What is the difference between hydroxylamine and hydroxyethylamine?

Hydroxylamine and Hydroxyethylamine are two compounds that differ in chemical properties and uses.

Hydroxyethylamine is an inorganic substance with the chemical formula H3NO or NH2OH and is a colourless crystalline compound. It is extremely hygroscopic and highly soluble in water, but decomposes in hot water. Hydroxylamine is also slightly soluble in ether, benzene, carbon disulphide and chloroform. It is unstable and decomposes rapidly at room temperature on absorption of water vapour and carbon dioxide and may explode violently on heating. Hydroxylamine is used as a reducing agent in organic synthesis and has a wide range of applications.

And hydroxyethylamine, also known as 2-hydroxyethylamine, 2-aminoethanol, ethanolamine, etc., is a kind of organic amine chemical products. It is a colourless viscous liquid with ammonia odour and strong alkaline and hygroscopicity at room temperature and pressure. Hydroxyethylamine is miscible with water, methanol, ethanol, acetone and so on, but slightly soluble in benzene, ether and carbon tetrachloride. In addition, hydroxyethylamine is flammable and has the risk of burning when exposed to open flame and high temperature, its vapour is toxic and irritating to eyes and nose, contact with the liquid may lead to eye damage, skin contact may cause stinging and burns, and when taken orally, it may damage the oral cavity and the gastrointestinal tract. Hydroxyethylamine is common in phospholipids and often co-exists with choline, hence the name cholamine, and is widely used for organic synthetic raw materials and solvent purposes.

In summary, there are significant differences between hydroxylamine and hydroxyethylamine in terms of chemical structure, physical properties, stability, toxicity, and uses. Hydroxylamine is mainly used as a reducing agent in organic synthesis, while hydroxyethylamine is mainly used as an organic synthetic raw material and solvent. Special attention needs to be paid to the safety and potential hazards of both compounds when they are used.

Recommended Related Reading:

Dabco NE1060/Non-emissive polyurethane catalyst

Non-emissive polyurethane catalyst/Dabco NE1060 catalyst

DMAPA

2-(2-Aminoethoxy)ethanol

Morpholine

TEDA

Jeffcat ZF-22

BDMAEE Exporter

N-Methylmorpholine

4-Formylmorpholine

Complete Collection of Polyurethane Catalyst Products

Can be used alone or in combination with other catalysts.
POLYCAT58 PC58 has a low odor and a surface curing catalyst.
POLYCAT77 PC77 balanced reaction catalyst, excellent opening and surface curing effect, can enhance the resilience of molded foam.
POLYCAT92 PC92 special serotonin, which prolongs milk white and reduces sponge rupture loss, is suitable for low to high density formulas, especially suitable for slow rebound.
Product Number Company Product Number Product Introduction for Other Countries
C-225 C-225 delayed hair blowing and cross-linking balance, improving fluidity.
PC CAT DBU DBU 1,8 diazabicyclo [5,4,0] undecen-7, strong gel catalyst.
SMP SMP composite tertiary amine, increase the hardness of foam
AS-33 AS-33 modified triethylenediamine, delayed catalyst, molded, box, soft foam
PCCAT NP15 Np15 bis – (3-dimethylaminopropyl) amino-2-propanolamine, low odor, high rebound
DMBA Dimethylbenzylamine
ZF-1 low atomization, foaming catalyst, can replace A-1
TMEDA Tetramethylethylenediamine Assisted Catalyst
TMPTA Tetramethylpropanediamine Assisted Catalyst
L-33 low atomization, gel type catalyst, performance can replace A-33
NMM N-methylmorpholine, polyurethane fast foam, open cell
DMP 1,4-dimethylpiperazine, self skinning
Metal catalysts
DABCO K-15 K-15 70% potassium octanoate in diethylene glycol solution, standard PIR catalyst.
DABCO T9 T9 100% stannous octanoate, an industrial standard tin catalyst.
DABCO T12 T12 Dibutyltin dilaurate, suitable for coatings or PU resins.
The DABCO 120 120 tetravalent tin catalyst reacts faster and more stably than T-12.
Related reading recommendations:

NT CAT A-33

NT CAT A-1

NT CAT 33L

NC CAT T

NT CAT 33LV

Dabco 33-S/Microporous catalyst

Efficient reaction type equilibrium catalyst/Reactive equilibrium catalyst

Dabco amine catalyst/Low density sponge catalyst

High efficiency amine catalyst/Dabco amine catalyst

Non-emissive polyurethane catalyst/Dabco NE1060 catalyst

A Brief Analysis of Catalysts for Polyurethane Raw Materials

During the preparation of polyurethane foam, the role of catalyst is mainly to adjust the speed of foaming reaction and gel reaction to keep them in good balance.
1、 Amine catalysts
Triethylenediamine is the most important tertiary amine catalyst in soft foam production, with 60% efficacy in promoting the reaction between isocyanates and water, i.e. foaming reaction. The 40% effect is used to promote the reaction of hydroxyl and isocyanate, that is, gel reaction. The width of triethylenediamine to organotin is narrow, but it can promote the late maturing of foam, and is an indispensable catalyst for all soft foams.
Bis (2-dimethylaminoethyl) ether (A-1) has been recommended as a versatile tertiary amine catalyst for soft foam. It has 80% efficacy to promote foaming reaction, 20% efficacy to promote gel reaction, widening the adjustable range of organotin catalyst, and improving the qualification rate of products. Currently, it is mostly used in combination with triethylenediamine.
Influence of improper dosage of amine catalyst on foam
1. Excessive amine will cause
(1) Short reaction time, rapid increase in initial viscosity, and excessive smoking during foaming
(2) Cracking of foam
2. The amount of amine used is too low
(1) The initial foaming speed is too slow.
(2) Affects foaming height.
2、 Tin based catalysts
Stannous octanoate is the most commonly used organic tin catalyst for general-purpose block polyether soft foams. It is highly susceptible to hydrolysis and oxidation in polyether mixtures containing water and tertiary amines.
The adjustable range of tin octoate dosage is wide. The lower the foam density is, the narrower the adjustable range is. The influence of tin dosage is as follows:
Too little: foam cracks
Too much dosage: the viscosity increases quickly, and the foam forms closed pores and shrinks, forming bottom skin and edge skin.
The impact of formula changes on the demand for stannous octanoate can be summarized as follows:
Formula change factor tin octanoate requirement
Reduce water volume
Increase physical foaming agent
Reduce isocyanate index and increase
In actual production, the balance state of foaming reaction and gel reaction is generally adjusted by changing the amount of stannous octoate rather than the amount of amine catalyst.
According to data reports, when producing polyether type blocky soft foam, the relationship between the amount of stannous octoate and the density of foam is as follows:
Where d is the density of foam (kg/m3)
The limiting conditions of this formula are as follows:
(1) Formula dosage based on 100 parts of polyether
(2) When d ≥ 20kg/m3, the TDI index is 1.06
When d<20kg/m3, the TDI index is 1.10
The index should be between 1.03 and 1.15. If the index is increased, its usage will decrease by about one thousandth of the index increase
(3) If the amount of MC is increased, the increase in stannous octanoate is about two thousandths of MC.
Reference dosage of stannous octanoate at various densities:
Density (kg/m3) Amount of stannous octanoate (by weight)
12 0.34
16 0.27
20 0.23
26 0.21
30 0.2
35 0.19
46 0.17
Related reading recommendations:
High efficiency amine catalyst/Dabco amine catalyst
Non-emissive polyurethane catalyst/Dabco NE1060 catalyst
Dabco NE1060/Non-emissive polyurethane catalyst
TMPEDA
TEDA
Morpholine
2-(2-Aminoethoxy)ethanol
DMAPA
High Quality 3164-85-0 / K-15 Catalyst / Potassium Isooctanoate
High Quality Bismuth Octoate / 67874-71-9 / Bismuth 2-Ethylhexanoate
Bismuth 2-Ethylhexanoate
Bismuth Octoate

Unleashing the Power of Coating Catalysts: A Revolution in Surface Protection and Enhancement

Discover how coating catalysts are transforming industries by providing superior surface protection and unparalleled performance benefits.
Introduction
Coating catalysts have emerged as a game-changer in the world of surface protection and enhancement. These innovative materials are revolutionizing various industries, including automotive, aerospace, marine, and electronics, by offering exceptional performance benefits. This article delves into the fascinating world of coating catalysts, exploring their functions, applications, and the cutting-edge advancements that are shaping their future.
Understanding Coating Catalysts
Coating catalysts are specialized substances that initiate or accelerate a chemical reaction in a coating system without being consumed in the process. They play a crucial role in enhancing the properties of coatings, such as corrosion resistance, scratch resistance, hardness, and adhesion. By facilitating the cross-linking of polymers, coating catalysts create a dense and robust network that significantly improves the overall performance of the coating.
Applications of Coating Catalysts
The versatility of coating catalysts has led to their widespread adoption across various industries. Some of the most prominent applications include:
Automotive: Coating catalysts are extensively used in automotive coatings to provide superior protection against corrosion, scratches, and UV radiation. They also contribute to the glossy and aesthetically pleasing appearance of vehicles.
Aerospace: In the aerospace industry, coating catalysts are employed to enhance the durability and resistance of aircraft surfaces to extreme environmental conditions, such as high temperatures, humidity, and chemical exposure.
Marine: The marine sector benefits from coating catalysts in the form of anti-fouling and anti-corrosion coatings, which protect ships and offshore structures from the damaging effects of seawater and marine organisms.
Electronics: Coating catalysts are used in the electronics industry to create conformal coatings that safeguard circuit boards and other electronic components from moisture, dust, and chemical contaminants.
Advancements in Coating Catalysts Technology
The field of coating catalysts is continually evolving, with researchers and manufacturers constantly seeking to develop new and improved materials. Some of the latest advancements in coating catalysts technology include:
Nanotechnology: The integration of nanotechnology in coating catalysts has led to the creation of advanced materials with enhanced properties, such as self-cleaning, self-healing, and anti-microbial functions.
Eco-friendly Catalysts: In response to growing environmental concerns, the development of eco-friendly coating catalysts has gained momentum. These materials are designed to reduce volatile organic compound (VOC) emissions and minimize waste generation during the coating process.
Smart Coatings: Smart coatings, also known as responsive coatings, are a new generation of coating systems that can change their properties in response to external stimuli, such as temperature, light, or pH. Coating catalysts play a crucial role in the development of these intelligent materials.
The Future of Coating Catalysts
As the demand for high-performance, durable, and eco-friendly coatings continues to grow, the market for coating catalysts is expected to expand significantly. According to a recent study, the global coating catalysts market is projected to reach USD 6.5 billion by 2026, growing at a CAGR of 5.2% during the forecast period.
The future of coating catalysts lies in the development of advanced materials that can address the evolving needs of various industries. Researchers are focusing on creating multifunctional catalysts that can provide multiple performance benefits simultaneously, such as corrosion resistance, self-healing, and anti-microbial properties. Additionally, the development of sustainable and eco-friendly coating catalysts will continue to be a priority, as the world moves towards a greener and more environmentally conscious future.
Conclusion
Coating catalysts have undeniably transformed the landscape of surface protection and enhancement, offering unparalleled performance benefits and opening up new possibilities for various industries. As advancements in technology continue to shape the future of coating catalysts, we can expect to see even more innovative and sustainable solutions that will further revolutionize the way we protect and enhance surfaces. With their unique properties and wide-ranging applications, coating catalysts are truly a testament to the power of human ingenuity and the relentless pursuit of progress.
Recommended Reading：
NT CAT DMDEE
NT CAT PC-5
NT CAT DMP-30
NT CAT DMEA
NT CAT BDMA
NT CAT PC-9
NT CAT ZR-50
NT CAT TMR-2
NT CAT PC-77
NT CAT PC-41

What are the ingredients contained in the varnish `hardener` thinner?

Diluent is based on Cyclohexanone. Butyl acetate. Anhydrous xylene is a mixture of organic solvents.
Curing agents, also known as hardeners, curing agents or modifiers, are a class of substances or mixtures that enhance or control the curing reaction.
Resin curing is the process of irreversible changes in thermosetting resins through chemical reactions such as condensation, ring closure, addition or catalysis, and curing is accomplished by the addition of curing (cross-linking) agents.
Classification of epoxy resin curing agents
(1) Alkaline and acidic curing agents:
(1) alkaline curing agents, including aliphatic diamines and polyamines, aromatic polyamines, other nitrogen compounds and modified fatty amines.
② acidic curing agents, including organic acids, anhydrides, and boron trifluoride and its complexes.
(2) Forming and catalytic curing agents:
This kind of curing agent and epoxy group undergoes addition reaction to form part of the chain segment of the curing product, and makes the linear molecule crosslinked into the body structure molecule through gradual polymerisation reaction, and this kind of curing agent is also known as melon-type curing agent. Such as primary amines, polythiols, polyphenols, low molecular polyamides, organic acids and anhydrides and low condensate curing agent.
② catalytic curing agent This type of curing agent only on the epoxy resin to trigger the role of opening the epoxy group, catalytic epoxy resin itself polymerisation into a network structure, the generation of ether bond as the main structure of the homopolymer, and the curing agent itself does not produce crosslinking reaction. Such as tertiary amine, imidazole, dicyandiamine, boron trifluoride complex, stannous chloride, stannous isooctanoate and stannous octanoate.

Common epoxy resin curing agent introduction:
Epoxy resin curing material has excellent mechanical properties, electrical properties, chemical resistance, and therefore widely used. Curing agent is one of the necessary raw materials for epoxy resin curing material, otherwise the epoxy resin will not be cured. In order to meet the requirements of various applications, the corresponding curing agent should be used. There are many types of curing agents, which are introduced below:
Fatty polyamines
Ethylenediamine
EDA H2NCH2CH2NH2 Molecular Weight 60 Active Hydrogen Equivalent 15 Colourless Liquid 6-8 parts per 100 parts of Standard Resin
Properties: toxic, aggressive odour, high volatility, low viscosity, fast curing at room temperature. Used for bonding, casting and coating. This kind of amine increases with molecular weight, viscosity increases, volatility decreases, toxicity decreases and performance improves. However, they have high heat release and short application period. Generally speaking, the higher molecular weight they have, the less they are affected by the amount of coordination. Prolonged exposure to fatty polyamines can cause dermatitis, and their vapour toxicity is very strong, so they should be operated with great care.
Diethylenetriamine
DETA H2NC2H4NHC2H4NH2 Molecular Weight 103 Active Hydrogen Equivalent 20.6 Colourless Liquid
Use 8-11 parts per 100 parts of standard resin. Curing: 2 hours at 20°C + 30 minutes at 100°C or 4 days at 20°C. Properties: Applicable period 50g 25°C for 45 minutes, heat distortion temperature 95-124°C, flexural strength 1000-1160kg/cm2, compressive strength 1120kg/cm2, tensile strength 780kg/cm2, elongation 5.5%, impact strength
0.4 ft-lb/in Rockwell hardness 99-108. dielectric constant (50 Hz, 23°C) 4.1 power factor (50 Hz, 23°C) 0.009 bulk resistance 2×1016
Ω-cm Curing at room temperature, high toxicity, high heat release, short application period.
Triethylenetetramine TETA H2NC2H4NHC2H4NHC2H4NH2
Molecular weight 146 Active hydrogen equivalent 24.3 Colourless viscous liquid 10-13 parts per 100 parts of standard resin
Curing: 2 hours at 20°C + 30 minutes at 100°C or 7 days at 20°C. Properties: Applicable period 50g 25℃45 minutes, heat distortion temperature 98-124℃, flexural strength 950-1200kg/cm2, compressive strength 1100kg/cm2, tensile strength 780kg/cm2, elongation 4.4%, impact strength
0.4 ft-lb/in Rockwell hardness 99-106, room temperature curing, toxicity is slightly lower than diethylenetriamine, heat release, short application period.
Tetraethylenepentamine TEPA
H2NC2H4(NHC2H4)3NH2 Molecular Weight 189 Active Hydrogen Equivalent 27 Brown Liquid 11-15 parts per 100 parts of standard resin.
Properties as above.
PEPA H2NC2H4(NHC2H4)nNH2 Light Yellow Liquid 14-15 parts per 100 parts of standard resin.
Properties: low toxicity, low volatility, long application period, low price.
Dipropylenetriamine DPTA H2N(CH2)3 NH(CH2)3NH2
Molecular weight 131 Active hydrogen equivalent 2

Recommended Related Reading:

Dabco NE1060/Non-emissive polyurethane catalyst

Non-emissive polyurethane catalyst/Dabco NE1060 catalyst

DMAPA

2-(2-Aminoethoxy)ethanol

Morpholine

TEDA

Jeffcat ZF-22

BDMAEE Exporter

N-Methylmorpholine

4-Formylmorpholine

Chilling Innovations: How Refrigerator Catalysts Enhance Energy Efficiency and Air Quality for a Greener Future

Explore the world of refrigerator catalysts and discover how they contribute to improved energy efficiency, air purification, and environmental sustainability in modern refrigeration systems.
Introduction
Refrigerator catalysts are specialized materials designed to improve the performance and energy efficiency of refrigeration systems while also enhancing air quality. These innovative catalysts play a crucial role in promoting a greener and more sustainable future for refrigeration technology. This article delves into the concept of refrigerator catalysts, their applications, and the advancements that are shaping their future.
Understanding Refrigerator Catalysts
Refrigerator catalysts are typically composed of metal or metal oxide nanoparticles, which are integrated into various components of the refrigeration system, such as the evaporator, condenser, or air filters. They function by facilitating chemical reactions that help to eliminate volatile organic compounds (VOCs), bacteria, and other airborne contaminants, resulting in improved air quality and reduced energy consumption.
Applications of Refrigerator Catalysts
The versatility of refrigerator catalysts has led to their widespread adoption across various refrigeration systems. Some of the most prominent applications include:
Air Purification: Refrigerator catalysts are used in air filters to remove VOCs, bacteria, and other airborne contaminants, ensuring that the air inside the refrigerator remains fresh and clean. This not only enhances food safety but also reduces the need for frequent cleaning and maintenance.
Energy Efficiency: Refrigerator catalysts can improve the heat transfer efficiency of the evaporator and condenser coils, leading to reduced energy consumption and lower operating costs. By facilitating the breakdown of frost and ice buildup, these catalysts also help to maintain optimal cooling performance.
Odor Elimination: Refrigerator catalysts can effectively eliminate unpleasant odors caused by food spoilage or other sources. This is achieved through the oxidation of odor-causing molecules, which are converted into harmless by-products such as water and carbon dioxide.
Advancements in Refrigerator Catalysts Technology
The field of refrigerator catalysts is continually evolving, with researchers and manufacturers constantly seeking to develop new and improved materials. Some of the latest advancements in refrigerator catalysts technology include:
Nanotechnology: The integration of nanotechnology in refrigerator catalysts has led to the creation of advanced materials with enhanced properties, such as increased surface area, improved stability, and better dispersion. These features contribute to more efficient and effective air purification and energy savings.
Photocatalysts: Photocatalysts are a type of refrigerator catalyst that utilizes light energy, typically from UV or visible light, to initiate chemical reactions. These materials can effectively decompose organic pollutants and eliminate bacteria, making them an attractive option for air purification and odor elimination in refrigeration systems.
Multifunctional Catalysts: Researchers are focusing on developing multifunctional refrigerator catalysts that can perform multiple tasks simultaneously, such as air purification, odor elimination, and energy efficiency enhancement. These innovative materials have the potential to revolutionize the refrigeration industry by offering comprehensive performance improvements in a single solution.
The Future of Refrigerator Catalysts
As the demand for energy-efficient, eco-friendly, and high-performance refrigeration systems continues to grow, the market for refrigerator catalysts is expected to expand significantly. According to a recent study, the global refrigerator catalysts market is projected to reach USD 1.2 billion by 2026, growing at a CAGR of 6.8% during the forecast period.
The future of refrigerator catalysts lies in the development of advanced materials that can address the evolving needs of the refrigeration industry. Researchers are focusing on creating more efficient, durable, and sustainable catalysts that can contribute to greener and more environmentally conscious refrigeration systems.
Conclusion
Refrigerator catalysts have undeniably transformed the landscape of refrigeration technology, offering unparalleled energy efficiency, air purification, and sustainability. As advancements in technology continue to shape the future of refrigerator catalysts, we can expect to see even more innovative and eco-friendly solutions that will further revolutionize the refrigeration industry. With their unique properties and wide-ranging applications, refrigerator catalysts are truly a testament to the power of human ingenuity and the relentless pursuit of progress.
Recommended Reading：
NT CAT DMDEE
NT CAT PC-5
NT CAT DMP-30
NT CAT DMEA
NT CAT BDMA
NT CAT PC-9
NT CAT ZR-50
NT CAT TMR-2
NT CAT PC-77
NT CAT PC-41
NT CAT PC-8

What are all the catalysts in the synthesis of polylactic acid?

The catalysts used in the synthesis of PLA are mainly as follows:

Tin catalysts: This is a class of catalysts commonly used in the synthesis of PLA, including tin, stannous chloride and stannous octanoate. Among them, stannous octanoate is considered to be the best catalyst. Under certain conditions, PLA synthesised using stannous octanoate as catalyst has excellent properties, such as no oxidation, discolouration, and the viscosity average molecular weight can reach a high level.
Metal catalysts: Metal catalysts also play an important role in the synthesis of PLA. These catalysts can promote the condensation reaction of lactic acid monomers, so as to effectively form PLA chains.
In addition to the common catalysts mentioned above, there are some other types of catalysts that may be used in the synthesis of PLA, but the exact catalyst to be used depends on factors such as the synthesis method, the reaction conditions, and the properties of the desired PLA. Therefore, when selecting a catalyst, various factors need to be considered in order to achieve the best synthesis results.

Please note that the selection and use of catalysts should follow the relevant safety regulations and operating procedures to ensure the safety and reliability of the experimental process. Meanwhile, with the continuous development of science and technology, new types of catalysts are emerging, so it may also be necessary to pay attention to the latest research results and technological advances in practical applications.

Recommended Related Reading:

Dabco NE1060/Non-emissive polyurethane catalyst

Non-emissive polyurethane catalyst/Dabco NE1060 catalyst

DMAPA

2-(2-Aminoethoxy)ethanol

Morpholine

TEDA

Jeffcat ZF-22

BDMAEE Exporter

N-Methylmorpholine

4-Formylmorpholine

How to prepare a solution of stannous toluene octanoate

To prepare the stannous octanoate toluene solution, the following steps may be followed:

Prepare the required materials and equipment including stannous octanoate, toluene solvent, containers, stirrers and suitable heating equipment.
Take an appropriate amount of the toluene solvent and pour it into the container and heat it to a suitable temperature to induce the dissolution process. The exact heating temperature should be determined according to the nature of the toluene solvent and stannous octanoate used to ensure that the temperature is not too high to cause volatilisation of the solvent or other unfavourable reactions.
Gradually add the corresponding proportion of stannous octanoate while mixing well with a stirrer. The amount of stannous octanoate added should be determined by the desired concentration of the solution.
Stir continuously until the stannous octanoate is completely dissolved in the toluene solvent and a homogeneous solution is formed.
Please note that the preparation process should be carried out in a safe manner, avoiding contact with skin and inhalation of harmful gases. Meanwhile, both stannous octanoate and toluene are chemical substances that need to be stored and used under suitable conditions to avoid reaction with other substances or causing environmental pollution.

In addition, the specific proportion and conditions of preparation may vary depending on the application requirements, nature of the materials or safety regulations. Therefore, in practice, it is recommended to refer to relevant chemical manuals, professional information or consult chemical experts to ensure the accuracy and safety of the formulation process.

Recommended Related Reading:

Dabco NE1060/Non-emissive polyurethane catalyst

Non-emissive polyurethane catalyst/Dabco NE1060 catalyst

DMAPA

2-(2-Aminoethoxy)ethanol

Morpholine

TEDA

Jeffcat ZF-22

BDMAEE Exporter

N-Methylmorpholine

4-Formylmorpholine

Calculation of catalysts in polyurethane soft foam formulations

The kinetics of the reaction between hydroxyl compounds and isocyanates – d (- NCO)/dt=K0 x (- NCO) x (- OH)
K1 is the forward reaction rate of the formation of complexes between isocyanates and hydroxyl compounds
K2 is the negative reaction rate of the formation of complexes between isocyanates and hydroxyl compounds
K3 is the forward reaction rate at which complexes react with hydroxyl compounds to form aminoformates and hydroxyl compounds.
K0=[K1 x K3 x (- OH)]/[K2+K3 x
Arrhenius equation
K=Ae ^ [- (Ea/RT)]
A: Exponential factor.
E=2.718
Ea: KJ/mol
R=8.31 (J/mol. K)
Calculation of reaction heat for the formation of functional groups such as urea, polyurethane, biuret, and urea formate:
Bond dissociation energy (KJ/mol)
C-N 205.1~251.2
C-C 230.2~293.0
C-O 293.0-314.0
N-H 351.6~406.0
C-H 364.9~393.5
O-H 422.8~460.5
C=C 418.6~523.3
C=O 594.1~694.9
Reaction formula:
RNCO+rOH → RNHCOOr
RNCO+HOH → RNHCOOH+RNCO → RNHCONHR+OCO ↑
RNHCOOr+RNCO → RNCONHRCOOr
RNHCONHr+RNCO → RNCONHRCONHr
The volume ratio of gas to the total volume of the polymerization system (Vg/Vo) in the polymerization system affects the temperature control ability: gas monomers affect the concentration (mol/L), which affects the polymerization heat [Q (KJ/L)=Rp (mol/L) * (- H)]. The heat of polymerization is transferred to the gas dispersion medium, causing the gas to absorb heat and expand (PV=NR/T). After a sudden increase in temperature in the polymerization system, the gas releases and carries away a large amount of heat (approximately in a straight line with Vg/Vo)
When preparing polyurethane in one step, the activation energy of amino acids is about 60 (mol. K), and the activation energy of urea reaction is 17 (mol. K)
The foam system is easier to implement than the solution suspension system. Dispersive polymerization exhibits the Norrish Tromasof effect at the beginning of the reaction, slowing down the rate of change of chain growth parameters over time and improving the monodispersity of the product.
Dispersion polymerization is a method of separating the polymerization system into numerous fine foam by gas, so that the polymerization components can be converted into the surface liquid film of foam and the “polyhedral boundary liquid cell” connecting multiple liquid films can form a special dispersion phase for polymerization.
The foam system uses gas as the dispersion medium, and the gas expands and cools suddenly when it is heated, and the negative pressure generated when the gas escapes will further polymerize the residual single concentration of the system, and accelerate and carry the evaporation of water molecules and the removal of small molecules.
The dispersion effect of gas on the polymerization system is not equivalent to true dilution of monomers.
General formula for half-life of non first-order reactions
T=[2 ^ (n-1) -1]/[a x k x (n-1) x A ^ (n-1)]
Second order reaction rate constant
A+B → Q+S
Kt=[1/(CA0-CB0)] x ln [(CB0 x CA)/(CA0 x CB)]
CA0 x Kt=[1/(1-M)] x ln {[M (1-xA)]/(M-xA)}, where M=CB0/CA0
Attachment:
Example of calculating the density of polyurethane soft foam
General polyether ternary alcohol Ppg: 50pop: 50tdi-80:42.8hoh: 3.17L-580:1a33:0.34sn: 0.17
Calculated: 4.34 2.17 6.51 38.2 112% 17% 5.2 1.74 122 Recalculated, 28kg/cubic meter
Example of calculation for polyurethane soft foam catalyst:
Universal polyether ternary alcohol ppg: 90 pop: 10 tdi-80:: 35.5 hoh: 2.2 L-580:0.84 Black slurry: 6
Calculated: A33:0.18 T-9:0.25
A33:0.14 T-9:0.24
A33:0.13 T-9:0.35
A33:0.12 T-9:0.30
Tolerance and turning points
Calculation of vertical foam flow rate and lifting speed:
Formula (for example only) PPG: 100, TDI: 80, HOH: 6, SI: 1.5, A33: * * *, SN: * * *, MC: 14.8
The diameter of the vertical bubble circular mold is 1.25.
Polyether flow rate is 12 kilograms per minute.
What is the speed of improvement in meters per minute
Calculate the formula density of 12 kilograms per cubic meter. The total weight of the formula is 173.5 kilograms. The formula volume is 14.46 cubic meters. Circular mold cross-sectional area: 1.23 square meters.
Set a loss rate of 5%.
Boosting speed: [14.46 x 12% x (1-5%)]/1.23=1.34 meters per minute.
Related reading recommendations:

NT CAT U26

NT CAT K-15

NT CAT D60

TMPEDA

TEDA

Morpholine

2-(2-Aminoethoxy)ethanol

N-Methylmorpholine

4-Formylmorpholine

dimethomorph

3-morpholinopropylamine

4-Acryloylmorpholine

Foaming Catalysts in Action: Unraveling the Role of Catalysts in Polyurethane Foam Production

Introduction
Polyurethane foams are a versatile class of materials widely used in various applications, including insulation, cushioning, and packaging. The production of polyurethane foams involves a reaction between polyols and isocyanates, which generates carbon dioxide gas, leading to the formation of a cellular structure. Foaming catalysts play a crucial role in this process, accelerating the reaction and influencing the properties of the resulting foam. This article delves into the role of foaming catalysts, their types, mechanisms, and the impact they have on the polyurethane foam industry.
Understanding Foaming Catalysts and Their Mechanisms
Foaming catalysts are substances that promote the formation of polyurethane foams by accelerating the reaction between polyols and isocyanates, as well as the decomposition of blowing agents, which generate the gas responsible for foam expansion. They work by increasing the nucleophilicity of the polyol, facilitating its reaction with the isocyanate, and enhancing the decomposition of blowing agents. Foaming catalysts can also influence the structure and properties of the resulting foam, such as its density, cell size, and mechanical properties.
Types of Foaming Catalysts
Foaming catalysts can be classified into three main categories based on their chemical nature:
Amines: Amines are the most commonly used foaming catalysts, and they can be further divided into tertiary amines and secondary amines. Tertiary amines, such as triethylenediamine (TEDA) and N,N-dimethylcyclohexylamine (DMCHA), are strong catalysts for both the gelation and blowing reactions. Secondary amines, such as N,N-dimethylethanolamine (DMEA), primarily catalyze the gelation reaction but have a weaker effect on the blowing reaction.

Metal Salts: Metal salts, such as tin, bismuth, and lead salts, are also used as foaming catalysts. They are typically more active in the gelation reaction than amines but less active in the blowing reaction. Examples of metal salt catalysts include dibutyltin dilaurate (DBTDL), stannous octoate, and bismuth neodecanoate.
Organometallic Compounds: Organometallic compounds, such as alkyl tin compounds and organotin mercaptides, are used as foaming catalysts due to their high activity and selectivity. They primarily catalyze the gelation reaction and can be used in combination with amine catalysts to achieve desired properties.
Impact of Foaming Catalysts on the Polyurethane Foam Industry
The use of foaming catalysts offers numerous benefits to the polyurethane foam industry, including:
Enhanced Foam Production Efficiency: Foaming catalysts accelerate the reaction between polyols and isocyanates, as well as the decomposition of blowing agents, enabling faster foam production times and increased productivity.
Improved Foam Properties: By influencing the structure and properties of polyurethane foams, catalysts can help achieve desired characteristics, such as improved mechanical strength, better insulation, and enhanced durability.
Customization of Polyurethane Foams: The selection of appropriate catalysts and their combinations allows for the customization of polyurethane foams to suit specific applications, such as flexible foams for furniture, rigid foams for insulation, or specialty foams for packaging.
Reduced Environmental Impact: Foaming catalysts can contribute to greener production processes by minimizing waste, reducing energy consumption, and enabling the use of renewable resources in polyurethane foam synthesis.
Foaming Catalysts in Action: The Polyurethane Foam Production Process
The polyurethane foam production process typically involves the following steps:
Mixing of Polyols and Isocyanates: Polyols and isocyanates are mixed together, along with other additives, such as surfactants, flame retardants, and blowing agents.
Catalyst Addition: Foaming catalysts are added to the mixture, accelerating the reaction between polyols and isocyanates and the decomposition of blowing agents.
Foam Expansion: The generated gas expands the mixture, creating a cellular structure.
Curing: The polyurethane foam is allowed to cure, forming a solid material with the desired properties.
Ongoing Research and Future Prospects
The field of foaming catalysts is continuously evolving, with researchers exploring new materials, designs, and applications. Some of the exciting developments in this area include:
Green Catalysts: The search for environmentally friendly foaming catalysts is an ongoing effort, aiming to minimize the use of toxic materials and promote sustainable production processes.
Nanotechnology: The incorporation of nanomaterials in foaming catalysts offers the potential for improved catalytic performance, enhanced foam properties, and new applications.
Computational Design: Advanced computational tools and techniques are being employed to predict and optimize the performance of foaming catalysts, accelerating the discovery and development of new materials.
Conclusion
Foaming catalysts play a vital role in the production and performance of polyurethane foams, offering numerous benefits to the polyurethane foam industry. As research continues to uncover new catalysts and applications, the role of foaming catalysts will undoubtedly expand, contributing to the development of innovative, sustainable, and high-performance polyurethane foam products.
Recommended Reading：
NT CAT U28
NT CAT U26
NT CAT K-15
NT CAT D60
TMPEDA
TEDA
Morpholine
2-(2-Aminoethoxy)ethanol
DMAPA
NT CAT A-1