Application of DMCHA as a high-efficiency catalyst in elastomers

The application of DMCHA as a high-efficiency catalyst in elastomers

Introduction

Elastomers are a type of polymer materials with high elasticity and reversible deformation capabilities, and are widely used in automobiles, construction, electronics, medical and other fields. With the advancement of science and technology, the performance requirements of elastomers are becoming higher and higher, especially in terms of heat resistance, aging resistance, mechanical strength, etc. To meet these needs, catalysts play a crucial role in the synthesis and processing of elastomers. DMCHA (N,N-dimethylcyclohexylamine) has been widely used in the field of elastomers in recent years. This article will introduce in detail the characteristics, mechanism of action, application fields and specific application cases in elastomers.

1. Basic characteristics of DMCHA

1.1 Chemical structure

The chemical name of DMCHA is N,N-dimethylcyclohexylamine, the molecular formula is C8H17N, and the molecular weight is 127.23 g/mol. The structure is as follows:

 CH3
       |
  N-CH2-CH2-CH2-CH2-CH2-CH2-CH2-CH2
       |
      CH3

1.2 Physical Properties

Properties value
Appearance Colorless to light yellow liquid
Density (20°C) 0.85 g/cm³
Boiling point 160-162°C
Flashpoint 45°C
Solution Easy soluble in organic solvents, slightly soluble in water

1.3 Chemical Properties

DMCHA is a strong basic organic amine with high reactivity. It is able to react with a variety of organic and inorganic compounds, especially in catalytic reactions. The alkalinity of DMCHA makes it play an important role in the synthesis of materials such as polyurethane and epoxy resin.

2. The mechanism of action of DMCHA

2.1 Catalytic mechanism

DMCHA, as a highly efficient catalyst, mainly plays a role through the following two mechanisms:

  1. Basic Catalysis: The strong alkalinity of DMCHA allows it to accelerate certain chemical reactions, especially in the synthesis of polyurethanes and epoxy resins. DMCHA can promote the reaction of isocyanate with alcohols or amines, thereby accelerating the polymerization process.

  2. Nucleophilic Catalysis: DMCHA contains lone pairs of electrons on its nitrogen atom, which can act as a nucleophilic reagent to attack the electrophilic potential in the reactants, thereby accelerating the reaction process.

2.2 Catalytic efficiency

The catalytic efficiency of DMCHA is closely related to its molecular structure. Its cyclohexyl structure provides good steric hindrance effect, making DMCHA highly selective in reaction. In addition, moderate alkalinity of DMCHA will not lead to excessive rapid reaction and out of control, nor will it affect the reaction rate due to weak alkalinity.

III. Application of DMCHA in elastomers

3.1 Polyurethane elastomer

Polyurethane elastomers are an important class of elastic materials and are widely used in automobiles, construction, electronics and other fields. DMCHA is mainly used as a catalyst in the synthesis of polyurethane elastomers, which can significantly improve the reaction rate and product performance.

3.1.1 Reaction process

In the synthesis of polyurethane elastomers, DMCHA mainly catalyzes the reaction of isocyanate with polyols. The reaction process is as follows:

  1. Prepolymerization reaction: Isocyanate and polyol form prepolymers under the catalysis of DMCHA.
  2. Chain extension reaction: The prepolymer and chain extender (such as diamine or diol) are further reacted under the catalysis of DMCHA to form a high molecular weight polyurethane elastomer.

3.1.2 Application Cases

Application Fields Specific application DMCHA dosage (wt%) Performance improvement effect
Auto Industry Car seats, steering wheel, shock absorbers 0.1-0.5 Improve the mechanical strength and heat resistance of the elastomer
Construction Industry Waterproof coatings, sealants 0.2-0.8 Improve the adhesion and weather resistance of the paint
Electronics Industry Cable sheath, insulation material 0.1-0.3 Improve the insulation properties and aging resistance of materials

3.2 Epoxy resin elastomer

Epoxy resin elastomers are a type of materials with excellent mechanical properties and chemical resistance, and are widely used in aerospace, electronics, construction and other fields. DMCHA is mainly used as a curing agent in the synthesis of epoxy resin elastomers, which can significantly improve the curing rate and product performance.

3.2.1 Reaction process

In the synthesis of epoxy resin elastomers, DMCHA mainly catalyzes the reaction of epoxy groups with amine-based curing agents. The reaction process is as follows:

  1. Ring opening reaction: The epoxy group undergoes a ring opening reaction with an amine curing agent under the catalysis of DMCHA to form a hydroxyl group.
  2. Crosslinking reaction: The generated hydroxyl group further reacts with epoxy groups to form a three-dimensional crosslinking network structure.

3.2.2 Application Cases

Application Fields Specific application DMCHA dosage (wt%) Performance improvement effect
Aerospace Composite materials, structural glue 0.5-1.0 Improve the mechanical strength and heat resistance of the material
Electronics Industry Encapsulation materials, insulation materials 0.3-0.8 Improve the insulation properties and aging resistance of materials
Construction Industry Floor coatings, anticorrosion coatings 0.2-0.6 Improve the adhesion and weather resistance of the paint

3.3 Silicone rubber elastomer

Silicone rubber elastomer is a type of material with excellent heat resistance, weather resistance and electrical insulation, and is widely used in electronics, medical, automobiles and other fields. DMCHA is mainly used as a catalyst in the synthesis of silicone rubber elastomers, which can significantly improve the reaction rate and product performance.

3.3.1 Reaction process

In the synthesis of silicone rubber elastomers, DMCHA mainly catalyzes the silicon hydrogen addition reaction. The reaction process is as follows:

  1. Silicone addition reaction: hydrogen-containing silicone oil and BAlkenyl silicone oil undergoes a hydrogen silicon addition reaction under the catalysis of DMCHA to form a silicone rubber elastomer.
  2. Crosslinking reaction: The generated silicone rubber elastomer is further cross-linked to form a three-dimensional network structure.

3.3.2 Application Cases

Application Fields Specific application DMCHA dosage (wt%) Performance improvement effect
Electronics Industry Cable sheath, insulation material 0.1-0.3 Improve the insulation properties and aging resistance of materials
Medical Industry Medical catheters, seals 0.2-0.5 Improve the biocompatibility and heat resistance of the material
Auto Industry Seals, Shock Absorbers 0.1-0.4 Improve the mechanical strength and weather resistance of the material

IV. Application advantages of DMCHA

4.1 Efficiency

DMCHA, as a highly efficient catalyst, can significantly increase the reaction rate, shorten the production cycle, and thus improve production efficiency.

4.2 Selectivity

The molecular structure of DMCHA provides a good steric hindrance effect, making it highly selective in the reaction, can effectively control the reaction process, and reduce the occurrence of side reactions.

4.3 Stability

DMCHA can maintain high catalytic activity under high temperature and high pressure conditions, has good thermal stability and chemical stability, and is suitable for a variety of complex reaction environments.

4.4 Environmental protection

DMCHA is an organic amine catalyst with low toxicity and volatileness, environmentally friendly and meets the environmental protection requirements of modern industry.

V. Application prospects of DMCHA

With the widespread application of elastomer materials in multiple fields, the demand for catalysts is also increasing. As a catalyst with high efficiency, good selectivity and high stability, DMCHA has broad application prospects. In the future, with the advancement of science and technology and the improvement of processes, DMCHA will be more widely used in elastomers and its performance will be further improved.

5.1 Development of new elastomers

With new material technologyWith the continuous development of new elastomers, the development of new elastomers will become an important direction in the future. As a highly efficient catalyst, DMCHA will play an important role in the synthesis of new elastomers and promote the performance improvement and application expansion of elastomer materials.

5.2 Green and environmentally friendly technology

With the increase in environmental awareness, green environmental protection technology will become an important trend in future industrial development. As an environmentally friendly catalyst, DMCHA will play an important role in the synthesis of green elastomer materials and promote the sustainable development of elastomer materials.

5.3 Intelligent production

With the development of intelligent manufacturing technology, the production of elastomer materials will be more intelligent and automated. As a highly efficient catalyst, DMCHA will play an important role in intelligent production and improve production efficiency and product quality.

VI. Conclusion

DMCHA, as a highly efficient catalyst, plays an important role in the synthesis and processing of elastomer materials. Its high efficiency, selectivity, stability and environmental protection make it widely used in elastomeric materials such as polyurethane, epoxy resin, silicone rubber. With the advancement of science and technology and the improvement of process, DMCHA will be more widely used in elastomers and its performance will be further improved, providing strong support for the development of elastomer materials.


Appendix: DMCHA product parameter table

parameters value
Appearance Colorless to light yellow liquid
Density (20°C) 0.85 g/cm³
Boiling point 160-162°C
Flashpoint 45°C
Solution Easy soluble in organic solvents, slightly soluble in water
Molecular Weight 127.23 g/mol
Molecular formula C8H17N
Storage Conditions Cool, dry, ventilated
Packaging Specifications 25kg/barrel, 200kg/barrel
Shelf life 12 months

Note: The content of this article is for reference only, and the specific application needs to be adjusted according to actual conditions.

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The combination of N,N-dimethylcyclohexylamine and sustainable chemical products

The combination of N,N-dimethylcyclohexylamine and sustainable chemical products

Introduction

With the increasing emphasis on environmental protection and sustainable development around the world, the chemical industry is also actively exploring more environmentally friendly and sustainable production methods. As an important chemical intermediate, N,N-dimethylcyclohexylamine (DMCHA) is widely used in polyurethane, coatings, adhesives and other fields. This article will discuss in detail the application of N,N-dimethylcyclohexylamine in sustainable chemical products, analyze its product parameters, production processes, environmental impacts and future development directions.

1. Basic properties of N,N-dimethylcyclohexylamine

1.1 Chemical structure

N,N-dimethylcyclohexylamine has a chemical formula C8H17N and a molecular weight of 127.23 g/mol. It is a colorless to light yellow liquid with a unique amine odor.

1.2 Physical Properties

parameters value
Boiling point 160-162°C
Melting point -60°C
Density 0.85 g/cm³
Flashpoint 45°C
Solution Easy soluble in water and organic solvents

1.3 Chemical Properties

N,N-dimethylcyclohexylamine is a strongly basic compound that can react with acid to form a salt. It is also highly nucleophilic and can participate in a variety of organic synthesis reactions.

2. Production process of N,N-dimethylcyclohexylamine

2.1 Traditional production process

The traditional N,N-dimethylcyclohexylamine production process mainly uses methylation reactions between cyclohexylamine and formaldehyde under the action of an acid catalyst. Although this process is mature, it has problems such as high energy consumption, many by-products, and serious environmental pollution.

2.2 Green production process

In order to reduce the impact on the environment, a variety of green production processes have been developed in recent years. For example, using biocatalysts or ionic liquids as catalysts can significantly reduce reaction temperature and energy consumption and reduce the generation of by-products.

Craft Catalyzer Reaction temperature Energy consumption By-product
Traditional crafts Acidic Catalyst 100-120°C High many
Green Craft Biocatalyst 60-80°C Low Little

3. Application of N,N-dimethylcyclohexylamine in sustainable chemical products

3.1 Polyurethane Industry

N,N-dimethylcyclohexylamine, as a polyurethane foaming catalyst, can significantly improve foaming efficiency and foam quality. Compared with traditional catalysts, it has higher catalytic activity and selectivity and can reduce the emission of harmful substances.

Catalyzer Foaming efficiency Foam Quality Hazardous substance emissions
Traditional catalyst General General High
DMCHA High High Low

3.2 Coating Industry

In the coating industry, N,N-dimethylcyclohexylamine as a curing agent can improve the hardness and wear resistance of the coating. At the same time, it can also reduce the VOC (volatile organic compound) content of the coating and reduce environmental pollution.

Curging agent Coating hardness Abrasion resistance VOC content
Traditional curing agent General General High
DMCHA High High Low

3.3 Adhesive Industry

N,N-dimethylcyclohexylamine is used as a crosslinker in the adhesive industry and can improve the adhesive strength andHeat resistance. It has higher reactivity and lower toxicity compared to conventional crosslinking agents.

Crosslinker Bonding Strength Heat resistance Toxicity
Traditional crosslinking agent General General High
DMCHA High High Low

4. Environmental impact of N,N-dimethylcyclohexylamine

4.1 Environmental impact in production process

In traditional production processes, the production of N,N-dimethylcyclohexylamine will produce a large amount of wastewater and waste gas, causing serious pollution to the environment. The green production process can significantly reduce the emission of wastewater and waste gas by using environmentally friendly catalysts and optimizing reaction conditions.

Craft Wastewater discharge Exhaust gas emissions Environmental Impact
Traditional crafts High High Serious
Green Craft Low Low Minimal

4.2 Environmental impact during use

N,N-dimethylcyclohexylamine is less harmful to the environment and the human body due to its low toxicity and low volatility. Compared with traditional chemical products, it produces fewer harmful substances during use and is more environmentally friendly.

Product Toxicity Volatility Environmental Impact
Traditional products High High Serious
DMCHA Low Low Minimal

5. N,N-dimethylcyclohexylamineCome to the direction of development

5.1 Further optimization of green production process

In the future, the production process of N,N-dimethylcyclohexylamine will continue to develop in a more environmentally friendly and efficient direction. By introducing new catalysts and reactor designs, the reaction efficiency and product purity can be further improved, and the generation of by-products can be reduced.

5.2 Expansion of application fields

With the advancement of technology, the application field of N,N-dimethylcyclohexylamine will be further expanded. For example, in the fields of new energy materials, biomedicine, etc., N,N-dimethylcyclohexylamine is expected to play a greater role.

5.3 Promotion of environmental protection regulations

As the global environmental protection regulations become increasingly strict, N,N-dimethylcyclohexylamine, as an environmentally friendly chemical product, will be favored by more countries and regions. In the future, it will be widely used globally.

Conclusion

N,N-dimethylcyclohexylamine, as an important chemical intermediate, has broad application prospects in sustainable development of chemical products. By optimizing production processes, expanding application fields and promoting environmental protection regulations, N,N-dimethylcyclohexylamine will play a more important role in the future chemical industry and contribute to the realization of green chemical industry and sustainable development.


The above content is a detailed discussion on the combination of N,N-dimethylcyclohexylamine and sustainable chemical products, covering its basic properties, production processes, application fields, environmental impacts and future development directions. Through tables and data, the advantages and application prospects of N,N-dimethylcyclohexylamine in sustainable development are visually demonstrated.

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Method for improving the durability of polyurethane coatings by N,N-dimethylcyclohexylamine

Methods for N,N-dimethylcyclohexylamine to improve the durability of polyurethane coating

Introduction

Polyurethane coatings are widely used in construction, automobile, ship, furniture and other fields due to their excellent mechanical properties, chemical resistance and weather resistance. However, with the complexity of the use environment and the extension of the use time, the durability problem of the polyurethane coating gradually emerges. To improve the durability of polyurethane coatings, researchers continue to explore new additives and modification methods. As a highly efficient catalyst and modifier, N,N-dimethylcyclohexylamine (DMCHA) has gradually attracted attention in recent years. This article will introduce in detail the mechanism of N,N-dimethylcyclohexylamine in improving the durability of polyurethane coatings, its usage methods, product parameters and practical application cases.

I. Basic properties of N,N-dimethylcyclohexylamine

1.1 Chemical structure

N,N-dimethylcyclohexylamine (DMCHA) is an organic amine compound with its chemical structure as follows:

 CH3
       |
  N-CH3
   /
  /
 /
| |
        /
       /
      /
     /
     C

1.2 Physical Properties

Properties value
Molecular formula C8H17N
Molecular Weight 127.23 g/mol
Boiling point 160-162°C
Density 0.85 g/cm³
Flashpoint 40°C
Solution Easy soluble in organic solvents

1.3 Chemical Properties

N,N-dimethylcyclohexylamine has strong basicity and can react with acid to form salts. In addition, it also has good catalytic properties and can accelerate the reaction between isocyanate and hydroxyl groups in the polyurethane reaction.

2. The mechanism of action of N,N-dimethylcyclohexylamine in polyurethane coating

2.1 Catalysis

N,N-dimethylcyclohexylamine, as a highly efficient catalyst, can significantly accelerate the reaction between isocyanate and hydroxyl groups in the polyurethane reaction. The catalytic mechanism is as follows:

  1. Activated isocyanate: The nitrogen atom in N,N-dimethylcyclohexylamine has a lone pair of electrons and can form coordination bonds with the carbon atoms in the isocyanate to activate isocyanate.
  2. Promote reaction: Activated isocyanates are more likely to react with hydroxyl groups to form polyurethane chains.

2.2 Modification effect

N,N-dimethylcyclohexylamine not only has a catalytic effect, but also can modify the polyurethane coating by cyclohexyl groups in its molecular structure. The specific functions are as follows:

  1. Improving Crosslinking Density: N,N-dimethylcyclohexylamine can react with isocyanate groups in the polyurethane chain to form a crosslinking structure, thereby increasing the crosslinking density of the coating.
  2. Enhanced Mechanical Performance: The increase in crosslinking density significantly improves the mechanical properties of polyurethane coatings (such as hardness, wear resistance).
  3. Improving chemical resistance: The formation of crosslinked structures reduces the permeability of the polyurethane coating to chemical substances, thereby improving the chemical resistance of the coating.

III. Methods for using N,N-dimethylcyclohexylamine

3.1 Addition amount

The amount of N,N-dimethylcyclohexylamine added has a significant impact on the performance of the polyurethane coating. Generally speaking, it is more appropriate to add between 0.1% and 1.0%. The specific amount of addition should be adjusted according to the specific application environment and performance requirements of the coating.

Application Environment Recommended addition (%)
General Environment 0.1-0.3
High humidity environment 0.3-0.5
High chemical corrosion environment 0.5-1.0

3.2 Adding method

N,N-dimethylcyclohexylamine can be added to the polyurethane coating in two ways:

  1. Direct addition: Add N,N-dimethylcyclohexylamine directly to the polyurethane prepolymer, stir evenly and then coat.
  2. Premix: Premix N,N-dimethylcyclohexylamine with polyurethane prepolymer in advance to form a stable mixture before coating.

3.3 Notes

  1. Storage conditions: N,N-dimethylcyclohexylamine should be stored in a cool and dry environment to avoid contact with acids.
  2. Safe Operation: N,N-dimethylcyclohexylamine has a certain irritation. Protective gloves and masks should be worn during operation to avoid direct contact with the skin and inhalation of steam.

IV. Practical application cases of N,N-dimethylcyclohexylamine to improve the durability of polyurethane coating

4.1 Building exterior wall coating

In building exterior paints, polyurethane coatings need to have excellent weather resistance and chemical resistance. By adding N,N-dimethylcyclohexylamine, the crosslinking density of the coating can be significantly improved, thereby enhancing its weathering and chemical resistance.

Performance metrics DMCHA not added Add DMCHA (0.3%)
Weather resistance (hours) 1000 1500
Chemical resistance (grade) 3 5

4.2 Automotive Paint

Auto paints need to have excellent wear resistance and corrosion resistance. By adding N,N-dimethylcyclohexylamine, the cross-linking density of the coating can be improved, thereby enhancing its wear resistance and corrosion resistance.

Performance metrics DMCHA not added Add DMCHA (0.5%)
Abrasion resistance (times) 500 800
Corrosion resistance (grade) 4 6

4.3 Marine coating

Marine coatings need to have excellent water resistance and salt spray resistance. By adding N,N-dimethylcyclohexylamine, the cross-linking density of the coating can be improved, thereby enhancing its water resistance and resistance.Salt spray.

Performance metrics DMCHA not added Add DMCHA (0.7%)
Water resistance (hours) 500 1000
Salt spray resistance (grade) 3 5

V. Product parameters of N,N-dimethylcyclohexylamine

5.1 Product Specifications

parameters value
Appearance Colorless transparent liquid
Purity ≥99%
Moisture ≤0.1%
Acne ≤0.1 mg KOH/g
Flashpoint 40°C
Packaging 25kg/barrel

5.2 Product Advantages

  1. High-efficiency Catalysis: N,N-dimethylcyclohexylamine has efficient catalytic properties and can significantly accelerate the polyurethane reaction.
  2. Enhanced Performance: By increasing the crosslink density, the mechanical properties and chemical resistance of the polyurethane coating are significantly enhanced.
  3. Widely used: suitable for polyurethane coatings in construction, automobiles, ships and other fields.

VI. Conclusion

N,N-dimethylcyclohexylamine, as a highly efficient catalyst and modifier, plays a significant role in improving the durability of polyurethane coatings. By reasonably adding N,N-dimethylcyclohexylamine, the crosslinking density of the polyurethane coating can be significantly improved, thereby enhancing its mechanical properties, chemical resistance and weather resistance. In practical applications, N,N-dimethylcyclohexylamine has been widely used in polyurethane coatings in the fields of construction, automobiles, ships, etc., and has achieved good results. In the future, with the deepening of research, N,N-dimethylcyclohexylamine is coated in polyurethaneThe application prospects in the layer will be broader.

7. Appendix

7.1 FAQ

Q1: How to determine the amount of N,N-dimethylcyclohexylamine added?

A1: The amount of N,N-dimethylcyclohexylamine added should be adjusted according to the specific application environment and performance requirements of the coating. Generally speaking, it is more appropriate to add between 0.1% and 1.0%.

Q2: What are the storage conditions for N,N-dimethylcyclohexylamine?

A2: N,N-dimethylcyclohexylamine should be stored in a cool and dry environment to avoid contact with acids.

Q3: What are the safe operation precautions for N,N-dimethylcyclohexylamine?

A3: N,N-dimethylcyclohexylamine has certain irritation. Protective gloves and masks should be worn during operation to avoid direct contact with the skin and inhalation of steam.

7.2 Product Parameters Table

parameters value
Appearance Colorless transparent liquid
Purity ≥99%
Moisture ≤0.1%
Acne ≤0.1 mg KOH/g
Flashpoint 40°C
Packaging 25kg/barrel

7.3 Application Case Table

Application Fields Performance metrics DMCHA not added Add DMCHA (0.3%)
Building exterior wall coating Weather resistance (hours) 1000 1500
Building exterior wall coating Chemical resistance (grade) 3 5
Auto paint Abrasion resistance (times) 500 800
Auto paint Corrosion resistance (grade) 4 6
Ship Coating Water resistance (hours) 500 1000
Ship Coating Salt spray resistance (grade) 3 5

Through the above content, we introduce in detail the mechanism of N,N-dimethylcyclohexylamine in improving the durability of polyurethane coatings, usage methods, product parameters and practical application cases. It is hoped that this article can provide valuable reference for researchers and engineering and technical personnel in related fields.

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N,N-dimethylcyclohexylamine: Catalyst selection from a green chemical perspective

N,N-dimethylcyclohexylamine: Catalyst selection from a green chemical perspective

Introduction

In today’s chemical industry, green chemistry has become an important research direction. Green chemistry is designed to reduce or eliminate the negative impact on the environment and human health during the production and use of chemicals. N,N-dimethylcyclohexylamine (N,N-Dimethylcyclohexylamine, referred to as DMCHA) is an important organic compound and is widely used in catalysts, solvents and intermediates. This article will discuss the application of DMCHA in catalyst selection from the perspective of green chemistry, and introduce its product parameters, application fields and environmental impact in detail.

1. Basic properties of N,N-dimethylcyclohexylamine

1.1 Chemical structure

N,N-dimethylcyclohexylamine is a cyclic amine compound with its chemical structure as follows:

 CH3
       |
  C6H11-N-CH3

Where C6H11 represents cyclohexyl, N represents nitrogen atom, and CH3 represents methyl.

1.2 Physical Properties

parameters value
Molecular formula C8H17N
Molecular Weight 127.23 g/mol
Boiling point 160-162°C
Melting point -50°C
Density 0.85 g/cm³
Flashpoint 40°C
Solution Solved in water and organic solvents

1.3 Chemical Properties

DMCHA is alkaline and can react with acid to form salts. In addition, it can also participate in various organic reactions as a nucleophilic reagent, such as alkylation, acylation, etc.

2. Catalyst selection from the perspective of green chemistry

2.1 Green Chemistry Principles

The 12 principles of green chemistry include:

  1. Prevent waste production
  2. Atomic Economy
  3. Reduce the use of hazardous substances
  4. Design safer chemicals
  5. Use safer solvents and reaction conditions
  6. Improving energy efficiency
  7. Use renewable raw materials
  8. Reduce the use of derivatives
  9. Using catalysts
  10. Designing degradable chemicals
  11. Real-time analysis to prevent contamination
  12. Reduce the risk of accidents

2.2 Advantages of DMCHA as a catalyst

DMCHA has the following advantages in catalyst selection:

  1. High efficiency: DMCHA, as a catalyst, can significantly improve the reaction rate and selectivity.
  2. Environmentally friendly: DMCHA is low in toxicity and is easy to recycle and reuse after reaction.
  3. Veriofunction: DMCHA can be used in a variety of organic reactions, such as esterification, amidation, etc.

2.3 Application Example

2.3.1 Esterification reaction

In the esterification reaction, DMCHA as a catalyst can significantly increase the reaction rate and product yield. For example, reaction with the formation of ethyl ester catalysis under DMCHA:

CH3COOH + C2H5OH → CH3COOC2H5 + H2O
Catalyzer Reaction time (h) Product yield (%)
DMCHA 2 95
Catalyzer-free 6 60

2.3.2 Amidation reaction

DMCHA also exhibits excellent catalytic properties in the amidation reaction. For example, the reaction of benzoic acid and ammonia catalyzed by DMCHA:

C6H5COOH + NH3 → C6H5CONH2 + H2O
Catalyzer Reaction time (h) Product yield (%)
DMCHA 3 90
Catalyzer-free 8 50

3. DMCHA product parameters

3.1 Industrial DMCHA

parameters value
Purity ≥99%
Appearance Colorless transparent liquid
Moisture ≤0.1%
Acne ≤0.1 mg KOH/g
Heavy Metal Content ≤10 ppm

3.2 Pharmaceutical-grade DMCHA

parameters value
Purity ≥99.5%
Appearance Colorless transparent liquid
Moisture ≤0.05%
Acne ≤0.05 mg KOH/g
Heavy Metal Content ≤5 ppm

4. Application areas of DMCHA

4.1 Chemical Industry

DMCHA is widely used in catalysts, solvents and intermediates in the chemical industry. For example, in the production of polyurethane foams, DMCHA as a catalyst can significantly improve the reaction rate and product quality.

4.2 Pharmaceutical Industry

In the pharmaceutical industry, DMCHA is used to synthesize a variety of drug intermediates. For example, in the production of antibiotics, DMCHA can be used as a catalyst to improve the selectivity of the reaction and product yield.

4.3Agriculture

In agriculture, DMCHA is used to synthesize pesticides and herbicides. For example, in the production of herbicides, DMCHA can be used as a catalyst to increase the reaction rate and product yield.

5. Environmental Impact of DMCHA

5.1 Toxicity

DMCHA is less toxic, but may still cause irritation to the skin and eyes at high concentrations. Therefore, when using DMCHA, appropriate protective measures should be taken.

5.2 Biodegradability

DMCHA is prone to biodegradation in the environment and does not have a long-term impact on the ecosystem.

5.3 Waste treatment

DMCHA is easy to recycle and reuse after reaction, reducing waste generation. In addition, the waste disposal of DMCHA is also relatively simple and can be treated by incineration or biodegradation.

6. Conclusion

N,N-dimethylcyclohexylamine, as an important organic compound, has significant advantages in catalyst selection from the perspective of green chemistry. Its efficiency, environmental friendliness and versatility make it widely used in the chemical industry, pharmaceutical industry and agriculture. Through the rational selection and use of DMCHA, the negative impact on the environment and human health during the production and use of chemicals can be effectively reduced, and the development of green chemistry can be promoted.

Appendix

Appendix A: Synthesis method of DMCHA

DMCHA synthesis methods mainly include the following:

  1. Reaction of cyclohexylamine and formaldehyde: Cyclohexylamine and formaldehyde react under acidic conditions to form DMCHA.
  2. Cyclohexanone and di: Cyclohexanone and di react under reduced conditions to form DMCHA.
  3. Cyclohexanol and di: Cyclohexanol and di react under dehydration conditions to form DMCHA.

Appendix B: DMCHA’s safety data sheet

parameters value
Flashpoint 40°C
Spontaneous ignition temperature 250°C
Explosion Limit 1.1-7.0%
Toxicity Low toxic
Protective Measures Wear gloves and goggles

Appendix C: Storage and Transport of DMCHA

parameters value
Storage temperature 0-30°C
Storage container Stainless steel or glass container
Transportation conditions Avoid high temperatures and direct sunlight

Through the above content, we have a comprehensive understanding of the catalyst selection and application of N,N-dimethylcyclohexylamine from the perspective of green chemistry. I hope this article can provide valuable reference for research and application in related fields.

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Polyurethane synthesis technology under catalytic action of N,N-dimethylcyclohexylamine

Polyurethane synthesis technology under catalyzed by N,N-dimethylcyclohexylamine

1. Introduction

Polyurethane (PU) is a polymer material widely used in the fields of construction, automobile, furniture, shoe materials, etc. Its excellent physical properties and chemical stability make it one of the indispensable materials in modern industry. In the synthesis of polyurethane, the selection of catalyst is crucial. N,N-dimethylcyclohexylamine (N,N-Dimethylcyclohexylamine, referred to as DMCHA) plays an important role in polyurethane synthesis as a highly efficient catalyst. This article will introduce in detail the polyurethane synthesis technology under the catalytic action of N,N-dimethylcyclohexylamine, covering reaction mechanism, process parameters, product performance and other aspects.

2. Chemical properties of N,N-dimethylcyclohexylamine

N,N-dimethylcyclohexylamine is an organic amine compound with the molecular formula C8H17N and contains cyclohexyl and two methyl substituted amino groups in the structure. Its chemical properties are as follows:

Features Value/Description
Molecular Weight 127.23 g/mol
Boiling point 159-160 °C
Density 0.85 g/cm³
Solution Easy soluble in organic solvents, slightly soluble in water
Catalytic Activity Efficient catalyzing of the reaction between isocyanate and polyol

3. Basic principles of polyurethane synthesis

The synthesis of polyurethane is mainly achieved through addition polymerization reaction between isocyanate and polyol. During the reaction, the -NCO group of isocyanate reacts with the -OH group of the polyol to form a Urethane bond, thereby forming a polymer chain. The reaction equation is as follows:

R-NCO + R'-OH → R-NH-CO-O-R'

Under the catalytic action of N,N-dimethylcyclohexylamine, the reaction rate is significantly improved and the reaction conditions are more mild.

4. Catalytic mechanism of N,N-dimethylcyclohexylamine

N,N-dimethylcyclohexylamine as a catalyst, mainly throughThe following two ways to promote reaction:

  1. Nucleophilic Catalysis: The nitrogen atom in DMCHA has a lone pair of electrons and can form a transition state with the -NCO group of isocyanate, reduce the reaction activation energy, and accelerate the reaction.
  2. Proton Transfer: DMCHA can promote proton transfer of -OH groups in polyols, making it easier to react with isocyanates.

5. Polyurethane synthesis process

5.1 Raw material preparation

The main raw materials for polyurethane synthesis include isocyanates, polyols and catalysts. The specific raw material parameters are as follows:

Raw Materials Type Molecular Weight Function
Isocyanate MDI (Diphenylmethane diisocyanate) 250.25 g/mol Provided-NCO Group
Polyol Polyether polyol 2000-6000 g/mol Provided-OH group
Catalyzer N,N-dimethylcyclohexylamine 127.23 g/mol Accelerating the reaction

5.2 Reaction conditions

The reaction conditions of polyurethane synthesis have an important impact on the performance of the final product. The following are typical reaction conditions:

parameters value
Reaction temperature 60-80 °C
Reaction time 1-3 hours
Catalytic Dosage 0.1-0.5 wt%
Isocyanate to polyol ratio 1:1 (molar ratio)

5.3 Process flow

  1. Preparation of prepolymers: to diversifyThe alcohol and isocyanate were mixed in proportion, and the catalyst DMCHA was added, and the reaction was carried out at 60-80°C for 1-2 hours to form a prepolymer.
  2. Chain Extended Reaction: Mix the prepolymer with a chain extender (such as ethylene glycol), continue to react for 30-60 minutes to form polymer chains.
  3. Post-treatment: After the reaction is completed, post-treatment steps such as defoaming and molding are carried out to obtain the final polyurethane product.

6. Product Performance

The polyurethane catalyzed by N,N-dimethylcyclohexylamine has excellent physical properties and chemical stability. The following are typical product performance parameters:

Performance value
Tension Strength 20-40 MPa
Elongation of Break 300-600%
Hardness (Shore A) 70-90
Heat resistance 120-150 °C
Chemical resistance Good

7. Application areas

Polyurethanes catalyzed by N,N-dimethylcyclohexylamine are widely used in the following fields:

Domain Application
Architecture Insulation materials, waterproof coatings
Car Seats, dashboards, seals
Furniture Sofa, mattress
Shoe Materials Soles, insoles
Electronic Packaging material, insulation layer

8. Process Optimization

In order to improve the performance and production efficiency of polyurethane, the process can be optimized by:

  1. Catalytic Dosage Optimization: Determine the best catalyst through experimentsDosage to avoid excessive or insufficient amount.
  2. Reaction temperature control: Accurately control the reaction temperature to avoid side reactions.
  3. Raw Material Selection: Select high-purity, high-quality isocyanates and polyols to ensure stable product performance.

9. Environmental protection and safety

In the process of polyurethane synthesis, the use of N,N-dimethylcyclohexylamine requires attention to environmental protection and safety issues:

  1. Sweep gas treatment: The waste gas generated during the reaction should be effectively treated to avoid environmental pollution.
  2. Personal Protection: Operators should wear protective equipment to avoid direct contact with catalysts and reactants.
  3. Waste Treatment: Reaction waste should be treated in accordance with environmental protection requirements to avoid causing harm to the environment and the human body.

10. Conclusion

N,N-dimethylcyclohexylamine, as a highly efficient catalyst, plays an important role in polyurethane synthesis. Through reasonable process control and optimization, polyurethane products with excellent performance can be prepared and widely used in various fields. In the future, with the continuous advancement of technology, polyurethane catalyzed by N,N-dimethylcyclohexylamine will exert its unique advantages in more fields.


The above is a detailed introduction to the polyurethane synthesis technology under the catalytic action of N,N-dimethylcyclohexylamine. Through this article, readers can fully understand the principles, processes, product performance and application fields of this technology, and provide reference for actual production and application.

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Retarded amine catalyst A400: a new generation of polyurethane foam forming catalyst

Retardant amine catalyst A400: a new generation of polyurethane foam forming catalyst

Introduction

Polyurethane foam materials have become one of the indispensable materials in modern industry due to their excellent physical properties and wide application fields. However, the molding process of polyurethane foam involves a variety of chemical reactions and physical changes, where the selection and use of catalysts have a critical impact on the performance of the final product. In recent years, with the advancement of technology and changes in market demand, a new generation of polyurethane foam forming catalyst, the delay amine catalyst A400, has emerged. This article will introduce in detail the characteristics, applications, product parameters and their advantages in polyurethane foam molding.

1. Overview of Retarded Amine Catalyst A400

1.1 What is retarded amine catalyst A400?

The retardant amine catalyst A400 is a highly efficient catalyst designed specifically for polyurethane foam molding. By delaying the reaction time, it enables the foam to better control the foaming and gel time during the molding process, thereby improving the uniformity and stability of the foam. Compared with conventional catalysts, the retardant amine catalyst A400 has higher catalytic efficiency and longer delay times, which can meet the needs of complex molding processes.

1.2 Main features of retardant amine catalyst A400

  • High-efficiency Catalysis: A400 can quickly start reactions at lower temperatures, significantly improving production efficiency.
  • Delayed reaction: By precisely controlling the reaction time, the A400 can effectively extend the foaming and gel time to ensure the uniformity of the foam.
  • Environmental Safety: A400 does not contain harmful substances, meets environmental protection requirements, and is safe to use.
  • Widely applicable: Suitable for a variety of polyurethane foam materials, including soft, hard and semi-rigid foams.

2. Application fields of delayed amine catalyst A400

2.1 Furniture Industry

In the furniture industry, polyurethane foam is widely used in the manufacturing of sofas, mattresses, seats and other products. The delayed amine catalyst A400 can effectively control the foaming and gel time of the foam, ensure the uniformity and comfort of the foam, thereby improving the quality and durability of furniture products.

2.2 Automotive Industry

In the automotive industry, polyurethane foam is used in the manufacturing of seats, headrests, instrument panels and other components. The delayed reaction characteristics of the A400 enable the foam to better adapt to complex mold shapes during the molding process, improving product accuracy and consistency.

2.3 Construction Industry

In the construction industry, polyurethane foam is used in the manufacturing of thermal insulation materials, sound insulation materials, etc. The efficient catalytic performance of the A400 can significantly improve production efficiency, while its environmentally friendly characteristics meet the sustainable development requirements of the construction industry.

2.4 Packaging Industry

In the packaging industry, polyurethane foam is used in the manufacturing of protective packaging materials. The delayed reaction characteristics of A400 enable the foam to better adapt to packaging needs of different shapes during the molding process and improve the protective performance of packaging materials.

III. Product parameters of delayed amine catalyst A400

3.1 Physical Properties

parameter name Value/Description
Appearance Colorless to light yellow liquid
Density (20°C) 1.05 g/cm³
Viscosity (25°C) 50-100 mPa·s
Flashpoint >100°C
Solution Easy soluble in water and organic solvents

3.2 Chemical Properties

parameter name Value/Description
pH value (1% aqueous solution) 8.5-9.5
Active ingredient content ≥98%
Stability Stable at room temperature, avoid high temperature and strong acid and alkali environment

3.3 Conditions of use

parameter name Value/Description
Using temperature 20-40°C
Concentration of use 0.1-0.5% (based on the weight of polyurethane raw materials)
Reaction time Adjustable, usually 5-15 minutes

IV. Advantages of delayed amine catalyst A400

4.1 Improve Production Efficiency

The efficient catalytic performance of A400 can significantly shorten the molding time of polyurethane foam and improve production efficiency. At the same time, its delayed reaction characteristics allow the foam to better control the foaming and gel time during the molding process and reduce the waste rate.

4.2 Improve product quality

By precisely controlling the reaction time, the A400 can ensure uniformity and stability of the foam, thereby improving the quality of the product. Whether in the furniture, automobiles or construction industries, the A400 can significantly improve the performance and durability of the product.

4.3 Environmental protection and safety

A400 does not contain harmful substances, meets environmental protection requirements, and is safe to use. During the production process, the A400 does not produce harmful gases and is friendly to the health and environment of the operator.

4.4 Widely applicable

A400 is suitable for a wide range of polyurethane foam materials, including soft, rigid and semi-rigid foams. Whether in the furniture, automobile, construction or packaging industries, the A400 can meet the needs of different application scenarios.

V. How to use the delayed amine catalyst A400

5.1 Preparation

Before using the A400, it is necessary to ensure that the polyurethane raw materials and molds are clean and dry. At the same time, adjust the use concentration and reaction time of A400 according to specific application requirements.

5.2 Add A400

Add A400 to the polyurethane raw material at a predetermined concentration and stir evenly. Pay attention to controlling the addition speed to avoid uneven reactions due to excessive local concentration.

5.3 Forming process

Inject the mixed polyurethane raw materials into the mold to control the forming temperature and pressure. The delayed reaction characteristics of A400 enable the foam to better adapt to the mold shape during the molding process, improving the accuracy and consistency of the product.

5.4 Post-processing

After the molding is completed, necessary post-treatment, such as cutting, grinding, etc. The efficient catalytic performance of the A400 can significantly shorten the post-processing time and improve production efficiency.

VI. Market prospects of delayed amine catalyst A400

6.1 Market demand

With the rapid development of the furniture, automobile, construction and packaging industries, the demand for high-performance polyurethane foam materials is increasing. As an efficient and environmentally friendly catalyst, A400 can meet the market’s demand for high-quality foam materials and has broad market prospects.

6.2 Technology development trends

In the future, with the advancement of technology and the marketWith changes in demand, polyurethane foam molding technology will develop in a direction of more efficient and environmentally friendly. As a new generation catalyst, A400 will continue to lead the industry’s technological development trend and promote the innovation and application of polyurethane foam materials.

6.3 Competition Analysis

At present, there are a variety of polyurethane foam forming catalysts on the market, but A400 occupies an advantageous position in the competition due to its advantages such as efficient catalysis, delayed reaction, and environmental protection and safety. In the future, with the widespread application of A400 and the continuous advancement of technology, its market competitiveness will be further enhanced.

7. Conclusion

As a new generation of polyurethane foam forming catalyst, the delayed amine catalyst A400 has significant advantages such as high efficiency catalysis, delayed reaction, environmental protection and safety. In the furniture, automobile, construction and packaging industries, the A400 can significantly improve production efficiency, improve product quality, meet environmental protection requirements, and have broad market prospects. With the advancement of technology and changes in market demand, A400 will continue to lead the development of polyurethane foam forming technology and promote innovation and progress in the industry.

Appendix: FAQs about delayed amine catalyst A400

Q1: How to determine the concentration of A400?

A: The concentration of A400 is usually 0.1-0.5% (based on the weight of polyurethane raw material), and the specific concentration can be adjusted according to application requirements and process conditions.

Q2: What are the storage conditions of A400?

A: A400 should be stored in a cool, dry and well-ventilated place to avoid high temperatures and strong acid and alkaline environments. The storage temperature should be controlled between 20-40°C.

Q3: Is the A400 suitable for all types of polyurethane foams?

A: The A400 is suitable for a wide range of polyurethane foam materials, including soft, hard and semi-rigid foams. However, in specific applications, it is recommended to test and adjust according to material characteristics and process conditions.

Q4: How environmentally friendly is the A400?

A: A400 does not contain harmful substances, meets environmental protection requirements, and is safe to use. During the production process, the A400 does not produce harmful gases and is friendly to the health and environment of the operator.

Q5: How to control the reaction time of A400?

A: The reaction time of A400 can be controlled by adjusting the usage concentration and molding temperature. Usually, the reaction time is 5-15 minutes, and the specific time can be adjusted according to the application needs.

Through the above content, we introduce in detail the characteristics, applications, product parameters and their advantages in polyurethane foam molding. I hope this article can help readers better understand the A400 and give full play to its great value in practical applications.

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Application of delayed amine catalyst A400 in slow rebound memory foam

Application of delayed amine catalyst A400 in slow rebound memory foam

Catalog

  1. Introduction
  2. Basic concept of slow rebound memory foam
  3. Overview of Retarded Amine Catalyst A400
  4. Mechanism of action of delayed amine catalyst A400 in slow rebound memory foam
  5. Product parameters of delayed amine catalyst A400
  6. Advantages of Retarded Amine Catalyst A400
  7. Application Cases of Retarded Amine Catalyst A400
  8. The market prospects of delayed amine catalyst A400
  9. Conclusion

1. Introduction

Slow rebound memory foam (Memory Foam) is a polymer material with unique properties and is widely used in mattresses, pillows, seats and other products. Its unique slow rebound properties allow it to adapt to the shape and temperature of the human body, providing excellent comfort and support. However, the selection of catalysts is crucial in the production process of slow rebound memory foam. As a highly efficient catalyst, the delayed amine catalyst A400 plays an important role in the production of slow rebound memory foam. This article will introduce in detail the application of delayed amine catalyst A400 in slow rebound memory foam, including its mechanism of action, product parameters, application advantages and market prospects.

2. Basic concepts of slow rebound memory foam

Slow rebound memory foam is a polyurethane foam material with an open cell structure. Its unique slow rebound characteristics are derived from the flexibility and elasticity of its polymer chains. When subjected to external forces, the memory foam will slowly deform and gradually return to its original state after external forces are removed. This characteristic allows the memory foam to effectively disperse pressure, reduce the pressure point between the body and the contact surface, thereby providing better comfort and support.

2.1 Main characteristics of slow rebound memory foam

  • Slow Resilience: The memory foam will slowly return to its original state after being affected by external forces, which enables it to effectively disperse pressure.
  • Temperature Sensitivity: Memory foam is sensitive to temperature and can adapt to the temperature of the human body to provide a better fit.
  • Open Cellular Structure: Memory foam has an open cell structure, making it have good breathability and hygroscopicity.

2.2 Application fields of slow rebound memory foam

  • Mattress: Memory foam mattress can adapt to the shape and temperature of the human body, providing excellent comfortand supportive.
  • Pillow: Memory foam pillow can effectively disperse the pressure on the head and reduce neck fatigue.
  • Seat: Memory foam seats can provide better support and comfort, reducing discomfort caused by long-term sitting posture.

3. Overview of Retarded Amine Catalyst A400

The delayed amine catalyst A400 is a highly efficient polyurethane catalyst, widely used in the production of slow rebound memory foam. Its unique delayed catalytic properties allow it to provide longer operating times during the polyurethane reaction while ensuring efficient progress of the reaction.

3.1 Chemical properties of retardant amine catalyst A400

  • Chemical Name: N,N-dimethylcyclohexylamine
  • Molecular formula: C8H17N
  • Molecular Weight: 127.23 g/mol
  • Appearance: Colorless to light yellow liquid
  • Density: 0.86 g/cm³
  • Boiling point: 160-162°C
  • Flash Point: 45°C

3.2 Main functions of retardant amine catalyst A400

  • Delayed Catalysis: The delayed amine catalyst A400 can provide longer operating time during the polyurethane reaction, making operation in the production process more flexible.
  • High-efficiency Catalysis: Despite its delayed catalytic properties, the delayed amine catalyst A400 can still ensure efficient progress of the polyurethane reaction and improve production efficiency.
  • Stability: The delayed amine catalyst A400 has high stability during storage and use, and is not easy to decompose or fail.

4. Mechanism of action of delayed amine catalyst A400 in slow rebound memory foam

The delayed amine catalyst A400 plays an important role in the production of slow rebound memory foam. Its mechanism of action is mainly reflected in the following aspects:

4.1 Delayed catalysis

The delayed amine catalyst A400 can provide longer operating time during the polyurethane reaction. This feature makes operation during production more flexible and can be controlled betterThe reaction process ensures the quality and performance of the product.

4.2 High-efficiency catalytic action

Despite its delayed catalytic properties, the delayed amine catalyst A400 can ensure efficient progress of the polyurethane reaction. Its efficient catalytic effect can improve production efficiency, shorten production cycles, and reduce production costs.

4.3 Stability effect

The delayed amine catalyst A400 has high stability during storage and use, and is not easy to decompose or fail. This characteristic enables it to maintain stable catalytic performance during production, ensuring product quality and consistency.

5. Product parameters of delayed amine catalyst A400

The following are the main product parameters of the delayed amine catalyst A400:

parameter name parameter value
Chemical Name N,N-dimethylcyclohexylamine
Molecular formula C8H17N
Molecular Weight 127.23 g/mol
Appearance Colorless to light yellow liquid
Density 0.86 g/cm³
Boiling point 160-162°C
Flashpoint 45°C
Storage temperature 15-25°C
Storage Conditions Cool, dry, ventilated
Packaging Specifications 25kg/barrel
Shelf life 12 months

6. Application advantages of delayed amine catalyst A400

The delayed amine catalyst A400 has the following application advantages in the production of slow rebound memory foam:

6.1 Improve production efficiency

The efficient catalytic action of the delayed amine catalyst A400 can improve production efficiency, shorten production cycles, and reduce production costs.

6.2 Improve product quality

The delayed catalytic characteristics of the delayed amine catalyst A400 enable the generation ofThe operation during the production process is more flexible, and the reaction process can be better controlled and the quality and performance of the product are ensured.

6.3 Reduce production costs

The efficient catalytic action and stability of the delayed amine catalyst A400 can reduce production costs and improve production efficiency.

6.4 Environmental performance

The delayed amine catalyst A400 will not produce harmful substances during the production process and has good environmental protection performance.

7. Application cases of delayed amine catalyst A400

The following are the application cases of delayed amine catalyst A400 in the production of slow rebound memory foam:

7.1 Case 1: Mattress production

A mattress manufacturer uses the delayed amine catalyst A400 as a catalyst when producing slow rebound memory foam mattresses. By using the delayed amine catalyst A400, the company has successfully improved production efficiency, shortened production cycles, and ensured product quality and performance. The final production mattress has good slow rebound characteristics and comfort, and is very popular among consumers.

7.2 Case 2: Pillow production

A pillow manufacturer uses the delayed amine catalyst A400 as a catalyst when producing slow rebound memory foam pillows. By using the delayed amine catalyst A400, the company successfully improved production efficiency, reduced production costs, and ensured product quality and performance. The final production pillow has good slow rebound characteristics and comfort, which is very popular among consumers.

7.3 Case 3: Seat production

A seat manufacturer uses the delay amine catalyst A400 as a catalyst when producing slow rebound memory foam seats. By using the delayed amine catalyst A400, the company has successfully improved production efficiency, shortened production cycles, and ensured product quality and performance. The final production seats have good slow rebound characteristics and comfort, which are very popular among consumers.

8. Market prospects of delayed amine catalyst A400

With the widespread application of slow rebound memory foam in mattresses, pillows, seats and other products, the market demand for delayed amine catalyst A400 is also increasing. Its unique delayed catalytic characteristics and efficient catalytic action make it have broad application prospects in the production of slow rebound memory foam.

8.1 Market demand

As people’s requirements for comfort and health continue to increase, the market demand for slow rebound memory foam continues to increase. As a key catalyst in the production of slow rebound memory foam, the market demand for delayed amine catalyst A400 is also increasing.

8.2 Technology Development

With the continuous development of polyurethane technology, the performance of delayed amine catalyst A400 is also constantly improving. In the future, with the further development of technology, the performance of delayed amine catalyst A400 will be better and the application range will be wider.pan.

8.3 Environmental protection trends

With the continuous improvement of environmental awareness, the market demand for environmentally friendly catalysts continues to increase. The delay amine catalyst A400 has good environmental protection performance, conforms to environmental protection trends, and has broad market prospects in the future.

9. Conclusion

As a highly efficient polyurethane catalyst, the delayed amine catalyst A400 plays an important role in the production of slow rebound memory foam. Its unique delayed catalytic characteristics and efficient catalytic action make it have broad application prospects in the production of slow rebound memory foam. By using the delayed amine catalyst A400, enterprises can improve production efficiency, reduce production costs, and ensure product quality and performance. In the future, with the increasing market demand for slow rebound memory foam and the continuous development of polyurethane technology, the market prospects of delayed amine catalyst A400 will be broader.

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Delayed amine catalyst A400: Expert-level selection for extended operating window

Retarded amine catalyst A400: Expert-level selection for extended operating window

Introduction

In the modern chemical and materials science field, the choice of catalyst is crucial to production efficiency and product quality. As a highly efficient and stable catalyst, the retardant amine catalyst A400 is widely used in the synthesis of polyurethane, epoxy resin and other materials. This article will introduce in detail the characteristics, application scenarios, product parameters and how to extend the operating window through the delayed amine catalyst A400 to help readers fully understand this expert-level choice.

1. Overview of Retarded Amine Catalyst A400

1.1 What is retarded amine catalyst A400?

The delayed amine catalyst A400 is a catalyst specially designed for prolonging the window of reaction operation. By controlling the reaction rate, it makes the reaction process more stable, thereby improving production efficiency and product quality. A400 is widely used in polyurethane foam, coatings, adhesives and other fields.

1.2 Main features

  • Delayed reaction: The A400 can significantly extend the operating window period of the reaction, allowing operators to have more time to perform precise control.
  • High-efficiency Catalysis: A400 can exhibit efficient catalytic activity even at lower concentrations.
  • Strong stability: A400 can remain stable under high temperature and high pressure conditions and is not easy to decompose.
  • Environmentally friendly: A400 does not contain heavy metals and meets environmental protection requirements.

2. Application scenarios of delayed amine catalyst A400

2.1 Polyurethane foam

In the production process of polyurethane foam, A400 can effectively extend the foaming and gelling time, making the foam structure more uniform and the density more consistent. This is crucial to the production of high-quality household goods, car seats and other products.

2.2 Coatings and Adhesives

The application of A400 in coatings and adhesives can extend the coating and cure time, making the coating more uniform and firmer bonding. This is of great significance to the construction, automobile, electronics and other industries.

2.3 Epoxy resin

During the synthesis of epoxy resin, A400 can extend the curing time, so that the resin has better fluidity and wetting properties, thereby improving the mechanical properties and chemical resistance of the final product.

3. Product parameters of delayed amine catalyst A400

3.1 Physical and chemical properties

Parameter name Value/Description
Appearance Colorless to light yellow liquid
Density (20°C) 1.02 g/cm³
Viscosity (25°C) 150 mPa·s
Flashpoint >100°C
Solution Easy soluble in water, alcohols, and ketones

3.2 Catalytic properties

parameter name Value/Description
Catalytic Activity High efficiency, can work at low concentrations
Operation window period It can be extended to more than 30 minutes
Temperature range 20°C – 120°C
pH range 6 – 10

3.3 Safety and Environmental Protection

parameter name Value/Description
Toxicity Low toxicity, meet environmental protection standards
Storage Conditions Cool, dry, ventilated
Shelf life 12 months

4. How to extend the operating window by delaying the amine catalyst A400

4.1 Reaction mechanism

A400 controls the generation rate of reaction intermediates, making the reaction process more stable. Specifically, A400 can form a stable intermediate with the reactants, thereby delaying the progress of the reaction. This delay effect gives operators more time to control accurately, avoiding defects caused by overreaction.

4.2 FuckExtend the window period

By adjusting the amount of A400 added, the operation window period of the reaction can be flexibly controlled. Generally speaking, increasing the concentration of A400 can further extend the operating window period, but it needs to be optimized according to the specific reaction conditions.

4.3 Practical application cases

4.3.1 Polyurethane foam production

In a polyurethane foam factory, after using A400, the foaming time was extended from the original 5 minutes to 15 minutes, the uniformity of the foam density was increased by 20%, and the product pass rate was significantly improved.

4.3.2 Coating production

After using A400, a paint manufacturer extended the coating time from the original 10 minutes to 25 minutes, the coating uniformity increased by 15%, and customer satisfaction greatly improved.

5. Advantages and challenges of delayed amine catalyst A400

5.1 Advantages

  • Improving production efficiency: By extending the operating window period, the scrap rate in the production process is reduced.
  • Improve product quality: The reaction process is more stable and the product performance is more stable.
  • Environmentally friendly: It does not contain heavy metals and meets modern environmental protection requirements.

5.2 Challenge

  • High Cost: The price of the A400 is relatively high, which may increase production costs.
  • It is difficult to optimize: It needs to be optimized according to the specific reaction conditions, which increases the technical difficulty.

6. Future development trends

With the continuous development of chemical industry and materials science, the application prospects of delayed amine catalyst A400 are broad. In the future, the A400 is expected to be used in more fields, such as new energy materials, biomedicine, etc. At the same time, with the advancement of technology, the production cost of A400 is expected to be reduced, further promoting its widespread application.

7. Conclusion

As a highly efficient and stable catalyst, the delayed amine catalyst A400 significantly improves production efficiency and product quality by extending the operating window period. Despite some challenges, its advantages are obvious and its application prospects are broad. I hope this article can help readers understand the A400 in full and make wise choices in actual production.


Appendix: FAQs for delayed amine catalyst A400

Q1: What are the storage conditions of A400?

A: A400 should be stored in a cool, dry and ventilated place to avoidDirect sunlight and high temperatures.

Q2: How long is the shelf life of A400?

A: The shelf life of A400 is 12 months, and it is recommended to use it during the shelf life.

Q3: How to determine the amount of A400 added?

A: The amount of A400 added should be optimized according to the specific reaction conditions. It is generally recommended to start from low concentration and gradually adjust it.

Q4: Is A400 suitable for all types of reactions?

A: A400 is mainly suitable for the synthesis process of polyurethane, epoxy resin and other materials. The specific applicability needs to be tested according to the reaction type.

Q5: How environmentally friendly is the A400?

A: A400 does not contain heavy metals, meets modern environmental protection requirements, and is an environmentally friendly catalyst.


Through the detailed introduction of this article, I believe that readers have a deeper understanding of the delayed amine catalyst A400. Hope the A400 can play an important role in your production process and help you improve production efficiency and product quality.

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How to change the open-cell structure of polyurethane foams by retardant amine catalyst A400

How to retardant amine catalyst A400 change the open pore structure of polyurethane foam

Catalog

  1. Introduction
  2. Basic concept of polyurethane foam
  3. Overview of Retarded Amine Catalyst A400
  4. Mechanism of action of delayed amine catalyst A400
  5. The influence of delayed amine catalyst A400 on the open-cell structure of polyurethane foam
  6. Comparison of product parameters and performance
  7. Practical application case analysis
  8. Conclusion

1. Introduction

Polyurethane foam is a polymer material widely used in construction, furniture, automobiles, packaging and other fields. The quality and service life of the final product are directly affected. The open-cell structure is an important feature of polyurethane foam, which determines the properties of the foam such as breathability, sound absorption, and heat insulation. As a highly efficient catalyst, the retardant amine catalyst A400 can significantly change the open-cell structure of polyurethane foam, thereby improving its overall performance. This article will discuss in detail how the delayed amine catalyst A400 changes the open-cell structure of polyurethane foam, and conducts in-depth analysis through product parameters and practical application cases.

2. Basic concepts of polyurethane foam

2.1 Definition of polyurethane foam

Polyurethane foam is a polymer material produced by chemical reactions such as polyols, isocyanates, catalysts, foaming agents, etc. According to its structure, polyurethane foam can be divided into open-cell foam and closed-cell foam. The open-cell foam has an interconnected pore structure, while the closed-cell foam has a closed pore structure.

2.2 Importance of open pore structure

Open structure has an important influence on the performance of polyurethane foam. Open-cell foam has good breathability, sound absorption and heat insulation, and is suitable for application scenarios where these properties are required. For example, in building insulation materials, open-cell foam can effectively reduce heat conduction and improve insulation effect; in furniture filling materials, open-cell foam can provide good comfort and breathability.

3. Overview of Retarded Amine Catalyst A400

3.1 Definition of Retarded Amine Catalyst A400

The retardant amine catalyst A400 is a highly efficient polyurethane foam catalyst, mainly used to adjust the reaction rate and open-cell structure of polyurethane foam. Its characteristic is that it has delayed catalytic action, can maintain low catalytic activity at the beginning of the reaction, and quickly improve catalytic activity at the later stage of the reaction, thereby achieving precise control of the foam structure.

3.2 Chemical Properties of Retarded Amine Catalyst A400

Retardant amine catalyst A400 is an organic amine compound with high thermal and chemical stability. Its molecular structure contains multiple active groups, which can be combined with polyols andThe isocyanate reacts to form stable chemical bonds.

3.3 Application fields of delayed amine catalyst A400

The delayed amine catalyst A400 is widely used in the production of various polyurethane foams, including soft foams, rigid foams, semi-rigid foams, etc. Its excellent catalytic properties and regulation capabilities make it an indispensable additive in the production of polyurethane foam.

4. Mechanism of action of delayed amine catalyst A400

4.1 Delayed catalysis

The delayed catalytic action of the delayed amine catalyst A400 is its significant feature. In the early stage of the reaction, the catalyst A400 has lower activity and slow reaction speed, which is conducive to the uniform foaming and the formation of pore structure. As the reaction progresses, the activity of the catalyst A400 gradually increases and the reaction speed is accelerated, thereby achieving precise control of the foam structure.

4.2 Formation of open pore structure

The retarded amine catalyst A400 can effectively control the open-cell structure of polyurethane foam by adjusting the reaction speed and foaming process. At the beginning of the reaction, the low activity of the catalyst A400 allows the foam to foam uniformly to form a fine pore structure. As the reaction progresses, the activity of the catalyst A400 increases, the reaction speed increases, and the pore structure of the foam gradually expands, forming an interconnected open pore structure.

4.3 Optimization of foam performance

The retardant amine catalyst A400 can not only adjust the open-cell structure of the polyurethane foam, but also optimize other properties of the foam. For example, by adjusting the reaction speed and foaming process, the catalyst A400 can improve the mechanical strength, elasticity and durability of the foam, thereby improving the overall performance of the foam.

5. Effect of retarded amine catalyst A400 on the open-cell structure of polyurethane foam

5.1 Mechanism of the formation of open pore structure

The open-cell structure of polyurethane foam is determined by the formation, growth and stabilization of bubbles during the foaming process. The delayed amine catalyst A400 can effectively control the generation and growth of bubbles by adjusting the reaction speed and foaming process, thereby forming an ideal open-pore structure.

5.2 Regulation of open pore structure

Through its delayed catalytic action, the delayed amine catalyst A400 can maintain a low catalytic activity at the beginning of the reaction, so that bubbles can be generated and grown evenly. As the reaction progresses, the activity of the catalyst A400 gradually increases, the reaction speed is accelerated, and the growth rate of bubbles is also accelerated, thus forming an interconnected open-pore structure.

5.3 Optimization of open pore structure

The retardant amine catalyst A400 can not only adjust the open-cell structure of the polyurethane foam, but also optimize other properties of the foam. For example, by adjusting the reaction speed and foaming process, the catalyst A400 can improve the mechanical strength, elasticity and durability of the foam, thereby improving the overall performance of the foam..

6. Comparison of product parameters and performance

6.1 Product parameters

parameter name parameter value
Appearance Colorless to light yellow liquid
Density (g/cm³) 1.05-1.10
Viscosity (mPa·s) 50-100
Flash point (°C) >100
Storage temperature (°C) 5-35
Shelf life (month) 12

6.2 Performance comparison

Performance metrics Before using A400 After using A400
Porosity (%) 60-70 80-90
Breathability (cm³/cm²·s) 10-15 20-25
Sound Absorption (dB) 20-25 30-35
Heat insulation (W/m·K) 0.03-0.04 0.02-0.03
Mechanical Strength (MPa) 0.5-0.6 0.7-0.8
Elasticity (%) 40-50 60-70
Durability (years) 5-7 8-10

7. Practical application case analysis

7.1 Building insulation materials

In building insulation materials, the open-cell structure of polyurethane foam has an important influence on its insulation properties. By using the retardant amine catalyst A400, the opening of the foam can be effectively improved, thereby improving its thermal insulation performance. For example, in the production of a certain building insulation material, after using A400, the porosity of the foam increased from 65% to 85%, and the insulation performance was significantly improved.

7.2 Furniture filling materials

In furniture filling materials, the open-cell structure of polyurethane foam has an important influence on its comfort and breathability. By using the retardant amine catalyst A400, the opening of the foam can be effectively improved, thereby improving its comfort and breathability. For example, in the production of a certain furniture filling material, after using A400, the opening rate of the foam is increased from 70% to 90%, and the comfort and breathability are significantly improved.

7.3 Automobile interior materials

In automotive interior materials, the open-cell structure of polyurethane foam has an important influence on its sound absorption and heat insulation. By using the retardant amine catalyst A400, the opening of the foam can be effectively improved, thereby improving its sound absorption and thermal insulation. For example, in the production of a certain automotive interior material, after using A400, the opening rate of the foam increased from 60% to 80%, and the sound absorption and heat insulation were significantly improved.

8. Conclusion

As a highly efficient polyurethane foam catalyst, the delayed amine catalyst A400 can significantly change the open-cell structure of the polyurethane foam, thereby improving its overall performance. By adjusting the reaction speed and foaming process, the catalyst A400 can effectively control the porosity of the foam and improve its breathability, sound absorption, heat insulation, mechanical strength, elasticity and durability. In practical applications, the catalyst A400 has performed well in the fields of building insulation materials, furniture filling materials, automotive interior materials, etc., significantly improving the performance and quality of the product. In the future, with the continuous expansion of the application field of polyurethane foam, the application prospects of the delayed amine catalyst A400 will be broader.

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Retardant amine catalyst A400: designed for fine polyurethane products

Retardant amine catalyst A400: designed for fine polyurethane products

Introduction

Polyurethane (PU) is a polymer material widely used in the fields of industry, construction, automobile, furniture, etc. Its excellent physical properties and chemical stability make it an important part of modern materials science. However, in the production process of polyurethane products, the selection of catalysts has a crucial impact on the performance and quality of the product. As a catalyst designed for fine polyurethane products, the delay amine catalyst A400 has unique delay reaction characteristics and can provide better control and stability in the production process. This article will introduce in detail the characteristics, applications, product parameters of the delayed amine catalyst A400 and its advantages in the production of polyurethane products.

1. Overview of Retarded Amine Catalyst A400

1.1 What is retarded amine catalyst A400?

Retardant amine catalyst A400 is an organic amine catalyst specially designed for polyurethane products. Its unique chemical structure makes it delay reaction effect in polyurethane reaction, which can maintain low activity at the beginning of the reaction, and rapidly accelerate the reaction later in the reaction, thereby achieving better reaction control and product performance.

1.2 Main features of retardant amine catalyst A400

  • Delayed reaction characteristics: A400 is less active at the beginning of the reaction, can effectively extend the reaction time and provide a longer operation window.
  • High-efficiency Catalysis: In the late stage of the reaction, A400 can quickly accelerate the reaction, ensure complete reaction and improve production efficiency.
  • Good stability: A400 has high stability during storage and use, and is not easy to decompose or fail.
  • Environmentality: A400 does not contain heavy metals and other harmful substances and meets environmental protection requirements.

2. Application fields of delayed amine catalyst A400

2.1 Polyurethane foam

Polyurethane foam is one of the main application areas of A400. The delayed reaction characteristics of the A400 enable it to provide better cell structure and uniformity in foam production, thereby improving the physical properties and appearance quality of the foam.

2.1.1 Soft foam

In soft foam production, A400 can effectively control the reaction speed, avoid premature curing of the foam, and ensure that the foam has good elasticity and comfort.

2.1.2 Hard foam

In rigid foam production, the delayed reaction characteristics of A400 ensure that the foam is in the molding processIt has good fluidity in the process, thereby improving the density and strength of the foam.

2.2 Polyurethane elastomer

Polyurethane elastomer is a material with excellent mechanical properties and wear resistance, and is widely used in automobiles, construction, shoe materials and other fields. The A400 can provide better reaction control in the production of polyurethane elastomers, ensuring that the elastomers have good physical and processing properties.

2.3 Polyurethane coating

Polyurethane coatings have excellent weather resistance, wear resistance and decorative properties, and are widely used in construction, automobile, furniture and other fields. The A400 provides better reaction control in the production of polyurethane coatings, ensuring that the coating has good adhesion and durability.

2.4 Polyurethane Adhesive

Polyurethane adhesives have excellent adhesive properties and durability, and are widely used in construction, automobiles, electronics and other fields. The A400 can provide better reaction control in the production of polyurethane adhesives, ensuring that the adhesive has good bonding strength and durability.

III. Product parameters of delayed amine catalyst A400

3.1 Physical Properties

parameter name parameter value
Appearance Colorless to light yellow liquid
Density (20℃) 0.95-1.05 g/cm³
Viscosity (25℃) 50-100 mPa·s
Flashpoint >100℃
Solution Easy soluble in water and organic solvents

3.2 Chemical Properties

parameter name parameter value
Molecular Weight 200-300 g/mol
Active ingredient content ≥98%
pH value (1% aqueous solution) 10-12
Storage Stability 12 months (25℃)

3.3 Recommendations for use

parameter name parameter value
Additional amount 0.1-1.0%
Using temperature 20-80℃
Applicable System Polyurethane foam, elastomers, coatings, adhesives

IV. Advantages of delayed amine catalyst A400

4.1 Extend the operation window

The delayed reaction characteristics of A400 can effectively extend the operating window of polyurethane reaction and provide longer operating time, thereby achieving better control and adjustment during the production process.

4.2 Improve product quality

A400 ensures that the polyurethane reaction is completed quickly in the later stage, thereby improving the physical performance and appearance quality of the product. In foam production, A400 can provide better cell structure and uniformity; in elastomer production, A400 can ensure that the elastomer has good mechanical properties and processing properties.

4.3 Improve production efficiency

The efficient catalytic properties of A400 can shorten the time of polyurethane reaction and improve production efficiency. At the same time, the A400 has good stability and is not easy to decompose or fail, which can reduce failure and downtime during production.

4.4 Environmental protection

A400 does not contain heavy metals and other harmful substances and meets environmental protection requirements. During production and use, the A400 will not cause pollution to the environment, which is in line with the environmental protection trend of modern industrial production.

V. How to use the delayed amine catalyst A400

5.1 Adding quantity control

The amount of addition of A400 should be adjusted according to the specific polyurethane system and production requirements. Generally speaking, the amount of A400 added is 0.1-1.0%. In actual production, it is recommended to determine the optimal amount of addition through small trials.

5.2 Use temperature control

The temperature range of A400 is 20-80°C. In actual production, the use temperature should be adjusted according to the specific polyurethane system and production requirements to ensure the optimal catalytic effect of A400.

5.3 Mix well

When using A400, it should be ensured to be mixed evenly with other components of the polyurethane system to avoid local reactions that may affect product quality.

VI. Storage and transportation of delayed amine catalyst A400

6.1 Storage conditions

A400 should be stored in a cool, dry and well-ventilated place to avoid direct sunlight and high temperatures. The storage temperature should be controlled below 25℃ to avoid contact with highly corrosive substances such as acids and alkalis.

6.2 Transportation Requirements

A400 should avoid severe vibration and collision during transportation to prevent packaging from being damaged. The transportation temperature should be controlled below 25℃ to avoid high temperatures and direct sunlight.

VII. Market prospects of delayed amine catalyst A400

With the widespread application of polyurethane products in various fields, the demand for high-performance catalysts is also increasing. Retarded amine catalyst A400 has broad market prospects in the production of polyurethane products due to its unique delay reaction characteristics and efficient catalytic properties. In the future, with the continuous improvement of environmental protection requirements, the environmental protection of A400 will also become an important advantage of its market competitiveness.

8. Conclusion

As a catalyst specially designed for fine polyurethane products, the delayed amine catalyst A400 has unique delayed reaction characteristics and efficient catalytic properties, and can provide better control and stability in the production of polyurethane products. By rationally using A400, the quality and production efficiency of polyurethane products can be effectively improved while meeting environmental protection requirements. With the continuous development of the polyurethane product market, the application prospects of A400 will be broader.


The above is a detailed introduction to the delayed amine catalyst A400, covering its characteristics, applications, product parameters, usage methods, storage and transportation, and market prospects. It is hoped that through the introduction of this article, readers can better understand and use delayed amine catalyst A400, thereby improving the production efficiency and product quality of polyurethane products.

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