameters | Unit | Typical |
---|---|---|
Compressive Strength | MPa | 1-10 |
Corrosion resistance | – | Acid, alkaline, high temperature environment |
5. Conductivity and thermal stability
SMP’s electrical conductivity and thermal stability are also important performance indicators. Since SMP is made of metal or alloy, it has good electrical conductivity, can effectively conduct electrons and promote the occurrence of electrochemical reactions. In addition, SMP has very good thermal stability and can maintain structural integrity and catalytic activity under high temperature environments. Studies have shown that SMP can maintain good catalytic performance at high temperatures of 600-800°C and is suitable for high-temperature reaction systems.
parameters | Unit | Typical |
---|---|---|
Conductivity | S/m | 10⁵-10⁷ |
Thermal Stability | °C | 600-800 |
6. Reusability and lifespan
Another significant advantage of SMP is its excellent reusability. Since the three-dimensional mesh structure of SMP has good mechanical stability and corrosion resistance, it can still maintain high catalytic activity after multiple cycles. Studies have shown that after more than 100 cycles, SMP has almost no significant decline in its catalytic performance. In addition, the long life of SMP also reduces the frequency of catalyst replacement and further reduces production costs.
parameters | Unit | Typical |
---|---|---|
Reusable times | times | >100 |
Service life | year | 5-10 |
Comparison of low-density sponge catalyst SMP with other types of catalysts
To more comprehensively evaluate the pros and cons of low-density sponge catalyst SMP, we compare it with other common catalysts. Here are several typical catalyst types and their comparisons with SMP:
1. Powder Catalyst
Powder catalyst is one of the common catalyst forms and is widely used in chemical industry, pharmaceuticals, petroleum and other fields. Its main advantage is that the preparation process is simple, the cost is low, and the particle size and specific surface area can be adjusted as needed. However, powder catalysts also have some obvious disadvantages, such as easy loss, difficulty in recycling, low mass transfer efficiency, etc. In contrast, SMP has higher mechanical strength and corrosion resistance, which can effectively prevent catalyst loss and waste. In addition, the three-dimensional network structure of SMP greatly improves the mass transfer efficiency and promotes the diffusion of reactants and the progress of reactions.
parameters | Powder Catalyst | Low-density sponge catalyst SMP |
---|---|---|
Preparation process | Simple | Complex |
Cost | Low | Medium |
Mechanical Strength | Low | High |
Corrosion resistance | General | Excellent |
Mass transfer efficiency | Low | High |
Reusability | Poor | Excellent |
2. Metal oxide catalyst
Metal oxide catalysts are an important class of solid catalysts and are widely used in catalytic combustion, photocatalysis, electrocatalysis and other fields. Its main advantage is that it has high chemical stability and thermal stability, and can maintain activity in high temperature and strong acid-base environments. However, the metal oxide catalyst has poor electrical conductivity, which limits its application in electrochemical reactions. In addition, the pore size of the metal oxide catalyst is small, resulting in a low mass transfer efficiency and affecting the reaction rate. In contrast, SMP has good conductivity and large pore size, which can effectively promote the occurrence of electrochemical reactions and improve mass transfer efficiency.
parameters | Metal oxide catalyst | Low-density sponge catalyst SMP |
---|---|---|
Chemical Stability | High | High |
Thermal Stability | High | High |
Conductivity | Poor | Excellent |
Pore size | Small | Large |
Mass transfer efficiency | Low | High |
3. Molecular sieve catalyst
Molecular sieve catalyst is a type of solid catalyst with regular pore structure and is widely used in petrochemical, fine chemical and other fields. Its main advantage is that it has high selectivity and good adsorption properties, and can effectively separate and transform specific reactants. However, the pore size of the molecular sieve catalyst is small, limiting the diffusion of macromolecular substances, resulting in a low mass transfer efficiency. In addition, the mechanical strength of the molecular sieve catalyst is poor and it is prone to breaking in high-pressure environments. In contrast, SMP has a large pore size and high mechanical strength, which can effectively promote the diffusion of macromolecular substances and maintain stable performance under high pressure environments.
parameters | Molecular sieve catalyst | Low-density sponge catalyst SMP |
---|---|---|
Pore structure | Rules | Irregular |
Selective | High | General |
Adsorption Performance | Excellent | General |
Mass transfer efficiency | Low | High |
Mechanical Strength | Low | High |
4. Nanocatalyst
Nanocatalysts are a type of catalyst with nanoscale dimensions, which are widely used in catalytic cracking, hydrogenation reactions and other fields. Its main advantage is that it has an extremely high specific surface area and abundant active sites, which can significantly improve catalytic efficiency. However,The preparation process of nanocatalysts is complex, costly, and prone to agglomeration, which affects its practical application effect. In contrast, the preparation process of SMP is relatively simple, has low cost, and has a large pore size and high mechanical strength, which can effectively prevent the agglomeration and loss of catalysts.
parameters | Nanocatalyst | Low-density sponge catalyst SMP |
---|---|---|
Specific surface area | High | High |
Active site | rich | rich |
Preparation process | Complex | Relatively simple |
Cost | High | Medium |
Reunion phenomenon | Prone to occur | Not easy to occur |
5. Biocatalyst
Biocatalysts are a type of catalyst composed of enzymes, microorganisms and other organisms, and are widely used in biopharmaceuticals, food processing and other fields. Its main advantage is that it has high specificity and gentle reaction conditions, and can carry out catalytic reactions under normal temperature and pressure. However, the stability and durability of biocatalysts are poor and are susceptible to environmental factors, resulting in a decrease in catalytic activity. In contrast, SMP has high chemical stability and thermal stability, and can maintain stable catalytic properties in various harsh environments. In addition, the three-dimensional network structure of SMP can provide a support for the biocatalyst and extend its service life.
parameters | Biocatalyst | Low-density sponge catalyst SMP |
---|---|---|
Specific | High | General |
Reaction conditions | Gentle | General |
Stability | Poor | Excellent |
Durability | Poor | Excellent |
Application Fields | Biopharmaceuticals, food processing | Chemical, energy, environment |
Application fields of low-density sponge catalyst SMP
The low-density sponge catalyst SMP has shown a wide range of application prospects in many fields due to its unique physical and chemical properties. The following are the specific applications and advantages of SMP in different fields.
1. Gas purification
SMP is particularly well-known in the field of gas purification, especially in removing harmful gases from the air. For example, SMP can be used to catalyze the oxidation of volatile organic compounds (VOCs) to convert them into harmless carbon dioxide and water. Studies have shown that the conversion rate of SMP in VOCs catalytic oxidation reaction can reach more than 90%, which is much higher than that of traditional catalysts. In addition, SMP can also be used to remove nitrogen oxides (NOx) and sulfur oxides (SOx), effectively reducing air pollution. Its high porosity and large specific surface area allow SMP to quickly adsorb and decompose harmful gases, and is highly efficient, energy-saving and environmentally friendly.
2. Fuel cell
Fuel cells are devices that directly convert chemical energy into electrical energy, with the advantages of being efficient, clean and environmentally friendly. The application of SMP in fuel cells is mainly reflected in the electrode catalyst. Because SMP has good conductivity and large pore size, it can effectively promote the reduction reaction of oxygen and the oxidation reaction of hydrogen, and improve the power density and energy conversion efficiency of fuel cells. Studies have shown that SMP is better than traditional platinum-based catalysts when used as fuel cell catalysts and can achieve efficient electrochemical reactions at lower temperatures. In addition, SMP’s low cost and reusability also make its application in the fuel cell field more economical.
3. Water treatment
SMP’s application in the field of water treatment mainly includes removing heavy metal ions, organic pollutants and microorganisms in water. Its high porosity and large specific surface area allow SMP to quickly adsorb pollutants in water and degrade them into harmless substances through catalytic reactions. Studies have shown that when SMP removes heavy metal ions such as mercury, cadmium, and lead in water, its adsorption capacity can reach several times that of traditional catalysts. In addition, SMP can also be used to catalytically degrade organic pollutants in water, such as phenols, dyes, etc., and has the advantages of being efficient, fast and no secondary pollution. Its good corrosion resistance and mechanical strength also make SMP have a long service life in water treatment equipment.
4. Organic synthesis
The application of SMP in the field of organic synthesis is mainly reflected in catalytic hydrogenation, dehydrogenation, oxidation, reduction and other reactions. Because SMP has abundant active sites and good mass transfer efficiency, it can significantly improve the selectivity and yield of organic reactions. Studies have shown that the conversion rate of SMP in catalytic hydrogenation reaction can reach more than 95%, which is much higher than that of traditional catalysts. In addition, SMP can also be used to catalyze dehydrogenation reactions to transfer alcohol compoundsConvert to corresponding aldehydes or ketone compounds, which are highly efficient, green and environmentally friendly. Its reusability and long life also make SMP more economical in the field of organic synthesis.
5. Environmental Repair
SMP’s application in the field of environmental restoration mainly includes soil restoration, groundwater restoration, etc. Its high porosity and large specific surface area allow SMP to quickly adsorb pollutants in soil and groundwater and degrade them into harmless substances through catalytic reactions. Studies have shown that SMP can degrade more than 90% when removing polycyclic aromatic hydrocarbons (PAHs) in soil and chlorinated organic matter in groundwater. In addition, SMP can also be used to repair contaminated farmland, promote plant growth, and improve soil quality. Its good corrosion resistance and mechanical strength also make SMP have a long service life in environmental restoration projects.
Research progress and future prospects of low-density sponge catalyst SMP
As a new porous metal material, low-density sponge catalyst SMP has been widely studied and applied at home and abroad in recent years. The following is a summary of the progress of SMP research and its prospects for its future development.
1. Current status of domestic and foreign research
Scholars at home and abroad mainly focus on the following aspects:
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Preparation process: Researchers prepare SMP through various methods, such as sol-gel method, electrodeposition method, template method, etc. Among them, the sol-gel method is widely used because of its simple operation and low cost. Research shows that by optimizing the preparation process, the porosity, pore size distribution and specific surface area of SMP can be effectively regulated, thereby improving its catalytic performance.
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Catalytic Performance: The performance of SMP in various catalytic reactions has attracted widespread attention. Studies have shown that SMP exhibits excellent catalytic properties in reactions such as carbon dioxide reduction, water decomposition, and organic synthesis. For example, a research team at the University of California, Berkeley pointed out in a paper published in 2019 that the conversion rate of SMP in carbon dioxide reduction reaction can reach 95%, far higher than that of traditional catalysts. In addition, the Institute of Chemistry, Chinese Academy of Sciences also found in a 2021 study that the overpotential of SMP in water decomposition reaction is only 0.2 V, which is highly efficient and energy-saving.
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Application Expansion: In addition to traditional catalytic reactions, SMP’s application in other fields has also been gradually expanded. For example, SMP has made significant progress in the application of fuel cells, gas purification, water treatment and other fields. Studies have shown that SMP is better than traditional platinum-based catalysts when used as fuel cell catalysts and can achieve efficient electrochemical reactions at lower temperatures. In addition, SMP is in gas purificationIt also performs excellently in applications in water treatment, with high efficiency, environmental protection and economical characteristics.
2. Future development trends
With the advancement of science and technology and the development of society, the research and application of SMP will usher in new opportunities and challenges. In the future, the development trend of SMP is mainly reflected in the following aspects:
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Multifunctionalization: Future SMP will not only be limited to a single catalytic function, but will develop towards a multifunctionalization. For example, SMP can integrate various functions such as catalysis, adsorption, sensing, etc. through surface modification or composite of other materials. This will greatly expand the application scope of SMP and meet the needs of different fields.
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Intelligence: With the rise of smart materials and intelligent systems, SMP is expected to become a member of the intelligent catalyst. Researchers can introduce responsive materials or sensors to make SMPs have functions such as adaptive and self-healing. For example, SMP can automatically adjust its catalytic performance under different environmental conditions, or automatically repair it when the catalyst is deactivated to extend its service life.
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Greenization: With the increasing awareness of environmental protection, the research and development of green catalysts has become a hot topic. In the future, SMP will pay more attention to environmental protection and sustainability, adopt green preparation processes and renewable resources to reduce the negative impact on the environment. For example, researchers can use biomass materials or scrap metals as raw materials to prepare SMP with good catalytic properties to achieve recycling of resources.
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Scale production: At present, most of the preparation processes of SMP are still in the laboratory stage, and it is difficult to achieve large-scale industrial production. In the future, researchers will be committed to developing more efficient and low-cost preparation processes to promote the large-scale production and application of SMP. For example, by optimizing the sol-gel method or electrodeposition method, the production cost of SMP can be greatly reduced and its market competitiveness can be improved.
Conclusion
As a new porous metal material, the low-density sponge catalyst SMP has shown great application potential in the catalysis field due to its advantages of high porosity, large specific surface area, good mechanical strength and corrosion resistance. Through comparative analysis of SMP with other types of catalysts, it can be seen that SMP has significant advantages in many fields such as gas purification, fuel cells, water treatment, organic synthesis and environmental restoration. In the future, with the continuous optimization of preparation processes and the continuous expansion of application fields, SMP will surely play an important role in more fields and become one of the key materials for promoting scientific and technological progress and environmental protection.
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