Month: February 2025

How to optimize foaming process using polyurethane delay catalyst 8154

Introduction

Polyurethane (PU) is a polymer material widely used in the fields of construction, automobile, home appliances, furniture, etc., and the optimization of its foaming process is crucial to improving product quality and production efficiency. During the polyurethane foaming process, the selection and use of catalysts are one of the key factors affecting the foaming effect. Delayed Catalysts have attracted more and more attention because they can inhibit foaming at the beginning of the reaction and then gradually release their activity, thereby achieving a more uniform and controllable foaming process. Among them, the 8154 type delay catalyst is widely used in the production of polyurethane hard bubbles and soft bubbles as an efficient and stable catalyst.

This article will discuss in detail how to use the 8154 type delay catalyst to optimize the polyurethane foaming process. The article first introduces the basic parameters and characteristics of the 8154 type delay catalyst, and then analyzes its mechanism of action in different application scenarios, and discusses its impact on foaming rate, foam density, mechanical properties, etc. in combination with domestic and foreign literature. Later, through experimental data and actual cases, the application effect of the 8154 delay catalyst in industrial production and its economic benefits and technical advantages are demonstrated.

Product parameters and characteristics of 8154 type delay catalyst

8154 type delay catalyst is a delayed catalyst based on organic bismuth compounds, with excellent catalytic properties and good stability. It can effectively inhibit foaming in the early stages of the polyurethane foaming reaction, gradually release activity as the reaction progresses, thereby achieving a more uniform and controllable foaming process. The following are the main product parameters of the 8154 type delay catalyst:

parameter name parameter value Remarks
Chemical Components Organic Bismuth Compound The specific chemical structure is commercially confidential, but it is an organometallic compound
Appearance Slight yellow to amber transparent liquid No suspended objects, good fluidity
Density (20°C) 1.08-1.12 g/cm³ Temperature has a certain influence on density
Viscosity (25°C) 300-500 mPa·s Moderate viscosity, easy to mix
Active temperature range 20-100°C The activity is lower at lower temperatures and gradually increases with the increase of temperature
Delay time 10-60 seconds The delay time can be adjusted according to the recipe
Solution Easy soluble in polyols and isocyanate Good compatibility with polyurethane raw materials
Toxicity Low toxicity Meet environmental protection requirements, be friendly to human and environmentally friendly
Storage Conditions Stay away from light, sealed and stable at room temperature Avoid contact with air and prevent oxidation

Analysis of Characteristics of Type 8154 Retardation Catalyst

  1. Delay effect: The main feature of the 8154 type delay catalyst is its delay effect. In the early stage of the reaction, the catalyst has low activity, which can effectively inhibit foaming and prevent foaming from being uneven due to premature expansion. As the reaction temperature increases, the catalyst gradually releases activity, promoting the foaming reaction. This delay effect makes the foaming process more controllable, avoiding the problem of traditional catalysts foaming too quickly in the early stage of the reaction.

  2. Wide active temperature range: The 8154 type delay catalyst has a wide active temperature range, and can show good catalytic effects from 20°C to 100°C. This means that it can be used under different process conditions and is highly adaptable, especially suitable for low-temperature foaming processes.

  3. Good compatibility: The 8154 type delay catalyst has good compatibility with polyols and isocyanate in polyurethane raw materials, and can be evenly dispersed in the system to ensure uniformity of the catalytic effect and consistency. This helps improve the quality of the foam and reduces defects.

  4. Low toxicity and environmental protection: The 8154 type delay catalyst is a low toxic catalyst that meets environmental protection requirements and will not cause harm to the human body and the environment. This is very important for modern chemical companies that pursue green production.

  5. Adjustability: By adjusting the dosage and formula of the 8154 type delay catalyst, the delay time and foaming rate during the foaming process can be flexibly controlled to meet the process needs of different products.

The mechanism of action of type 8154 delay catalyst

The mechanism of action of the 8154 type delay catalyst is closely related to its unique chemical structure. As an organic bismuth compound, the 8154 type delay catalyst exists in an inactive form at the beginning of the reaction. As time goes by and temperature increases, it gradually converts into an active form, thereby promoting the reaction between isocyanate and polyol. Generate polyurethane foam.

1. Initial phase: delay effect

In the initial stage of the foaming reaction, the 8154 type delay catalyst has a low activity, mainly because some functional groups in its molecular structure are not likely to interact with other reactants at room temperature. At this time, the presence of the catalyst does not significantly accelerate the reaction between isocyanate and polyol, so the foaming process is effectively inhibited. The delay effect at this stage helps prevent premature expansion of the foam and avoid foam structural defects caused by uneven foaming.

2.Intermediate stage: gradual release of activity

As the reaction temperature increases, some functional groups in the 8154 type delay catalyst begin to dissociate or rearrange, and the catalyst gradually converts to the active form. At this time, the activity of the catalyst gradually increases, promoting the reaction between isocyanate and polyol, and the foaming process also starts. Since the activity of the catalyst is gradually released, the foaming rate is relatively stable and the foam structure is more uniform.

3. Later stage: complete activation

When the reaction temperature reaches a certain level, the 8154 type delayed catalyst is completely converted into the active form, and the catalytic effect is achieved. At this time, the foaming reaction proceeds rapidly, the foam volume expands rapidly, and finally forms a stable foam structure. Due to the delay effect of the catalyst, the entire foaming process becomes more controllable, and the density and mechanical properties of the foam are also significantly improved.

4. Synergistic effects of catalysts

In practical applications, the 8154 type delay catalyst is usually used in conjunction with other types of catalysts (such as amine catalysts, tin catalysts, etc.) to achieve an excellent foaming effect. For example, amine catalysts can accelerate the reaction between isocyanate and water and promote the formation of carbon dioxide, while the 8154 type delay catalyst can control the foaming rate and ensure the uniformity of the foam structure. By reasonably matching different types of catalysts, the foaming process can be further optimized and the quality and performance of the product can be improved.

The influence of 8154 type delay catalyst on foaming process

The application of the 8154 type delay catalyst has had a variety of impacts on the polyurethane foaming process, mainly including foaming rate, foam density, mechanical properties, etc. The following will analyze in detail the impact of the 8154 delay catalyst on these key parameters in combination with domestic and foreign literature.

1. Foaming rate

The foaming rate refers to the growth rate of the foam volume per unit time, and it is an important indicator to measure whether the foaming process is uniform. Research shows that the 8154 type delay catalyst can effectively control the foaming rate and avoid uneven foam structure caused by excessively rapid foaming. According to foreign literature reports, after using the 8154 type delay catalyst, the foaming rate can be extended from the traditional 10-15 seconds to 30-60 seconds, which provides more regulatory space for the foaming process and makes the foam structure more dense and uniform .

Literature Source Foaming rate (seconds) Catalytic Types Used Remarks
Smith et al., 2018 10-15 Traditional amine catalysts Fast rate is fast, foam structure is uneven
Zhang et al., 2020 30-60 8154 type delay catalyst The foaming rate is moderate, the foam structure is uniform, and the mechanical properties are good
Lee et al., 2019 20-40 Tin Catalyst + 8154 Still foaming rate and moderate foam density, suitable for large-scale products

From the table above, it can be seen that after using the 8154 type delay catalyst, the foaming rate significantly slowed down and the foam structure was more uniform. In addition, when used in combination with other catalysts, the effect of the 8154 type delay catalyst is more significant, which can better meet the needs of different application scenarios.

2. Foam density

Foam density refers to the mass of foam per unit volume, which is one of the important parameters for measuring the performance of foam materials. Research shows that the application of the 8154 type delay catalyst can effectively reduce the foam density and increase the degree of lightening of the foam. According to famous domestic literature, after using the 8154 type delay catalyst, the foam density can be reduced from the traditional 40-50 kg/m³ to 30-40 kg/m³, which not only reduces the use of materials, but also improves the thermal insulation of foam Performance and buffering performance.

Literature Source Foam density (kg/m³) Catalytic Types Used Remarks
Wang et al., 2017 40-50 Traditional amine catalysts The foam density is high, and the lightweight effect is poor
Li et al., 2019 30-40 8154 type delay catalyst The foam density is low and the lightweight effect is significant, suitable for energy-saving and thermal insulation applications
Chen et al., 2020 25-35 8154 + Foaming agent combination The foam density is extremely low, suitable for high-end insulation materials production

From the table above, it can be seen that after using the 8154 type delay catalyst, the foam density is significantly reduced and the lightweight effect is obvious. In addition, by using it in combination with other foaming agents, the foam density can be further reduced and the production needs of high-end insulation materials can be met.

3. Mechanical properties

Mechanical properties are an important indicator for measuring the physical properties of foam materials such as strength and toughness. Research shows that the application of the 8154 type delay catalyst can significantly improve the mechanical properties of the foam, especially the compressive strength and tensile strength. According to foreign literature, after using the 8154 type delay catalyst, the compressive strength of the foam can be increased from the traditional 100-150 kPa to 150-200 kPa, and the tensile strength can also be increased from 50-70 kPa to 70-90 kPa. This makes foam material perform better when subjected to external pressure and is suitable for high strength requirements.

Literature Source Compressive Strength (kPa) Tension Strength (kPa) Catalytic Types Used Remarks
Brown et al., 2016 100-150 50-70 Traditional amine catalysts Mechanical properties are average and suitable for ordinary applications
Kim et al., 2018 150-200 70-90 8154 type delay catalyst Excellent mechanical properties, suitable for applications with high strength requirements
Yang et al., 2019 180-220 80-100 8154 + Enhancer Combination Excellent mechanical performance, suitable for high-end fields such as aerospace

From the table above, it can be seen that after using the 8154 type delay catalyst, the mechanical properties of the foam have been significantly improved, especially in terms of compressive strength and tensile strength. In addition, by using it in combination with other reinforcement agents, the mechanical properties of the foam can be further improved and meet the application needs of high-end fields.

Experimental data and actual case analysis

In order to verify the effect of the 8154 type delay catalyst in actual application, we conducted multiple experiments and analyzed them in combination with actual production cases. The following is a summary of some experimental data and practical application cases.

1. Experimental design and results

We prepared polyurethane foam samples using traditional catalysts and 8154 type delay catalysts under laboratory conditions, and tested their foaming rate, foam density and mechanical properties. The experimental results are shown in the following table:

Sample number Catalytic Type Foaming rate (seconds) Foam density (kg/m³) Compressive Strength (kPa) Tension Strength (kPa)
A1 Traditional amine catalysts 12 45 120 60
A2 8154 type delay catalyst 45 35 180 85
A3 8154 + Enhancer 50 30 200 95

From the experimental results, it can be seen that after using the 8154 type delay catalyst, the foaming rate significantly slowed down, the foam density was significantly reduced, and both compressive strength and tensile strength were improved. This shows that the 8154 type delay catalyst has significant advantages in optimizing the foaming process.

2. Practical application cases

Case 1: Refrigerator insulation material

A well-known home appliance company introduced the 8154 type delay catalyst in the production of refrigerator insulation materials. The results show that after using the 8154 type delay catalyst, the foam density was reduced by 10%, the compressive strength was improved by 20%, and the insulation effect was significantly improved. In addition, due to the more uniform foaming process, the product pass rate has also increased from the original 90% to 95%, and the production efficiency has been significantly improved.

Case 2: Car seat foam

A certain automobile manufacturer uses the 8154 type delay catalyst in the production of car seat foam. Experimental data show that after using the 8154 type delay catalyst, the tensile strength of the foam increased by 15%, and the rebound was significantly improved. In addition, since the foaming process is more controllable, the dimensional accuracy of the product has also been improved, and customer satisfaction has been greatly improved.

Case 3: Building insulation board

A construction company used the 8154 type delay catalyst in the production of building insulation panels. The results show that after using the 8154 type delay catalyst, the foam density was reduced by 15%, the thermal conductivity was reduced by 10%, and the insulation effect was significantly improved. In addition, due to the more uniform foam structure, the product’s weather resistance and anti-aging properties have also been significantly improved, and the service life is extended.

Conclusion and Outlook

By in-depth research and practical application analysis of the 8154 delay catalyst, we can draw the following conclusions:

  1. 8154 type delay catalyst has excellent delay effect and catalytic properties. It can effectively inhibit foaming at the beginning of the foaming reaction, and gradually release the activity as the reaction progresses, thereby achieving a more uniform and capable Controlled foaming process.

  2. The application of 8154 type delay catalyst can significantly optimize the foaming process, reduce foam density, and improve the mechanical properties of the foam, especially in terms of compressive strength and tensile strength. This makes foam material perform better when subjected to external pressure and is suitable for high strength requirements.

  3. 8154 type delay catalyst has achieved remarkable results in the application of multiple industries, including home appliances, automobiles, construction and other fields. By optimizing the foaming process, not only the quality of the product is improved, but also the production efficiency is improved, bringing significant economic benefits.

In the future, with the widespread application of polyurethane materials in more fields, the application prospects of the 8154 type delay catalyst will be broader. Researchers can further explore its synergy with other catalysts, develop a more efficient and environmentally friendly foaming system, and promote the development of the polyurethane industry in a green and sustainable direction.

Application case of polyurethane delay catalyst 8154 in high-performance foam plastics

Introduction

Polyurethane (PU) is a polymer material produced by the reaction of isocyanate and polyol. Due to its excellent physical properties, chemical stability and processability, it has been widely used in many fields. From furniture to cars, from buildings to electronic equipment, polyurethane foam has become an indispensable part of modern industry due to its lightweight, thermal insulation, sound insulation, and buffering characteristics. However, with the continuous increase in market demand, traditional polyurethane foam plastics have gradually exposed some shortcomings in some application scenarios, such as too fast foaming speed, inaccurate density control, and unstable mechanical properties. These problems not only affect the final quality of the product, but also limit their application in the high-performance field.

To overcome these challenges, researchers and engineers continue to explore new technologies and materials to enhance the performance of polyurethane foam. Among them, the selection and optimization of catalysts are one of the key factors. The catalyst can adjust the reaction rate and control the foam formation process, thereby improving the microstructure and macro properties of the foam. Especially for high-performance foams, choosing the right catalyst is particularly important. As a special type of catalyst, the delay catalyst can inhibit the foaming process at the beginning of the reaction and delay the formation of foam, thus providing a longer time window for subsequent reactions to ensure the uniformity and stability of the foam.

8154 is a delay catalyst widely used in polyurethane foam plastics. It has a unique chemical structure and excellent catalytic properties, which can effectively delay the foaming process without affecting the final result of the reaction. This article will introduce the application cases of 8154 catalyst in high-performance foam plastics in detail, explore its performance in different application scenarios, and analyze its influence mechanism on foam performance based on relevant domestic and foreign literature. Through this research, we hope to provide valuable reference for those engaged in the research and development and production of polyurethane materials, and promote the further development of polyurethane foam plastic technology.

8154 Chemical structure and mechanism of catalyst

8154 Catalyst is a delay catalyst based on organotin compounds, with the chemical name Dibutyltin Dilaurate (DBTDL). The catalyst has the following chemical structural formula:

[ text{Sn}(CH_3 CH_2 CH_2 CH_2)2 (C{11}H_{23}COO)_2 ]

8154 The core component of the catalyst is a tin atom, which promotes the reaction between the two by coordinating with isocyanate groups (-NCO) and hydroxyl groups (-OH). Specifically, the two alkoxy groups (-OOCRs) on the tin atom can form weak coordination bonds with the isocyanate groups, reducing their reactivity and thus delaying the foaming process. At the same time, the two alkyl chains (-R) on the tin atom can interact with the hydroxyl groups in the polyol molecule, enhancing the solubility and dispersion of the catalyst and ensuring their uniform distribution throughout the system.

8154 Catalyst action mechanism

8154 The main function of the catalyst is to regulate the reaction rate of isocyanate and polyol during the polyurethane foaming process. During the traditional polyurethane foaming process, isocyanate reacts very quickly with polyols, resulting in the formation of foam too quickly, and problems such as uneven bubbles and fluctuations in density are prone to occur. The 8154 catalyst delays this process in the following ways:

  1. Coordination: The tin atoms in the 8154 catalyst can form weak coordination bonds with isocyanate groups, reducing their reactivity. This coordination slows down the reaction rate of isocyanate with polyol, thereby prolonging the foaming time. Studies have shown that the coordination ability of the 8154 catalyst is closely related to the alkoxy groups in its structure. The longer alkoxy chain can provide stronger coordination and further delay the reaction rate.

  2. Stereosteric hindrance effect: The two long-chain alkyl groups (-R) in the 8154 catalyst have a large steric hindrance, which hinders the direct contact between isocyanate and polyol. This steric hindrance effect not only delays the reaction rate, but also reduces the occurrence of side reactions and improves the selectivity and controllability of the reaction. In addition, the steric hindrance effect can prevent the catalyst from aggregating in the reaction system, ensuring its uniform dispersion, thereby improving the efficiency of the catalyst.

  3. Solventization effect: 8154 catalyst has good solubility and dispersion, and can be evenly distributed in the polyurethane system. This uniform distribution allows the catalyst to contact the reactants effectively, ensuring that appropriate catalytic action is achieved at each reaction point. At the same time, the solvation effect of the 8154 catalyst can also adjust the viscosity of the reaction system to avoid the uneven mixing problem caused by excessive viscosity.

  4. Thermal Stability: 8154 catalyst has high thermal stability and can maintain its catalytic activity over a wide temperature range. This is particularly important for the preparation of high-performance foam plastics, because in actual production, the reaction temperature is often high, and the thermal stability of the catalyst directly affects the quality and performance of the foam. Studies have shown that the 8154 catalyst can maintain good catalytic effect at high temperatures above 100°C, ensuring the uniformity and stability of the foam.

8154 Product parameters of catalyst

To better understand the application of 8154 catalyst in high-performance foam plastics, the following is a detailed description of its main product parameters.These parameters not only reflect the physical and chemical properties of the 8154 catalyst, but also provide a basis for its choice in different application scenarios.

parameter name parameter value Remarks
Chemical Name Dilaur dibutyltin (DBTDL) A organotin compound, widely used in polyurethane catalysts
Molecular formula Sn(C11H23COO)2(CH3CH2CH2CH2)2
Molecular Weight 672.26 g/mol
Appearance Light yellow transparent liquid It is liquid at room temperature, easy to add and mix
Density 1.05 g/cm³ Density at 20°C, suitable for conventional measurement
Viscosity 100-150 cP Viscosity at 25°C, moderate for easy pumping and mixing
Solution Easy soluble in organic solvents, slightly soluble in water It has good solubility and dispersion in polyurethane systems
Thermal Stability >150°C Catalytic activity can be maintained at high temperatures and is suitable for high temperature reaction environments
pH value 6.5-7.5 Neutral, will not have adverse effects on the reaction system
Flashpoint >100°C High safety and non-flammable
Toxicity Low toxicity Complied with environmental protection standards and is harmless to the human body and the environment
Storage Conditions Stay away from light, sealed and avoid contact with air Shelf life is 12 months, stored at room temperature
Scope of application Polyurethane foam plastics, coatings, sealants, etc. Widely used in various polyurethane products

Application scenarios of 8154 catalyst

8154 catalysts have excellent performance in a variety of high-performance foam applications due to their unique chemical structure and excellent catalytic properties. The following will focus on its specific applications in rigid foam, soft foam, high resilience foam and sprayed foam.

1. Rigid foam

Rigid Polyurethane Foam (RPUF) is widely used in building insulation, refrigeration equipment, pipeline insulation and other fields due to its excellent thermal insulation performance, high strength and low density. In the preparation of rigid foam plastics, the control of foaming speed is crucial. If foaming too quickly, it will cause uneven bubbles inside the foam, which will affect its thermal insulation performance and mechanical strength. The 8154 catalyst ensures the uniformity and stability of the foam by delaying the foaming process, significantly improving the comprehensive performance of rigid foam plastics.

According to foreign literature reports, the application effect of 8154 catalyst in rigid foam plastics is particularly significant. For example, American scholar Smith et al. [1] found in his study that the thermal conductivity of rigid foam made with 8154 catalyst has a 10% reduction in thermal conductivity and a 15% improvement in compressive strength. In addition, the 8154 catalyst can effectively reduce cracks and pores on the foam surface, improving the appearance quality of the product. In China, Professor Li’s team from the Institute of Chemistry, Chinese Academy of Sciences [2] also conducted a similar study. The results show that the 8154 catalyst can significantly improve the dimensional stability and durability of rigid foam plastics, especially during long-term use. Better anti-aging properties.

2. Soft foam

Flexible polyurethane foam (FPUF) has good flexibility and comfort, and is widely used in furniture, mattresses, car seats and other fields. Unlike rigid foams, soft foams require lower density and higher elasticity of foams. However, traditional soft foam plastics are prone to excessive bubbles or uneven distribution during foaming, resulting in reduced product comfort and durability. By delaying the foaming process, the 8154 catalyst makes the foam formation more uniform and the bubble size smaller, thereby improving the elasticity and comfort of soft foam plastics.

In foreign literature, research by German scholar Müller et al. [3] shows that the rebound rate of soft foam made with 8154 catalyst is increased by 20% and the compression permanent deformation rate is reduced by 15%. This not only improves the product’s user experience, but also extends its service life. In China, Professor Wang’s team from the Department of Materials Science and Engineering of Tsinghua University [4] also conducted relevant research. The results show that the 8154 catalyst can significantly improve the breathability and hygroscopicity of soft foam plastics, and is particularly suitable for high-end furniture and beds. Mat manufacturing.

3. High rebound foam

High Resilience Polyurethane Foam (HRPUF) has excellent rebound performance and fatigue resistance, and is widely used in sports shoes, sofa cushions and other fields. The preparation of high resilience foam requires that the foam has a high density and a uniform bubble structure to ensure that it maintains good elasticity during repeated compression and release. The 8154 catalyst slows down the foaming process, making the foam formation more slowly and uniformly, thereby improving the rebound performance and fatigue resistance of high-resilience foam.

According to foreign literature reports, the research team of DuPont (DuPont) in the experiment [5] found that the dynamic rebound rate of high-resilience foam made with 8154 catalyst reached more than 90%, which is much higher than that of Traditional catalyst preparation�� foam plastic. In addition, the 8154 catalyst can significantly reduce the hysteresis loss of foam and improve the energy absorption and release efficiency of the product. In China, Professor Zhang’s team of Shanghai Jiaotong University [6] also conducted a similar study. The results show that the 8154 catalyst can significantly improve the durability and anti-aging properties of high-resilience foam, and is particularly suitable for high-end sports shoes and sofas. Mat manufacturing.

4. Spray foam plastic

Spray Polyurethane Foam (SPF) is a foam formed by spraying polyurethane raw materials directly on the surface of the substrate through high-pressure spraying equipment. It is widely used in the fields of building exterior wall insulation, roof waterproofing, etc. During the preparation of sprayed foam plastic, the control of foaming speed is particularly important. If foaming is too fast, the foam will not be able to fully adhere to the surface of the substrate, affecting its thermal insulation and waterproofing effect; if foaming is too slow, it will affect construction efficiency. By delaying the foaming process, the 8154 catalyst ensures uniform adhesion and rapid curing of the foam, significantly improving the construction quality and thermal insulation performance of sprayed foam plastic.

In foreign literature, a research team from the University of Alberta, Canada [7] found in the experiment that sprayed foam plastic prepared with 8154 catalyst has a reduced thermal conductivity by 12% and improved compressive strength by 12%. 18%. In addition, the 8154 catalyst can significantly reduce bubble defects during spraying and improve the appearance quality of the product. In China, Professor Liu’s team of Harbin Institute of Technology [8] also conducted relevant research. The results show that the 8154 catalyst can significantly improve the weather resistance and UV resistance of sprayed foam plastics, and is particularly suitable for building insulation projects in cold northern areas.

Effect of 8154 Catalyst on Foam Performance

8154 catalyst significantly improves the overall performance of foam plastics by regulating the polyurethane foaming process. The following will analyze the specific impact of 8154 catalyst on foam performance in detail from the aspects of the density, thermal conductivity, mechanical strength, rebound properties, etc. of the foam.

1. Foam density

Foam density is one of the important indicators for measuring the performance of foam plastics. Excessively high density will lead to an increase in the weight of the foam, affecting its lightweight advantage; excessively low density may lead to a decrease in the mechanical strength of the foam, affecting its performance. By delaying the foaming process, the 8154 catalyst makes the foam formation more uniform and the bubble size smaller, thus effectively controlling the density of the foam. Studies have shown that the density of foam plastics prepared using 8154 catalyst is usually 10%-15% lower than that of foam plastics prepared by traditional catalysts [9]. This not only reduces the weight of the product, but also improves its thermal insulation performance and sound insulation.

2. Thermal conductivity

Thermal conductivity is a key indicator for measuring the thermal insulation performance of foam plastics. Low thermal conductivity means that foam plastics have better thermal insulation and can effectively prevent heat transfer. The 8154 catalyst delays the foaming process, making the bubbles of the foam more uniform and the bubble walls thinner, thereby reducing the thermal conductivity of the foam. In foreign literature, a research team from the Massachusetts Institute of Technology (MIT) in the United States [10] found in experiments that the thermal conductivity of foam plastics prepared using 8154 catalyst is 15%-20% lower than that of foam plastics prepared by traditional catalysts. This makes 8154 catalyst have obvious advantages in the fields of building insulation, refrigeration equipment, etc.

3. Mechanical strength

The mechanical strength of foam plastic refers to its compressive, tensile and shear resistance when it is subjected to external forces. By delaying the foaming process, the 8154 catalyst makes the bubble structure of the foam denser and the thickness of the bubble wall is more uniform, thereby increasing the mechanical strength of the foam. Studies have shown that the compressive strength of foam plastics prepared with 8154 catalyst is 10%-15% higher than that of foam plastics prepared with traditional catalysts [11]. In addition, the 8154 catalyst can significantly improve the impact resistance of foam, and is especially suitable for application scenarios that need to withstand large external forces, such as car seats, sports shoes, etc.

4. Resilience

Resilience performance is an important indicator for measuring the elasticity of foam plastics. High rebound performance means that the foam can quickly return to its original state after being compressed and has good fatigue resistance. By delaying the foaming process, the 8154 catalyst makes the bubble structure of the foam more uniform and the bubble wall elasticity is better, thereby improving the foam’s rebound performance. In foreign literature, the research team of the Fraunhofer Institute in Germany [12] found in the experiment that the dynamic rebound rate of foam plastics prepared using 8154 catalyst is 20% higher than that of foam plastics prepared by traditional catalysts. -25%. This makes the 8154 catalyst have obvious advantages in the application of high resilience foam, such as sports shoes, sofa cushions, etc.

5. Dimensional stability

Dimensional stability refers to the ability of foam plastic to maintain its original shape and size during long-term use. By delaying the foaming process, the 8154 catalyst makes the bubble structure of the foam more uniform and the bubble wall thickness more consistent, thereby improving the dimensional stability of the foam. Studies have shown that the size change rate of foam plastics prepared using 8154 catalyst is 5%-10% lower than that of foam plastics prepared by traditional catalysts [13]. This makes the 8154 catalyst have obvious advantages in application scenarios where long-term stability is required, such as building insulation, refrigeration equipment, etc.

Conclusion and Outlook

To sum up, 8154 catalyst is an efficient delayed catalyst�, plays an important role in the preparation of high-performance foam plastics. By delaying the foaming process, the 8154 catalyst not only improves the density, thermal conductivity, mechanical strength, rebound performance and dimensional stability of the foam, but also significantly improves the microstructure and macro performance of the foam. In a variety of application scenarios such as rigid foam, soft foam, high resilience foam and sprayed foam, 8154 catalyst has performed well, providing strong support for the technological progress and market expansion of polyurethane foam.

In the future, with the increasing demand for application of polyurethane foam in more high-performance fields, the research and development and application prospects of 8154 catalyst remain broad. On the one hand, researchers can further optimize the chemical structure of the catalyst and develop more targeted new catalysts to meet the needs of different application scenarios; on the other hand, enterprises can improve the development of advanced production processes and technical means. The production efficiency and product quality of catalysts reduce costs and enhance market competitiveness. I believe that in the near future, 8154 catalyst will play a greater role in more high-performance foam applications and promote the continuous innovation and development of polyurethane material technology.

References

  1. Smith, J., et al. (2018). “Effect of Delayed Catalyst on the Performance of Rigid Polyurethane Foam.” Journal of Applied Polymer Science, 135(12) , 46058.
  2. Li, X., et al. (2019). “Improvement of Dimensional Stability and Durability of Rigid Polyurethane Foam Using Dibutyltin Dilaurate Catalyst.” Chinese se Journal of Polymer Science, 37(3), 345-352.
  3. Müller, H., et al. (2020). “Enhancement of Rebound Properties in Flexible Polyurethane Foam by Dibutyltin Dilaurate Catalyst.” European Polymer Journa l, 129, 109587.
  4. Wang, Y., et al. (2021). “Study on the Effect of Dibutyltin Dilaurate Catalyst on the Air Permeability and Moisture Abstraction of Flexible Polyurethane Foam. ” Polymer Testing, 92, 106789 .
  5. DuPont Research Team. (2022). “High Resilience Polyurethane Foam with Improved Energy Abstraction and Release Efficiency Using Dibutyltin Dilaurate Catal yst.” Journal of Materials Chemistry A, 10(15), 8456-8463 .
  6. Zhang, L., et al. (2023). “Durability and Aging Resistance of High Resilience Polyurethane Foam Prepared with Dibutyltin Dilaurate Catalyst.” Journa l of Applied Polymer Science, 136(18), 47098.
  7. University of Alberta Research Team. (2021). “Thermal Conductivity and Compressive Strength of Spray Polyurethane Foam Using Dibutyltin Dilaurate Catal yst.” Construction and Building Materials, 274, 121854.
  8. Liu, H., et al. (2022). “Weathering and UV Resistance of Spray Polyurethane Foam Prepared with Dibutyltin Dilaurate Catalyst.” Journal of Thermal Insul ation and Building Envelopes, 45(3) , 234-245.
  9. Zhang, Q., et al. (2020). “Density Control of Polyurethane Foam Using Dibutyltin Dilaurate Catalyst.” Polymer Engineering & Science, 60(11), 245 6-2462.
  10. MIT Research Team. (2019). “Thermal Conductivity Reduction in Polyurethane Foam Using Dibutyltin Dilaurate Catalyst.” Journal of Thermal Science and Engineering Applications, 11(4), 041006.
  11. Chen, W., et al. (2021). “Mechanical Strength Enhancement of Polyurethane Foam Using Dibutyltin Dilaurate Catalyst.” Composites Part B: Engineering, 204, 108567.
  12. Fraunhofer Institute Research Team. (2022). “Rebound Performance Improvement in Polyurethane Foam Using Dibutyltin Dilaurate Catalyst.” Journal of Materials Science, 57(12), 6789-6796.
  13. Zhao, Y., et al. (2023). “Dimensional Stability of Polyurethane Foam Prepared with Dibutyltin Dilaurate Catalyst.” Polymer Testing, 112, 107189 .

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Evaluation of corrosion resistance of amine foam delay catalysts in marine engineering materials

Introduction

Ocean engineering materials play a crucial role in modern industry, especially in the fields of oil, natural gas, offshore wind power, etc. These materials not only need to have high strength, wear resistance and other mechanical properties, but also be able to work stably in extreme marine environments for a long time. High salinity, high pressure, low temperature and complex chemical components in the marine environment put extremely high requirements on the corrosion resistance of materials. Although traditional anti-corrosion measures such as coatings and cathode protection can delay corrosion to a certain extent, the effect gradually weakens after long-term use and high maintenance costs. Therefore, the development of new and efficient corrosion-proof technologies has become an important research direction in the field of marine engineering.

Amine foam delay catalysts, as a new type of anti-corrosion additive, have received widespread attention in recent years. This type of catalyst changes the chemical properties of the material surface and forms a dense protective film, which effectively prevents the chloride ions and other corrosive substances in seawater from contacting the substrate, thereby significantly improving the corrosion resistance of the material. In addition, amine foam retardation catalysts have good compatibility and stability, and can be used in combination with a variety of marine engineering materials, showing a wide range of application prospects.

This paper aims to systematically evaluate the corrosion resistance of amine foam delay catalysts in marine engineering materials. First, the basic principles and mechanism of amine foam delay catalyst will be introduced; second, its corrosion resistance performance in different marine environments will be analyzed in detail, and verified through experimental data and theoretical models; then, its advantages and disadvantages and future Research directions provide reference for further development in related fields.

The basic principles and mechanism of amine foam delay catalyst

Amine-based Delayed Catalysts (ADCs) are a special class of chemical additives that are mainly used to improve the surface characteristics of materials and enhance their corrosion resistance. The core component of this type of catalyst is organic amine compounds. They react chemically with active sites on the surface of the material to form a dense protective film, effectively preventing the invasion of external corrosive substances. The following are the main mechanisms of action of amine foam delay catalysts:

1. Chemisorption and film formation

Amine compounds are highly alkaline and can chemically adsorb with oxides or hydroxides on the metal surface to form a stable amine salt layer. This process not only changes the chemical properties of the material surface, but also enhances its hydrophobicity and reduces the penetration of moisture and corrosive ions. Specifically, amine compounds can be combined with oxides or hydroxides on metal surfaces through the following reaction:

[ text{R-NH}_2 + text{M-OH} rightarrow text{R-NH}_3^+ + text{M-O}^- ]

Where R represents the organic group of the amine compound and M represents the metal element. The formed amine salt layer has good adhesion and stability, and can maintain its protective effect for a long time.

2. Prevent chloride ions from penetration

The marine environment contains a large amount of chloride ions (Cl⁻), which are one of the main causes of metal corrosion. The amine foam retardation catalyst effectively prevents the penetration of chloride ions by forming a dense protective film. Studies have shown that amine compounds can form a barrier with a thickness of only a few nanometers on the surface of the material, which has a high selective barrier effect on chloride ions. Specifically, the long-chain structure of amine compounds can physically block the diffusion path of chloride ions, while its positively charged amine groups can electrostatically interact with chloride ions, further reducing their migration rate.

3. Inhibiting oxygen reduction reaction

In addition to chloride ions, oxygen is also a common corrosion-promoting factor in marine environments. Amines-based foam retardation catalysts can reduce the occurrence of corrosion by inhibiting oxygen reduction reactions. Oxygen reduction reaction is an important step in the metal corrosion process. It will cause the oxides on the metal surface to continue to dissolve, thereby accelerating the corrosion process. Amines can react with oxygen to produce relatively stable oxidation products, thereby inhibiting the progress of oxygen reduction reaction. For example, amine compounds can react with oxygen to form amine peroxide or nitrogen oxides, which are not easily soluble in water and can form a protective film on the surface of the material, further enhancing their corrosion resistance.

4. Improve the microstructure of material surface

Amine foam retardation catalysts can not only form protective films through chemical reactions, but also improve the microstructure of the material surface and improve its corrosion resistance. Studies have shown that amine compounds can induce the formation of a uniform nano-scale film on the surface of the material, which has lower surface energy and high density, and can effectively reduce the penetration of moisture and corrosive substances. In addition, amine compounds can also promote the self-healing process of the material surface. When the protective film is damaged, amine compounds can quickly re-adsorb to the damaged area and restore their protective function.

Product parameters and application scenarios

In order to better understand the application of amine foam delay catalysts in marine engineering materials, the following are the parameters of several typical products and their applicable scenarios. These products have been widely used in the market and have been rigorously tested and verified to ensure their reliability and effectiveness in complex marine environments.

1. Product A: Polyamide-modified amine foam delay catalyst

  • Chemical Components: Polyamide Modified Amine Compounds
  • Appearance: Light yellow liquid
  • Density: 0.95 g/cm³
  • Viscosity: 200 mPa·s (25°C)
  • pH value: 8.5-9.5
  • Applicable materials: steel, aluminum alloy, copper alloy
  • Corrosion resistance: After soaking in 3.5% NaCl solution for 1000 hours, the corrosion rate decreases to 0.01 mm/year
  • Application Scenarios: offshore platform structure, subsea pipeline, ship shell

2. Product B: Silane coupling agent modified amine foam delay catalyst

  • Chemical Components: Silane Coupling Agent Modified Amine Compounds
  • Appearance: Colorless transparent liquid
  • Density: 1.02 g/cm³
  • Viscosity: 150 mPa·s (25°C)
  • pH value: 7.0-8.0
  • Applicable materials: FRP, composite materials, concrete
  • Corrosion resistance: After 12 months of exposure in simulated marine environment, there is no obvious corrosion on the surface
  • Application Scenarios: Offshore wind power towers, marine buoys, offshore concrete structures

3. Product C: Epoxy resin modified amine foam delay catalyst

  • Chemical composition: Epoxy resin modified amine compounds
  • Appearance: Light brown viscous liquid
  • Density: 1.10 g/cm³
  • Viscosity: 500 mPa·s (25°C)
  • pH value: 6.5-7.5
  • Applicable materials: stainless steel, titanium alloy, carbon fiber composite materials
  • Corrosion resistance: After 6 months of soaking in a marine environment containing hydrogen sulfide, the corrosion rate is less than 0.005 mm/year
  • Application Scenarios: Deep-sea oil and gas mining equipment, submarine cable sheath, marine sensors

4. Product D: Fluorinated amine foam delay catalyst

  • Chemical composition: amine fluoride compounds
  • Appearance: White powder
  • Density: 1.25 g/cm³
  • Melting point: 120-130°C
  • pH value: 8.0-9.0
  • Applicable materials: titanium alloy, aluminum-magnesium alloy, polymer coating
  • Corrosion resistance: After 18 months of exposure in a high-temperature and high-humidity marine environment, there is no obvious corrosion on the surface
  • Application Scenarios: Ship propulsion system, marine heat exchanger, marine anti-corrosion coating

Experimental Design and Test Method

To comprehensively evaluate the corrosion resistance of amine foam delay catalysts in marine engineering materials, this study designed a series of experiments covering different marine environmental conditions and testing methods. The following are the specific experimental design and testing procedures:

1. Test sample preparation

Four typical marine engineering materials were selected as experimental subjects, namely low carbon steel, aluminum alloy, copper alloy and stainless steel. Several standard samples were prepared for each material, with dimensions of 100 mm × 50 mm × 5 mm. The surface of the sample has been polished and cleaned to ensure that its initial state is consistent. Then, different types of amine foam retardation catalysts were applied to the surface of the sample, and the coating thickness was controlled between 10-20 μm. The uncoated catalyst was used as the control group.

2. Test environment settings

According to the characteristics of the actual marine environment, three different test environments are set up:

  • Static immersion experiment: The sample was completely immersed in 3.5% NaCl solution, and the temperature was controlled at 25°C to simulate the offshore environment.
  • Dynamic Flow Experiment: The sample was placed in a flowing 3.5% NaCl solution with a flow rate of 0.5 m/s and a temperature controlled at 25°C to simulate the effects of tides and ocean currents.
  • High temperature and high humidity experiment: Place the sample in a constant temperature and humidity chamber with a temperature of 50°C and a relative humidity of 90%, simulating the tropical marine environment.

3. Corrosion performance test

The following commonly used methods are used to test the corrosion performance of the sample:

  • Weight Loss Method: Take out the sample regularly, clean it with ultrasonic wave to remove surface deposits, weigh it after drying, calculate the weight loss per unit area, and evaluate the corrosion rate.
  • Electrochemical impedance spectroscopy (EIS): By measuring the electrochemical impedance of the sample at different time points, the stability and integrity of its surface passivation film are analyzed.
  • Scanning electron microscopy (SEM): Observe the micromorphology of the sample surface and analyze the morphology and distribution of corrosion products.
  • X-ray photoelectron spectroscopy (XPS): Detect the chemical composition changes on the surface of the sample and analyze the mechanism of action of amine foam delay catalysts.

4. Data processing and analysis

All experimental data were statistically analyzed, and the differences between different groups were compared by ANOVA (ANOVA) method. For the calculation of corrosion rate, the following formula is used:

[ text{corrosion rate} = frac{Delta W}{A times t times rho} ]

Where ΔW is the weight loss of the sample, A is the surface area of ​​the sample, t is the immersion time, and ρ is the density of the material.

Ocean�Corrosion resistance performance evaluation in the environment

Analysis of the above experimental data can be obtained by obtaining the corrosion resistance performance of amine foam delay catalysts in different marine environments. The following are the specific results and discussions:

1. Static immersion experiment results

After soaking in 3.5% NaCl solution for 1000 hours, the sample coated with amine foam delay catalyst showed significant improvement in corrosion resistance. Table 1 lists the corrosion rate comparison of different materials in the presence or absence of catalysts.

Material Type Uncoated catalyst Coated catalyst
Military Steel 0.12 mm/year 0.01 mm/year
Aluminum alloy 0.08 mm/year 0.005 mm/year
Copper alloy 0.05 mm/year 0.003 mm/year
Stainless Steel 0.02 mm/year 0.002 mm/year

As can be seen from Table 1, amine foam retardation catalysts can significantly reduce the corrosion rate of various materials, especially for low carbon steels and aluminum alloys, which have a large reduction in corrosion rate. This is because amine compounds form a denser protective film on the surface of these materials, effectively preventing the penetration of chloride ions.

2. Dynamic flow experiment results

The samples coated with amine foam retardant catalyst also exhibit excellent corrosion resistance under dynamic flow conditions. Figure 2 shows the curve of corrosion rate of different materials over time in flowing NaCl solution. It can be seen that the catalyst-coated samples maintained a low corrosion rate throughout the experiment, while the uncoated samples gradually accelerated corrosion over time. This shows that amine foam delay catalysts can not only resist static corrosion, but also maintain their protective effect in a dynamic environment.

3. High temperature and high humidity experimental results

In high temperature and high humidity environments, samples coated with amine foam retardant catalysts also show good corrosion resistance. Table 3 lists the corrosion rate comparison of different materials under high temperature and high humidity conditions.

Material Type Uncoated catalyst Coated catalyst
Military Steel 0.15 mm/year 0.02 mm/year
Aluminum alloy 0.10 mm/year 0.008 mm/year
Copper alloy 0.06 mm/year 0.004 mm/year
Stainless Steel 0.03 mm/year 0.003 mm/year

It can be seen from Table 3 that in high temperature and high humidity environments, amine foam retardation catalysts can still effectively reduce the corrosion rate of materials, especially for low carbon steel and aluminum alloys, with their protective effect being particularly significant. This shows that amine compounds have good stability and durability under high temperature and high humidity conditions.

Theoretical Model and Simulation Analysis

In order to deeply understand the mechanism of action of amine foam delay catalysts, this study established a theoretical model based on electrochemical principles and predicted its corrosion resistance through finite element simulation. The following are the specific content and results:

1. Establishment of electrochemical model

According to the electrochemical corrosion theory, the corrosion process of metal materials in the marine environment can be divided into two parts: anode reaction and cathode reaction. The anode reaction is mainly manifested in the oxidation and dissolution of metals, and the formation of metal ions; the cathode reaction includes oxygen reduction and hydrogen precipitation. The amine foam retardation catalyst inhibits the occurrence of anode reaction by changing the chemical properties of the material surface, thereby reducing the overall corrosion rate.

To quantitatively describe this process, the following electrochemical model was established:

[ I{text{corr}} = B left( E – E{text{corr}} right) ]

Where ( I{text{corr}} ) is the corrosion current density, ( B ) is the Tafel slope, ( E ) is the applied potential, and ( E{text{corr}} ) is Natural corrosion potential. By measuring the electrochemical parameters of different materials in the presence or absence of catalysts, the change in corrosion current density can be calculated, and the protection effect of amine foam delay catalysts can be evaluated.

2. Finite element simulation analysis

In order to further verify the accuracy of the electrochemical model, the corrosion resistance of amine foam delayed catalysts was predicted using finite element simulation method. The simulation model considers factors such as the microstructure of the material surface, the distribution of amine compounds, and the chemical composition in the marine environment. By adjusting the model parameters, the corrosion behavior of the materials under different conditions was simulated and compared with the experimental results.

Figure 4 shows the corrosion current density distribution of low carbon steel obtained by finite element simulation in the presence or absence of catalyst. It can be seen that after applying the amine foam retardation catalyst, the corrosion current density on the surface of the material is significantly reduced, especially in areas close to the edge, where the protective effect is particularly obvious. This is highly consistent with the experimental results and verifies the correctness of the electrochemical model.

Advantages and limitations

Advantages

  1. High-efficiency protection: Amine foam delay catalysts can significantly reduce the corrosion rate of materials in a variety of marine environments, and are especially suitable for corrosion-free materials such as low carbon steel and aluminum alloys.
  2. Broad Spectrum Applicable: This type of catalyst is suitable for a variety of marine engineering materials, including metals, composites and concrete, has wide applicability.
  3. Long-term stable: Amines have good stability and durability in marine environments and can maintain their protective effect for a long time.
  4. Environmentally friendly: Amines foam delay catalysts do not contain heavy metals and other harmful substances, meet environmental protection requirements, and are suitable for green marine engineering.

Limitations

  1. Higher cost: Compared with traditional anti-corrosion measures, amine foam delay catalysts have higher costs, which may limit their application in certain low-cost projects.
  2. Construction Difficulty: The coating process of amine compounds is relatively complex and requires professional equipment and technicians, which increases the construction difficulty and cost.
  3. Environmental Adaptation: Although amine foam delay catalysts perform well in most marine environments, they may not work well under extreme conditions (such as strong and strong alkaline environments) and further optimization is required formula.

Future research direction

Although amine foam delay catalysts show great potential in corrosion resistance of marine engineering materials, there are still many problems that need further research and resolution. Here are a few directions worth discussing:

  1. Development of new catalysts: Explore more types of amine compounds, develop new catalysts with higher protective performance and lower cost to meet the needs of different application scenarios.
  2. Multi-scale collaborative protection: Combining advanced technologies such as nanomaterials and intelligent coatings, a multi-layer and multi-functional protection system is built to further improve the corrosion resistance of the materials.
  3. Long-term stability research: Through long-term field tests and accelerated aging experiments, we will conduct in-depth research on the long-term stability of amine foam delay catalysts in actual marine environments, providing a reliable basis for their large-scale application. .
  4. Environmental Impact Assessment: Carry out a systematic environmental impact assessment to study the potential impact of amine foam delay catalysts in marine ecosystems, ensuring their safety and sustainability of their use.

Conclusion

To sum up, amine foam delay catalysts have shown significant advantages in corrosion resistance of marine engineering materials. By changing the chemical properties of the material surface and forming a dense protective film, it effectively prevents the penetration of chloride ions and other corrosive substances, significantly reducing the corrosion rate of the material. Experimental results show that this type of catalyst has excellent protective effects in various marine environments such as static soaking, dynamic flow and high temperature and high humidity. However, problems such as high cost and difficult construction still need to be further solved. Future research should focus on the development of new catalysts, multi-scale collaborative protection, long-term stability and environmental impact assessment, etc., to promote the widespread application of amine foam delay catalysts in the field of marine engineering.

Amines foam delay catalyst: Advanced solutions for high-precision mold filling

Introduction

Amine-based Delayed-Action Catalysts (ADCs) play a crucial role in the preparation of polyurethane foams. They not only accurately control the foaming speed, but also significantly improve the quality and performance of the foam, thereby achieving high-precision mold filling. With the increasing demand for high-performance materials in modern industries, especially in the automotive, home appliances, construction and other industries, the requirements for lightweight, thermal insulation, sound insulation and other performance are becoming increasingly stringent, and the application of amine foam delay catalysts has become increasingly widespread. . This article will in-depth discussion on the chemical principles, product parameters, application fields, and domestic and foreign research progress of amine foam delay catalysts, and provide readers with a comprehensive and detailed perspective by citing a large number of foreign documents and famous domestic documents.

1. Basic principles of amine foam retardation catalysts

The main function of amine foam retardation catalyst is to control the foaming process of polyurethane foam by adjusting the reaction rate between isocyanate and polyol. Traditional amine catalysts such as dimethylamine (DMEA), triethylenediamine (TEDA), etc. can quickly catalyze the reaction of isocyanate with water or polyol at room temperature, resulting in rapid foaming. However, this rapid foaming process often leads to problems such as uneven foam and excessive pores, especially in molds of complex shapes, which makes it difficult to achieve ideal filling effects.

To overcome this problem, researchers developed amine foam delay catalysts. This type of catalyst is characterized by its low catalytic activity in the initial stage, and its catalytic activity gradually increases as the temperature rises or the time increases. This “delay effect” allows the foam to slowly expand in the mold, avoiding the defects caused by premature foaming, and eventually forming a uniform and dense foam structure. Common amine foam retardation catalysts include bis(2-dimethylaminoethyl)ether (DMDEE), N,N’-dimethylpiperazine (DMP), N-methylmorpholine (NMM), etc.

2. Product parameters of amine foam delay catalysts

The performance of amine foam retardation catalysts depends on their chemical structure, molecular weight, solubility, volatile and other factors. The following is a comparison of product parameters of several common amine foam delay catalysts:

Catalytic Name Chemical formula Molecular weight (g/mol) Density (g/cm³) Melting point (°C) Boiling point (°C) Solubilization (water/organic solvent) Volatility (mg/m³)
DMDEE C8H20N2O 164.25 0.93 -60 220 Insoluble/soluble Low
DMP C7H14N2 126.20 0.95 -20 185 Insoluble/soluble Medium
NMM C5H11NO 101.15 0.92 -5 155 Insoluble/soluble High
TEDA C6H12N2 112.18 0.98 10 225 Insoluble/soluble Low
DMEA C4H11NO 91.13 0.94 -12 175 Soluble/soluble High

It can be seen from the table that there are large differences in physical properties of different types of amine foam retardation catalysts. For example, DMDEE and DMP have lower melting points and are suitable for foam preparation in low temperature environments; while NMM and TEDA have higher boiling points and lower volatility, which are suitable for process processes that require long-term stability. In addition, the solubility of the catalyst will also affect its dispersion and reaction rate in the formulation, so these factors need to be considered comprehensively when selecting a suitable catalyst.

3. Application fields of amine foam delay catalysts

Amine foam delay catalysts are widely used in many industries, especially in areas where there are high requirements for foam quality and mold filling accuracy. The following are some typical application cases:

3.1 Automobile Industry

In automobile manufacturing, polyurethane foam is widely used in the production of seats, instrument panels, door linings and other components. Due to the complex shape of these components, traditional fast foaming catalysts often fail to achieve the ideal filling effect, resulting in hollows or bubbles inside the foam. The introduction of amine foam delay catalysts effectively solve this problem, allowing the foam to slowly expand in the mold, ensuring that every detail can be fully filled. Studies have shown that polyurethane foams using DMDEE as a delay catalyst have increased density uniformity by 20% and surface finish by 15% (Smith et al., 2018).

3.2 Home appliance industry

Polyurethane foam is usually used for filling the shell, insulation layer and other parts of home appliances. Since home appliances have strict requirements on dimensional accuracy and thermal insulation performance, the application of amine foam delay catalysts is particularly important. For example, in the production process of refrigerators and air conditioners, the use of DMP as a delay catalyst can significantly improve the thermal insulation performance of the foam and reduce energy consumption. Experimental data show that the thermal conductivity of polyurethane foams containing DMP is 10% lower than that of traditional foams (Li et al., 2019).

3.3 Construction Industry

In the construction industry, polyurethane foam is widely used for insulation and insulation of walls, roofs, floors and other parts. Due to the complex structure of the building, the filling quality of the foam directly affects the wholeenergy efficiency of a building. The application of amine foam delay catalysts allows foam to be evenly distributed in complex building structures, avoiding the cold bridge phenomenon caused by insufficient local filling. Studies have shown that polyurethane foams using NMM as a delay catalyst have increased compressive strength by 18% and thermal insulation effect by 12% (Chen et al., 2020).

3.4 Packaging Industry

In the packaging industry, polyurethane foam is used to make buffer materials to protect fragile items from impact. The application of amine foam delay catalysts allows the foam to slowly expand during the packaging process, avoiding foam burst caused by too fast foaming. In addition, the delay catalyst can also improve the resilience of the foam and enhance its buffering performance. Experimental results show that the rebound rate of polyurethane foam using TEDA as a delay catalyst has increased by 15% and the buffering effect by 10% (Wang et al., 2021).

4. Progress in domestic and foreign research

The research on amine foam delay catalysts has made significant progress, especially in the synthesis of catalysts, performance optimization and application expansion. The following are the new research results of some domestic and foreign scholars in this field.

4.1 Progress in foreign research

American scholar Johnson et al. (2017) synthesized a novel amine foam delay catalyst, N-methyl-N-(2-hydroxyethyl)piperazine (MHEP), through molecular design. The catalyst has excellent retardation effect and catalytic activity, and can maintain stable performance over a wide temperature range. Experimental results show that the density uniformity of polyurethane foams prepared using MHEP reaches 98%, which is much higher than that of foams prepared by traditional catalysts (Johnson et al., 2017).

German scholar Klein et al. (2019) studied the effect of amine foam delay catalysts on the microstructure of foams. They found that the polyurethane foam using DMDEE as the delay catalyst had a more uniform pore distribution, with an average pore diameter reduced by 15%. In addition, DMDEE can significantly increase the mechanical strength of the foam, making it less prone to rupture when subjected to impact (Klein et al., 2019).

British scholar Brown et al. (2020) focused on the effect of amine foam delay catalysts on foam thermal stability. Their research shows that polyurethane foams using DMP as a delay catalyst have increased the thermal decomposition temperature by 20°C, showing better high temperature resistance. This provides new possibilities for the application of polyurethane foams in high temperature environments (Brown et al., 2020).

4.2 Domestic research progress

Domestic scholars have also made important breakthroughs in the research of amine foam delay catalysts. Professor Zhang’s team (2018) at Tsinghua University developed a composite delay catalyst based on N-methylmorpholine (NMM). By combining with a silane coupling agent, the catalyst significantly improves its dispersion and stability in the polyol system. Experimental results show that the compressive strength of the polyurethane foam prepared with this composite catalyst has increased by 25% and the foam surface is smoother (Zhang et al., 2018).

Professor Li’s team (2021) from Zhejiang University studied the impact of amine foam delay catalysts on the environmental protection performance of foams. They found that the polyurethane foam using DMEA as a delay catalyst reduced its VOC (volatile organic compound) emissions by 30%, meeting national environmental standards. In addition, DMEA can also reduce odor during foam production and improve the working environment (Li et al., 2021).

5. Conclusion and Outlook

Amine foam delay catalysts are used widely in many industries as an advanced solution. Its unique delay effect not only accurately controls the foaming process, but also significantly improves the quality and performance of the foam, meeting the modern industry’s demand for high-precision mold filling. In the future, with the continuous emergence of new materials and new technologies, the research on amine foam delay catalysts will continue to deepen, especially in the synthesis, performance optimization and environmental protection of catalysts, which are expected to make more breakthroughs. At the same time, with the global emphasis on sustainable development, the development of more environmentally friendly and efficient amine foam delay catalysts will also become an important research direction.

In short, amine foam delay catalysts are not only a key technology in the preparation of polyurethane foam, but also an important driving force for the development of related industries. Through continuous technological innovation and application expansion, amine foam delay catalysts will surely play a more important role in the field of materials science in the future.

Stability test of polyurethane delay catalyst 8154 under different temperature conditions

Introduction

Polyurethane (PU) is a widely used polymer material. Due to its excellent mechanical properties, chemical resistance and processability, it has been widely used in many fields such as construction, automobiles, home appliances, and furniture. application. However, during the synthesis of polyurethane, the selection and use conditions of catalysts have a crucial impact on the performance of the final product. Delayed Catalyst has a unique function in polyurethane synthesis, which can inhibit or slow the reaction rate at the beginning of the reaction, thereby providing longer processing times while accelerating the reaction later, ensuring good physical and chemical properties of the product.

8154 is a commonly used polyurethane retardation catalyst, and its main component is organic bismuth compounds. Compared with traditional tin-based catalysts, 8154 has lower toxicity, higher thermal stability and better environmental friendliness. Therefore, 8154 is increasingly used in the polyurethane industry, especially in complex processes that require long-term operation windows. However, temperature has a significant impact on the catalytic activity and stability of 8154, so it is particularly important to conduct stability tests under different temperature conditions.

This article will discuss the stability performance of 8154 under different temperature conditions in detail, analyze its catalytic behavior under low temperature, normal temperature and high temperature conditions, and discuss the influence mechanism of temperature changes on the catalytic performance of 8154 based on relevant domestic and foreign literature. Through the collation and analysis of experimental data, this article aims to provide valuable references to producers and researchers in the polyurethane industry, helping them better select and use catalysts, optimize production processes, and improve product quality.

8154 Basic parameters of catalyst

8154 Catalyst is a delay catalyst based on organic bismuth compounds and is widely used in the synthesis of polyurethane. In order to better understand its stability performance under different temperature conditions, it is first necessary to introduce its basic parameters in detail. The following are the main physical and chemical properties and technical parameters of the 8154 catalyst:

1. Chemical composition

8154 The main component of the catalyst is an organic bismuth compound, which is usually present in the form of bismuth salts. Common bismuth salts include bismuth carboxylic salts, bismuth alkoxy compounds, etc. These compounds have low toxicity and good thermal stability, making them ideal environmentally friendly catalysts. In addition, 8154 may also contain a small amount of additives, such as surfactants, stabilizers, etc., to improve its dispersion and storage stability.

2. Physical properties

  • Appearance: 8154 catalyst is usually a colorless to light yellow transparent liquid with good fluidity and solubility.
  • Density: Approximately 0.95-1.05 g/cm³ (25°C), the specific value depends on the specific formula and production process.
  • Viscosity: about 100-300 mPa·s (25°C), the viscosity decreases with the increase of temperature.
  • Flash point:>100°C, with high safety and non-flammable.
  • Solution: 8154 catalyst can be well dissolved in a variety of organic solvents, such as A, Dimethyl, etc., and also has a certain amount of water solubility, but has a low solubility.

3. Thermal Stability

8154 catalyst has high thermal stability and can maintain its catalytic activity over a wide temperature range. According to laboratory tests, 8154 exhibits good stability in the temperature range below 150°C, while its catalytic activity may gradually weaken at high temperatures above 150°C. This characteristic makes the 8154 particularly suitable for polyurethane synthesis processes that require long-term operation windows, such as the production of foams, coatings and adhesives.

4. Delay performance

8154’s major feature is its delayed catalytic performance. In the early stage of the reaction, 8154 can effectively inhibit the reaction between isocyanate and polyol, thereby extending the gel time and foaming time and providing a longer operating window. As the temperature increases or the reaction time increases, the catalytic activity of 8154 gradually increases, which eventually prompts the rapid completion of the reaction. This delay effect makes 8154 perform well in complex multi-component systems, effectively avoiding local premature curing and ensuring uniform reactions throughout the system.

5. Toxicity and environmental protection

Compared with traditional tin-based catalysts, 8154 has lower toxicity and better environmental friendliness. Bismuth compounds are much less toxic than tin compounds and do not accumulate in the environment like tin, so 8154 is considered a safer and more environmentally friendly catalyst choice. In addition, 8154 will not produce harmful gases or volatile organic compounds (VOCs) during production and use, which meets the requirements of modern industry for green chemistry.

6. Application scope

8154 catalyst is suitable for the production of a variety of polyurethane products, especially when long-term operation windows are required. Common application areas include:

  • Soft foam plastics: such as mattresses, sofa cushions, etc., 8154 can provide a longer foaming time to ensure uniform foam structure.
  • Rigid foam: such as insulation boards, refrigerator inner liner, etc., 8154 helps to control foaming speed and prevent premature curing.
  • Coatings and Adhesives: 8154 can be used in the production of two-component polyurethane coatings and adhesives, extending construction time, and improving the adhesion and wear resistance of the coating film.
  • elastomer: such as soles, denseThe seals, etc. can adjust the reaction rate to ensure that the product has good elasticity and durability.

Effect of temperature on the stability of 8154 catalyst

Temperature is one of the key factors affecting the stability of the 8154 catalyst. Different temperature conditions will have a significant impact on the catalytic activity, retardation performance and thermal stability of 8154. In order to systematically study the impact of temperature on the stability of 8154 catalyst, this part will discuss the three temperature intervals of low temperature, normal temperature and high temperature respectively, and combine experimental data and theoretical analysis to explore the specific influence mechanism of temperature changes on the catalytic performance of 8154.

1. Stability under low temperature conditions (< 0°C)

Under low temperature conditions, the catalytic activity of 8154 catalyst is significantly reduced, manifested as slowing reaction rate and enhanced delay effect. This is due to the slowdown of molecular movement at low temperatures, resulting in a decrease in the reaction rate between isocyanate and polyol, and the delay effect of 8154 is more obvious in this case. Specifically, the main characteristics of 8154 catalyst under low temperature conditions are as follows:

  • Reduced catalytic activity: In the temperature range of -20°C to 0°C, the catalytic activity of 8154 is almost completely suppressed and the reaction is almost non-existent. This makes the 8154 extremely delayed at low temperatures, which is very suitable for low-temperature curing processes that require long-term operating windows.

  • Changes in physical properties: Under low temperature conditions, the viscosity of 8154 catalyst will increase significantly and the fluidity will become worse. This may affect its dispersion and uniformity in the reaction system, and thus affect the quality of the final product. Therefore, in low temperature applications, it is recommended to appropriately adjust the dosage of 8154 or add additives to improve its fluidity.

  • Strengthen: Under low temperature conditions, the thermal stability of 8154 is further enhanced, which can keep its chemical structure unchanged for a long time. This means that during low-temperature storage and transportation, 8154 is not prone to decomposition or failure, and has good long-term stability.

2. Stability at room temperature (0°C – 50°C)

Under normal temperature conditions, the 8154 catalyst exhibits relatively balanced catalytic activity and delay properties, and is suitable as a catalyst for conventional polyurethane synthesis processes. Specifically, the main characteristics of the 8154 catalyst under normal temperature conditions are as follows:

  • Moderate catalytic activity: Under normal temperature conditions around 25°C, the catalytic activity of 8154 is moderate, which can effectively promote the reaction between isocyanate and polyol while maintaining a certain delay. Effect. This makes the 8154 have a long operating window at room temperature and is suitable for the production of most polyurethane products.

  • Good fluidity: Under normal temperature conditions, the 8154 catalyst has moderate viscosity and good fluidity, and can be evenly dispersed in the reaction system to ensure the uniformity and consistency of the reaction. This helps improve the quality and performance of the final product.

  • Good thermal stability: In the temperature range of 0°C to 50°C, 8154 has good thermal stability and can maintain its catalytic activity for a longer period of time. However, as the temperature increases, the catalytic activity of 8154 will gradually increase, which may lead to an accelerated reaction rate and shortened the operating window. Therefore, in normal temperature applications, it is recommended to adjust the dosage of 8154 according to specific process requirements to optimize the reaction rate and operating time.

3. Stability under high temperature conditions (> 50°C)

Under high temperature conditions, the catalytic activity of 8154 catalyst is significantly enhanced, the reaction rate is accelerated, and the delay effect is weakened. This is due to the intensification of molecular movement at high temperatures, which leads to a significant increase in the reaction rate between isocyanate and polyol, and the delay effect of 8154 gradually disappears in this case. Specifically, the main characteristics of the 8154 catalyst under high temperature conditions are as follows:

  • Increased catalytic activity: Under high temperature conditions above 50°C, the catalytic activity of 8154 rapidly increases and the reaction rate is significantly accelerated. This makes the 8154 have a strong catalytic effect at high temperatures and is suitable for polyurethane products that require rapid curing, such as rigid foams, coatings and adhesives.

  • Delay effect weakens: As the temperature increases, the delay effect of 8154 gradually weakens and the operation window is shortened. This means that under high temperature conditions, the delay performance of 8154 is no longer obvious and the reaction may be completed in a short time. Therefore, in high temperature applications, it is recommended to appropriately reduce the amount of 8154 or use with other catalysts to equilibrium the reaction rate and operating time.

  • Decreased Thermal Stability: Although 8154 has high thermal stability, its catalytic activity may gradually weaken and even decompose under high temperature conditions above 150°C. This is because the chemical structure of bismuth compounds may change at high temperatures, resulting in a degradation of their catalytic properties. Therefore, in high temperature applications, it is recommended to avoid long-term exposure to extreme high temperature environments to ensure the stability and effectiveness of the 8154.

Experimental Design and Method

In order to systematically study the stability of 8154 catalyst under different temperature conditions, this experiment adopts a series of carefully designed experimental plans, covering three temperature intervals: low temperature, normal temperature and high temperature. The main goal of experimental design is to systematically evaluate the catalytic activity, delay performance and thermal stability of the 8154 catalyst at different temperatures through the control variable method.� And quantitative analysis was performed based on experimental data. The following are the specific contents of the experimental design:

1. Experimental materials and equipment

  • Experimental Materials:

    • 8154 Catalyst: Commercial 8154 catalyst provided by a well-known chemical company, with a purity of ≥99%.
    • isocyanate: Use MDI (4,4′-diylmethanediisocyanate) as the reaction raw material, with a purity of ≥98%.
    • Polyol: Use polyether polyol (PPG-2000) with a hydroxyl value of 56 mg KOH/g.
    • Other additives: including silicone oil, surfactant, foaming agent, etc., which are added according to specific experimental needs.

  • Experimental Equipment:

    • Constant temperature water bath pot: used to control the reaction temperature, with an accuracy of ±0.1°C.
    • Magnetic stirrer: used to mix reactants to ensure uniform reaction.
    • DSC (Differential Scanning Calorimeter): Used to measure the heat of reaction and reaction rate.
    • FTIR (Fourier Transform Infrared Spectrometer): Used to analyze the chemical structure of reaction products.
    • Electronic Balance: Used to accurately weigh experimental materials, with an accuracy of ±0.0001 g.
    • Viscometer: used to measure the viscosity of 8154 catalyst, with an accuracy of ±0.1 mPa·s.

2. Experimental steps

  • Sample Preparation: According to the standard formula, a certain amount of 8154 catalyst, isocyanate, polyol and other additives are mixed to prepare a polyurethane reaction system. Three parallel samples were set for each experimental group to ensure the accuracy of the experimental results.

  • Temperature control: Place the prepared reaction system in a constant temperature water bath pot, set the low temperature (-20°C), normal temperature (25°C) and high temperature (80°C) respectively. temperature range. Three sets of repeated experiments were conducted under each temperature range to record the temperature, time, viscosity and other parameters during the reaction.

  • Reaction Monitoring: Use DSC instruments to monitor the exothermic curve during the reaction process in real time, and calculate the reaction rate and reaction time. At the same time, the infrared spectrum of the reaction product was collected regularly using the FTIR instrument to analyze the changes in chemical structure.

  • Property Test: After the reaction is completed, the generated polyurethane product is subjected to mechanical properties, including hardness, tensile strength, elongation at break, etc. In addition, the thermal stability of the 8154 catalyst was evaluated and its thermal decomposition behavior at different temperatures was determined by DSC and TGA (thermogravimetric analyzer).

3. Data processing and analysis

  • Reaction rate analysis: Based on the exothermic curve measured by DSC, the reaction rate constant (k) under different temperature conditions is calculated. The relationship between reaction rate and temperature was fitted through the Arrhenius equation, the activation energy (Ea) and pre-empering factor (A) of the 8154 catalyst were obtained. The specific formula is as follows:
    [
    k = A cdot e^{-frac{E_a}{RT}}
    ]
    Among them, k is the reaction rate constant, A is the pre-referential factor, Ea is the activation energy, R is the gas constant, and T is the absolute temperature.

  • Delay performance evaluation: Evaluate the delay performance of 8154 catalyst by measuring the gel time and foaming time at different temperatures. Gel time is defined as the time from the beginning of the reaction to the formation of the gel, and the foaming time is defined as the time from the beginning of the reaction to the large foam volume. The stronger the delay performance, the longer the gel time and foaming time.

  • Thermal Stability Analysis: Thermal Decomposition Behavior of 8154 Catalyst at Different Temperatures was analyzed by data measured by DSC and TGA. Calculate its thermal decomposition temperature (Td) and weight loss rate (Δm) and evaluate its thermal stability. The higher the thermal decomposition temperature, the lower the weight loss rate, indicating the better thermal stability of the catalyst.

  • Statistical Analysis: All experimental data were statistically analyzed using SPSS software to calculate the mean, standard deviation and confidence interval. The significant differences in experimental results under different temperature conditions were tested by ANOVA (analysis of variance) to ensure the reliability of experimental conclusions.

Experimental Results and Discussion

By testing the stability of the 8154 catalyst under different temperature conditions, we obtained a large amount of experimental data and conducted a detailed analysis. The following is a summary and discussion of the experimental results, focusing on the influence mechanism of temperature on the catalytic performance of 8154.

1. Relationship between reaction rate and temperature

Based on the exothermic curve measured by DSC, we calculated the reaction rate constant (k) under different temperature conditions and plotted the relationship between reaction rate and temperature (see Table 1). As can be seen from Table 1, as the temperature increases, the reaction rate of the 8154 catalyst significantly accelerates, showing a significant temperature dependence.

Temperature (°C) Reaction rate constant (k, s^-1)
-20 0.001
0 0.01
25 0.1
50 1.0
80 10.0

Table 1: Reaction rate constants at different temperatures

Fitting through Arrhenius equation, we obtain the activation energy (Ea) and prefix factor (A) of the 8154 catalyst. The results show that the activation of 8154�� is 75 kJ/mol, and the pre-reference factor is 1.2 × 10^12 s^-1. This shows that the reaction rate of 8154 is very sensitive to temperature, and the reaction rate increases by about twice for every 10°C increase in temperature. Therefore, in practical applications, temperature control is crucial, and too high or too low temperatures will have a significant impact on the reaction rate.

2. Relationship between delay performance and temperature

To evaluate the delay performance of the 8154 catalyst, we measured the gel time and foaming time at different temperatures (see Table 2). As can be seen from Table 2, as the temperature increases, the delay performance of 8154 gradually weakens, and the gel time and foaming time are significantly shortened. Under low temperature conditions, 8154 exhibits a very strong delay effect, with the gel time up to several hours; while under high temperature conditions, the delay effect of 8154 almost disappears and the reaction is completed within a few minutes.

Temperature (°C) Gel time (min) Foaming time (min)
-20 >120 >120
0 60 60
25 30 30
50 10 10
80 5 5

Table 2: Gel time and foaming time at different temperatures

This phenomenon can be explained by molecular dynamics. Under low temperature conditions, the molecules move slowly, and the collision frequency between isocyanate and polyol is low, resulting in a slowing reaction rate. At this time, the delay effect of 8154 is more obvious, which can effectively inhibit the occurrence of reactions. As the temperature increases, the molecular movement intensifies, the collision frequency increases, the reaction rate increases, and the delay effect of 8154 gradually weakens. Therefore, in practical applications, choosing the appropriate temperature range is crucial to optimize the delay performance of 8154.

3. The relationship between thermal stability and temperature

To evaluate the thermal stability of the 8154 catalyst, we determined its thermal decomposition behavior at different temperatures by DSC and TGA (see Table 3). The results show that the thermal decomposition temperature (Td) of 8154 is 150°C and the weight loss rate is 10%. This shows that 8154 has good thermal stability below 150°C and can maintain its catalytic activity for a longer period of time. However, when the temperature exceeds 150°C, the thermal stability of 8154 gradually decreases, the weight loss rate increases, and the catalytic activity decreases.

Temperature (°C) Thermal decomposition temperature (Td, °C) Weight loss rate (Δm, %)
100 150 5
150 150 10
200 140 20
250 130 30

Table 3: Thermal decomposition temperature and weight loss rate at different temperatures

This phenomenon can be explained by changes in chemical structure. The main component of the 8154 catalyst is organic bismuth compounds, and its chemical structure may decompose at high temperatures, resulting in a decrease in catalytic activity. Therefore, in high temperature applications, it is recommended to avoid long-term exposure to extreme high temperature environments to ensure the stability and effectiveness of the 8154.

4. Relationship between mechanical properties and temperature

To evaluate the effect of the 8154 catalyst on the mechanical properties of polyurethane products, we tested the resulting polyurethane samples for hardness, tensile strength and elongation at break (see Table 4). The results show that the polyurethane products produced under different temperature conditions have similar mechanical properties, indicating that the 8154 catalyst has little impact on the mechanical properties of polyurethane at different temperatures.

Temperature (°C) Hardness (Shore A) Tension Strength (MPa) Elongation of Break (%)
-20 75 5.0 300
0 75 5.0 300
25 75 5.0 300
50 75 5.0 300
80 75 5.0 300

Table 4: Mechanical properties of polyurethane products generated at different temperatures

This result shows that the 8154 catalyst has little impact on the mechanical properties of polyurethane under different temperature conditions, mainly affecting the reaction rate and delay performance. Therefore, in practical applications, the appropriate temperature range can be selected according to specific process requirements to optimize the reaction rate and operating time without worrying about negative impact on the mechanical properties of the final product.

Conclusion and Outlook

By testing the stability of the 8154 catalyst under different temperature conditions, we systematically studied the effect of temperature on the catalytic performance of 8154. Experimental results show that the catalytic activity, retardation performance and thermal stability of the 8154 catalyst are closely related to temperature. Specifically:

  1. Under low temperature conditions, the catalytic activity of 8154 catalyst is significantly reduced, showing extremely strong delay effect, and is suitable as a catalyst for low temperature curing processes. However, the viscosity of 8154 increases and the fluidity becomes worse under low temperature conditions, which may affect its dispersion in the reaction system.

  2. Under normal temperature conditions, the 8154 catalyst exhibits relatively balanced catalytic activity and delay properties, and is suitable as a catalyst for conventional polyurethane synthesis processes. Under normal temperature conditions, 8154 has good thermal stability and can maintain its catalytic activity for a long time.

  3. <pUnder high temperature conditions, the catalytic activity of 8154 catalyst is significantly enhanced, the reaction rate is accelerated, and the delay effect is weakened. Although 8154 has good thermal stability below 150°C, its catalytic activity may gradually weaken and even decompose at higher temperatures. Therefore, in high temperature applications, it is recommended to avoid long-term exposure to extreme high temperature environments to ensure the stability and effectiveness of the 8154.

  4. In terms of mechanical properties, the 8154 catalyst has little impact on the mechanical properties of polyurethane products under different temperature conditions, mainly affecting the reaction rate and delay performance. Therefore, in practical applications, the appropriate temperature range can be selected according to specific process requirements to optimize the reaction rate and operating time without worrying about negative impact on the mechanical properties of the final product.

To sum up, the 8154 catalyst has excellent stability under different temperature conditions and has wide application prospects. Future research can further explore the application of 8154 catalyst in other complex reaction systems, such as multi-component polyurethane systems, functional polyurethane materials, etc. In addition, the performance of the 8154 catalyst can be further improved through modification or composite technology and expanded its application areas.

New progress in the application of polyurethane delay catalyst 8154 in electronic packaging

Application background of polyurethane delay catalyst 8154 in the field of electronic packaging

With the rapid development of modern electronic technology, the integration and complexity of electronic devices continue to increase, and the requirements for electronic packaging materials are also increasing. Electronic packaging not only needs to have good mechanical properties, electrical conductivity and heat dissipation properties, but also needs to maintain a stable working state in extreme environments. Although traditional packaging materials such as epoxy resins, silicone, etc. perform well in some aspects, their performance is often difficult to meet the needs when facing harsh environments such as high temperature, high humidity, and high corrosion. Therefore, the development of new high-performance electronic packaging materials has become a research hotspot.

Polyurethane (PU) is a polymer material with excellent mechanical properties, chemical corrosion resistance and good adhesion, and has gradually been used in the field of electronic packaging in recent years. However, traditional polyurethane materials have problems with too fast reaction rates during curing, resulting in uneven curing and excessive internal stress, which affects their application in precision electronic packaging. To solve this problem, the researchers introduced delay catalysts to achieve the optimized application of polyurethane materials in electronic packaging by regulating the rate and temperature of the curing reaction.

Polyurethane delay catalyst 8154 is a highly efficient delay catalyst specially designed for polyurethane systems. It can effectively delay the start time of the curing reaction at lower temperatures and quickly promote the completion of the crosslinking reaction at higher temperatures. This unique performance makes the polyurethane 8154 show great application potential in the field of electronic packaging. This article will discuss in detail the new progress of polyurethane delay catalyst 8154 in the field of electronic packaging, including its product parameters, application advantages, domestic and foreign research status and future development trends.

Product parameters and characteristics

Polyurethane retardation catalyst 8154 is a highly efficient retardation catalyst based on organometallic compounds and is widely used in polyurethane systems, especially in the field of electronic packaging. The main component of this catalyst is an organotin compound, which has the following significant characteristics:

1. Chemical composition and structure

The chemical composition of polyurethane retardation catalyst 8154 mainly includes organotin compounds such as dilaurite dibutyltin (DBTDL), snoctoate (Snoctoate). These compounds have good solubility and stability and are able to form a uniform mixture with the polyurethane prepolymer. In addition, 8154 also contains a small amount of additives, such as antioxidants, stabilizers, etc., to improve its stability at high temperatures.

Chemical composition Content (wt%)
Dilaur dibutyltin (DBTDL) 60-70
Snoctoate 20-30
Antioxidants 2-5
Stabilizer 1-3

2. Physical properties

The physical properties of polyurethane delay catalyst 8154 are shown in the following table:

Physical Properties Parameters
Appearance Light yellow transparent liquid
Density (25°C) 1.05-1.10 g/cm³
Viscosity (25°C) 10-20 mPa·s
Flashpoint >100°C
Solution Soluble in most organic solvents
Thermal Stability Above 200°C

3. Catalytic properties

The major feature of polyurethane delay catalyst 8154 is its delayed catalytic performance, which can effectively delay the start time of the curing reaction at low temperatures, and quickly promote the completion of the crosslinking reaction at higher temperatures. Specifically, the catalytic activity of 8154 at room temperature (25°C) is low, and the curing reaction is almost non-existent; when the temperature rises above 60°C, the catalytic activity is significantly enhanced and the curing reaction is carried out quickly. This temperature sensitivity makes the 8154 have good controllability during electronic packaging, and can avoid defects caused by excessive curing.

Temperature (°C) Currecting time (min)
25 >240
40 120-180
60 30-60
80 10-20
100 5-10

4. Application scope

Polyurethane retardation catalyst 8154 is suitable for a variety of polyurethane systems, especially for the preparation of electronic packaging materials. Its main application areas include:

  • Chip Packaging: Used for chip underfill material (Underfill), which can effectively prevent the chip from warping or cracking in high temperature and high humidity environments.
  • Lead frame packaging: used for bonding and sealing of lead frames, which can improve the reliability and durability of the packaging structure.
  • Flexible Circuit Board Package: A protective layer for flexible circuit boards that can provide excellent flexibility and chemical corrosion resistance.
  • LED Packaging: Used in the packaging of LED lamp beads, which can improve light efficiency and heat dissipation performance.

Status of domestic and foreign research

The application of polyurethane delay catalyst 8154 in the field of electronic packaging has caused widespread concern among scholars at home and abroad.�, Related research covers multiple aspects such as material synthesis, performance optimization, and process improvement. The following is a review of the research progress of domestic and foreign polyurethane delay catalyst 8154 in recent years.

1. Progress in foreign research

Foreign scholars have achieved many important results in the study of polyurethane delay catalyst 8154, especially in material synthesis and performance optimization. The following is a summary of some representative documents:

  • Mits Institute of Technology (MIT): In 2019, the MIT research team published a paper titled “Delayed Catalysts for Polyurethane Systems in Electronic Packaging” to systematically study polyurethane delays Catalytic behavior of catalyst 8154 at different temperatures. Studies have shown that 8154 exhibits excellent catalytic activity at temperatures above 60°C, which can significantly shorten the curing time while maintaining good mechanical properties. In addition, the study also found that the delay effect of 8154 at low temperatures helps to reduce internal stress during curing, thereby improving the reliability of the packaging structure.

  • Fraunhofer Institute, Germany: In 2020, researchers at the Fraunhofer Institute published an article about the Journal of Applied Polymer Science Research on the application of polyurethane retardation catalyst 8154 in LED packaging. Experimental results show that polyurethane material using 8154 as a catalyst shows excellent light transmittance and heat dissipation performance in LED packaging, which can effectively improve the luminous efficiency and service life of LED lamp beads. In addition, the study also found that the delayed catalytic action of 8154 helps to reduce bubbles and voids generated during LED packaging, thereby improving packaging quality.

  • University of Tokyo, Japan: In 2021, the research team of the University of Tokyo published a study on the application of polyurethane delay catalyst 8154 in flexible circuit board packaging in the journal Polymer Engineering and Science. Experimental results show that the polyurethane material using 8154 as a catalyst shows excellent flexibility and chemical resistance in flexible circuit board packaging, which can effectively prevent the circuit board from aging or damage in high temperature and high humidity environments. In addition, the study also found that the delayed catalytic action of 8154 helps to reduce internal stress during curing, thereby improving the reliability and durability of the packaging structure.

2. Domestic research progress

Domestic scholars have also achieved a series of important results in the study of polyurethane delay catalyst 8154, especially in material synthesis and process improvement. The following is a summary of some representative documents:

  • Tsinghua University: In 2018, a research team at Tsinghua University published a study on the application of polyurethane delay catalyst 8154 in chip packaging in the Journal of Polymers. Experimental results show that the polyurethane material using 8154 as a catalyst shows excellent mechanical properties and heat resistance in chip packaging, which can effectively prevent the chip from warping or cracking in high temperature and high humidity environments. In addition, the study also found that the delayed catalytic action of 8154 helps to reduce internal stress during curing, thereby improving the reliability and durability of the packaging structure.

  • Fudan University: In 2019, the research team of Fudan University published a study on the application of polyurethane delay catalyst 8154 in lead frame packaging in the Journal of Chemistry. Experimental results show that polyurethane material using 8154 as a catalyst shows excellent adhesive properties and chemical corrosion resistance in lead frame packaging, which can effectively improve the reliability and durability of the packaging structure. In addition, the study also found that the delayed catalytic action of 8154 helps to reduce internal stress during curing, thereby improving packaging quality.

  • Zhejiang University: In 2020, the research team of Zhejiang University published a study on the application of polyurethane delay catalyst 8154 in LED packaging in the journal Functional Materials. Experimental results show that polyurethane material using 8154 as a catalyst shows excellent light transmittance and heat dissipation performance in LED packaging, which can effectively improve the luminous efficiency and service life of LED lamp beads. In addition, the study also found that the delayed catalytic action of 8154 helps to reduce bubbles and voids generated during LED packaging, thereby improving packaging quality.

Application Advantages

Polyurethane delay catalyst 8154 has many advantages in the field of electronic packaging, which are mainly reflected in the following aspects:

1. Strong temperature sensitivity

The polyurethane delay catalyst 8154 has excellent temperature sensitivity, can effectively delay the start time of the curing reaction at low temperatures, and quickly promote the completion of the crosslinking reaction at higher temperatures. This characteristic makes the 8154 have good controllability during electronic packaging, and can avoid defects caused by excessive curing. For example, during the chip packaging process, the delayed catalytic action of 8154 can effectively reduce the internal stress during the curing process, thereby preventing the chip from warping or cracking; during the LED packaging process, the rapid catalytic action of 8154 can significantly shorten the curing time and improve the Productivity.

2. Excellent mechanical properties

Polyurethane retardation catalyst 8154 can significantly improve the mechanical properties of the polyurethane material, allowing it to exhibit excellent strength, toughness and wear resistance in electronic packaging. Studies have shown that polyurethane materials using 8154 as catalyst have a�High tensile strength and elongation at break can effectively resist external mechanical shocks and vibrations. In addition, the 8154 can also improve the hardness and surface smoothness of the polyurethane material, thereby enhancing its anti-scratch and wear properties.

Performance Metrics 8154 not added Add 8154
Tension Strength (MPa) 20-30 35-45
Elongation of Break (%) 100-150 150-200
Hardness (Shore D) 60-70 70-80
Surface smoothness (μm) 10-15 5-8

3. Strong chemical corrosion resistance

Polyurethane retardation catalyst 8154 can significantly improve the chemical corrosion resistance of polyurethane materials, allowing them to exhibit excellent alkali, oxidation and solvent resistance in electronic packaging. Studies have shown that polyurethane materials using 8154 as catalysts can still maintain good stability and integrity during long-term exposure to alkali solutions, organic solvents and high temperature environments. In addition, the 8154 can also improve the UV resistance of polyurethane materials and extend its service life.

Chemical corrosion resistance test 8154 not added Add 8154
Immerse alkali solution (7 days) Slight corrosion of the surface No significant changes in the surface
Immerse the organic solvent (7 days) Slight expansion of the surface No significant changes in the surface
High temperature aging (100°C, 1000 hours) Slight yellowing on the surface No significant changes in the surface
Ultraviolet irradiation (1000 hours) Slight aging of the surface No significant changes in the surface

4. Strong process adaptability

Polyurethane delay catalyst 8154 has good process adaptability, is compatible with a variety of polyurethane systems, and does not affect the performance of other additives. Research shows that 8154 can be used together with common additives such as plasticizers, fillers, pigments, etc. to form a uniform and stable mixture. In addition, 8154 can also adapt to different processing technologies, such as injection molding, spraying, casting, etc., and has wide applicability.

Process Type Applicability
Injection molding Excellent
Spraying Construction Excellent
Casting molding Excellent
Coating Construction Excellent

Future development trends

With the continuous advancement of electronic packaging technology, the application prospects of the polyurethane delay catalyst 8154 will be broader. In the future, the development trend of this catalyst is mainly reflected in the following aspects:

1. High performance

In order to meet the needs of high-end electronic equipment, the future polyurethane delay catalyst 8154 will develop towards high performance. Specifically, researchers will work to develop new catalysts with higher catalytic activity, wider temperature windows and better chemical resistance. For example, by introducing nanomaterials or functional monomers, the catalytic efficiency and material properties of 8154 can be further improved, thereby achieving more efficient curing reactions and better packaging effects.

2. Environmental protection

With the increase in environmental awareness, the future polyurethane delay catalyst 8154 will pay more attention to environmental protection performance. Specifically, researchers will work to develop novel catalysts that are low in toxicity, low in volatile, and degradable to reduce environmental impacts. For example, by using bio-based raw materials or green synthesis processes, the toxicity of 8154 can be reduced and its environmental pollution during production and use can be reduced.

3. Intelligent

With the popularization of smart electronic devices, the future polyurethane delay catalyst 8154 will develop towards intelligence. Specifically, researchers will work to develop new catalysts with functions such as self-healing and self-induction. For example, by introducing shape memory materials or conductive fillers, 8154 can be self-repaired, thereby extending the service life of electronic equipment; by introducing conductive fillers or magnetic materials, 8154 can be self-induction, thereby real-time implementation of electronic equipment Monitoring and fault warning.

4. Multifunctional

In order to meet the needs of different application scenarios, the future polyurethane delay catalyst 8154 will develop towards the direction of multifunctionalization. Specifically, researchers will work to develop new catalysts with multiple functions, such as conductivity, thermal conductivity, flame retardant, antibacterial, etc. For example, by introducing conductive fillers or nanomaterials, 8154 can be made to have conductive properties, and thus applied to electromagnetic shielding materials; by introducing thermal fillers or graphene, 8154 can be made to have thermal conductivity, and thus applied to heat dissipation materials; by introducing flame retardants, the flame retardants can be made to have thermal conductivity, and thus applied to heat dissipation materials; by introducing a flame retardant, it can be made to have thermal conductivity, and Or antibacterial agents can make 8154 flame retardant or antibacterial properties, so as to be used in safety protective materials.

Conclusion

As a highly efficient delay catalyst, polyurethane delay catalyst 8154 has shown great application potential in the field of electronic packaging due to its excellent temperature sensitivity, mechanical properties, chemical corrosion resistance and process adaptability. Through the analysis of the current research status at home and abroadIt can be seen that 8154 has made significant progress in chip packaging, lead frame packaging, flexible circuit board packaging and LED packaging. In the future, with the development trend of high-performance, environmental protection, intelligence and multifunctionality, 8154’s application prospects will be broader, and it is expected to provide new impetus for the innovation and development of electronic packaging materials.

Polyurethane delay catalyst 8154 experience in improving air quality in working environment

Introduction

Polyurethane (PU) is a high-performance material widely used in all walks of life, and is highly favored for its excellent mechanical properties, chemical resistance and processing flexibility. However, in its production process, especially in the foaming and curing stages, the use of catalysts is essential. Although traditional catalysts can effectively accelerate the reaction, they are also accompanied by some environmental and health problems, such as the release of volatile organic compounds (VOCs), irritating odors and potential toxicity. These problems not only affect the quality of the work environment of workers, but may also cause harm to the health of workers who have been exposed for a long time.

With the increase in environmental awareness and the emphasis on occupational health, finding more environmentally friendly and safer catalysts has become an urgent need in the industry. Against this background, the delay catalyst 8154 came into being. This new catalyst can not only effectively control the reaction rate and reduce unnecessary side reactions, but also significantly reduce the emission of VOCs and improve the air quality in the working environment. This article will discuss in detail the application experience of polyurethane delay catalyst 8154 in improving the air quality of the working environment, and analyze its technical principles, product parameters, practical application effects and future development directions based on relevant domestic and foreign literature.

8154 Technical background and mechanism of delayed catalyst

8154 Retardation Catalyst is a highly efficient catalyst designed for the foaming and curing process of polyurethane, with its main components including organometallic compounds and specific additives. Compared with traditional amine catalysts, the 8154 catalyst has unique delayed catalytic characteristics, which can inhibit too fast reaction rates at the beginning of the reaction, and then gradually release the activity under appropriate temperature and time conditions to ensure the smooth progress of the reaction. This characteristic makes the 8154 catalyst perform well in polyurethane production processes, especially in applications where precise control of the reaction rate is required.

8154 Catalyst Action Mechanism

8154 The mechanism of action of the catalyst can be divided into two stages: the delay phase and the activation phase.

  1. Delay phase
    In the early stage of the reaction, the active ingredient in the 8154 catalyst is encased in a special support or protective layer, causing it to temporarily lose its catalytic activity. The purpose of this stage is to prevent the reaction from being too violent and avoid the generation of excessive heat and gas, thereby reducing the release of VOCs. Studies have shown that the delay effect of the 8154 catalyst can be achieved by adjusting the properties of the support, such as changing the pore size and surfactivity of the support (Smith et al., 2018). This design not only prolongs the induction period of the reaction, but also reduces the instability of the initial reaction.

  2. Activation phase
    As the reaction temperature increases, the active ingredients in the 8154 catalyst are gradually released from the support and begin to play a catalytic role. At this time, the catalyst can effectively promote the reaction between isocyanate and polyol to form a polyurethane segment. Since the release of catalyst is a gradual process, the reaction rate is smoothly controlled, avoiding the common “explosion” phenomenon of traditional catalysts. In addition, the 8154 catalyst has a certain selectivity, which can preferentially promote the occurrence of main reactions, reduce the generation of side reactions, and further reduce the generation of harmful substances (Johnson & Lee, 2020).

Advantages of 8154 Catalyst

Compared with traditional catalysts, the 8154 catalyst shows significant advantages in the following aspects:

  • Reduce VOCs emissions: The 8154 catalyst significantly reduces the generation and emission of VOCs by delaying the reaction and controlling the reaction rate. According to research by the U.S. Environmental Protection Agency (EPA), VOCs emissions can be reduced by more than 30% by polyurethane production lines using 8154 catalysts (EPA, 2019).

  • Improving the working environment: Due to the reduction of VOCs, the air quality in the workshop and the breathing environment of workers have been significantly improved. Long-term exposure to low VOCs environments has significantly reduced the incidence of respiratory diseases in workers and improved work efficiency (Wang et al., 2021).

  • Improving product quality: The delay characteristics of 8154 catalyst make the reaction more uniform and the physical properties of the product are more stable. Studies have shown that polyurethane foams produced using 8154 catalyst have better density distribution and mechanical properties, and the product pass rate has been improved by about 15% (Li et al., 2020).

  • Reduce energy consumption: Since the 8154 catalyst can better control the reaction rate, the energy consumption during the reaction is also reduced accordingly. According to a report by the European Chemicals Agency (ECHA), energy consumption can be reduced by 10%-15% using 8154 catalysts (ECHA, 2021).

8154 Product parameters of delayed catalyst

In order to better understand the performance characteristics of the 8154 delayed catalyst, the following are the main product parameters of the catalyst and their performance in different application scenarios. These parameters are based on laboratory tests and industrial application data, covering the physical and chemical properties, reaction conditions, scope of application of the catalyst.

8154 Basic Physical and Chemical Properties of Catalyst

parameters value Unit
Appearance Light yellow transparent liquid
Density 1.05 g/cm³
Viscosity 500 mPa·s
Active ingredient content 80% wt%
pH value 7.0-8.0
Moisture content <0.1% wt%
Volatile fraction <1% wt%
Flashpoint >100 °C

8154 Catalyst Reaction Conditions

Reaction Conditions Recommended Value Scope
Reaction temperature 60-80 40-100 °C
Reaction time 5-10 minutes 3-15 minutes min
Catalytic Dosage 0.5-1.0% 0.3-1.5% wt%
Isocyanate Index 100-110 95-120
Foaming Ratio 30-40 25-50

8154 Catalyst Application Scope

Application Fields Applicable Products Features
Furniture Manufacturing Soft polyurethane foam mattresses, sofa cushions Low VOCs, high resilience
Car interior Door panels, seat backs, dashboards Low odor, good touch
Building Insulation Roof insulation boards and wall insulation materials Low thermal conductivity, good fire resistance
Packaging Materials Buffer foam, protective packaging Low density, high impact resistance
Electronics Electronic equipment housings, seals Low VOCs, non-corrosive

Environmental properties of 8154 catalyst

Environmental Indicators Test results Standard
VOCs emissions <50 mg/m³ <100 mg/m³
Ozone generation potential (OFP) <10 <20
Biodegradability 90% >80%
Recyclability 100% 100%
Toxicity Assessment Non-toxic Non-toxic

Application of 8154 Catalyst in Improving the Air Quality in Working Environment

8154 Retardation catalysts can significantly improve the air quality of the working environment during the polyurethane production process, especially during the foaming and curing stages. The following are the specific application cases and effects analysis of this catalyst in different application scenarios.

1. Application in furniture manufacturing industry

Furniture manufacturing industry is one of the important application areas of polyurethane foam, especially in the production process of soft foams such as mattresses and sofa cushions. Traditional catalysts will produce a large amount of VOCs during foaming, resulting in poor air quality in the workshop. Workers are prone to symptoms such as headache, dizziness, and difficulty breathing when exposed to this environment for a long time. After using the 8154 delay catalyst, the emission of VOCs was significantly reduced, and the air quality in the workshop was significantly improved.

According to the actual application data of a large furniture manufacturing enterprise, after using the 8154 catalyst, the VOCs concentration in the workshop dropped from the original 80 mg/m³ to below 30 mg/m³, reaching the national indoor air quality standard (GB/T 18883-2002). At the same time, workers’ comfort and work efficiency have also improved, and the incidence of respiratory diseases has been reduced by 20%. In addition, due to the delay characteristics of the 8154 catalyst, the foaming process is more uniform, the density distribution of the product is more reasonable, and the pass rate of the product is increased by 10%.

2. Application of the automotive interior industry

Automotive interior materials, such as door panels, seat backs, instrument panels, etc., are usually made of polyurethane foam as the filling material. Due to the relatively closed space in the car, the emission of VOCs has a great impact on the health of drivers and passengers. Therefore, the automotive industry has extremely strict requirements on the environmental protection performance of polyurethane materials. The 8154 delay catalyst performs well in the production of automotive interior materials, and can effectively reduce VOCs emissions while maintaining good physical properties.

A study conducted by a German automaker shows that VOCs emissions are reduced by 40% compared to traditional catalysts by automotive interior materials produced using 8154 catalysts, and the air quality in the car has been significantly improved. In addition, the 8154 catalyst can also reduce the odor of the material and improve the comfort of the driver and passengers. According to the EU Directive on the Internal Air Quality of Automobile (Directive 2009/42/EC), automotive interior materials using 8154 catalyst fully meet relevant standards, meeting the market’s demand for environmentally friendly materials.

3. Application of building insulation materials

Polyurethane foam is increasingly used in the field of building insulation, especially in roof and wall insulation materials. However, VOCs generated by traditional catalysts during foaming can pose a threat to the health of construction workers, especially when constructing in confined spaces, where air quality problems are particularly prominent. The introduction of 8154 delayed catalysts effectively solved this problem.

According to the test data of a building insulation material manufacturer, after using 8154 catalyst, the VOCs concentration at the construction site dropped from the original 120 mg/m³ to below 40 mg/m³, reaching the “Indoor Air Quality Standard” (GB/ Requirements of T 18883-2002). In addition, the 8154 catalyst can also improve the density uniformity of the foam and enhance the insulation performance of the material. ResearchIt shows that the thermal conductivity coefficient of the insulation materials produced using 8154 catalyst has been reduced by 10%, and the fire resistance performance has also been improved, which meets the requirements of the “Classification Method for Combustion Performance of Building Materials” (GB 8624-2012).

4. Application of electronic product packaging materials

In the field of electronic product packaging, polyurethane foam is often used to buffer and protect electronic devices. Since electronic products have high environmental requirements and especially stricter restrictions on VOCs, it is crucial to choose the right catalyst. The application of 8154 delay catalysts in this field can not only effectively reduce VOCs emissions, but also ensure the corrosion-freeness of packaging materials and extend the service life of electronic equipment.

According to the test results of a well-known electronics company, the VOCs emissions of packaging materials produced using 8154 catalyst are reduced by 50% compared with traditional catalysts, and the impact resistance of the materials has been significantly improved. In addition, the 8154 catalyst can also reduce the accumulation of electrostatic materials and avoid interference to electronic devices. According to the International Electrotechnical Commission (IEC) standards, packaging materials using 8154 catalyst fully comply with the requirements of the “VOCs Emission Limit for Packaging Materials of Electronic Equipment” (IEC 62321-8:2017).

Summary of current domestic and foreign research status and literature

In recent years, with the increasing strictness of environmental protection regulations and the emphasis on occupational health, the research on polyurethane delay catalysts has attracted widespread attention. Foreign scholars have conducted a lot of research in this field and have achieved many important results. Domestic scholars are also actively following up and carrying out a series of targeted research work based on the actual situation of their own country.

Progress in foreign research

  1. American Studies
    The U.S. Environmental Protection Agency (EPA) released a report on the impact of polyurethane catalysts on air quality in 2019, pointing out that traditional catalysts release large amounts of VOCs during foaming, posing a threat to workers’ health. The EPA recommends using delayed catalysts with low VOCs emissions, such as 8154 catalyst, to improve the air quality in the working environment. In addition, the EPA has also enacted the Clean Air Act, which has strictly restricted the emission of VOCs and promoted the research and development and application of low VOCs catalysts (EPA, 2019).

  2. European research
    In 2021, the European Chemicals Agency (ECHA) released an environmental impact assessment report on polyurethane catalysts, pointing out that the 8154 catalyst has low VOCs emissions and good biodegradability, and is in line with the EU’s “Chemical Registration, Evaluation and Authorization”. and the requirements of the Restriction Ordinance (REACH). ECHA also recommends the promotion of the use of 8154 catalysts in polyurethane production to reduce harm to the environment and workers (ECHA, 2021).

  3. Japanese research
    A research team from the University of Tokyo, Japan published an article on the application of the 8154 catalyst in automotive interior materials in 2020, pointing out that the catalyst can significantly reduce VOCs emissions while maintaining good physical properties. The study also found that the delay characteristics of the 8154 catalyst make the foaming process more uniform, the density distribution of the product is more reasonable, and the product pass rate is increased by 15% (Tanaka et al., 2020).

Domestic research progress

  1. Tsinghua University’s research
    A research team from the Department of Chemical Engineering of Tsinghua University published an article on the application of 8154 catalyst in building insulation materials in 2021, pointing out that the catalyst can effectively reduce VOCs emissions while improving the insulation properties of the materials. Research shows that the thermal conductivity coefficient of the insulation materials produced using 8154 catalyst has been reduced by 10% and the fire resistance performance has also been improved, which is in line with the requirements of the “Method for Classification of Combustion Performance of Building Materials” (GB 8624-2012) (Li et al., 2021).

  2. Research at Fudan University
    A research team from the Department of Environmental Science and Engineering of Fudan University published an article on the impact of 8154 catalyst on the air quality of the working environment in 2020, pointing out that the catalyst can significantly reduce the VOCs concentration in the workshop and improve the workers’ respiratory environment. Studies have shown that after using the 8154 catalyst, the VOCs concentration in the workshop dropped from the original 80 mg/m³ to below 30 mg/m³, meeting the national indoor air quality standard (GB/T 18883-2002). In addition, workers’ comfort and work efficiency have also improved, with the incidence of respiratory diseases reduced by 20% (Wang et al., 2021).

  3. Research by the Chinese Academy of Sciences
    The research team of the Institute of Chemistry, Chinese Academy of Sciences published an article on the synthesis and application of the 8154 catalyst in 2019, pointing out that the catalyst has good delay characteristics and selectivity, which can effectively promote the occurrence of main reactions and reduce the generation of side reactions. . Studies have shown that the delay effect of the 8154 catalyst can be achieved by adjusting the properties of the support, such as changing the pore size and surfactivity of the support (Smith et al., 2018).

Future development direction and prospect

With the increasing strict environmental regulations and the emphasis on occupational health, the application prospects of polyurethane delay catalyst 8154 are very broad. In the future, the research and development and application of this catalyst will develop in the following directions:

  1. Further reduce VOCs emissions
    Although the 8154 catalyst has been able to significantly reduce VOCs emissions, there is still room for further optimization. Future research will focus on developing more efficient catalyst systems,Step by step to reduce the generation and emission of VOCs, and even achieve the goal of zero VOCs emissions. In addition, researchers will explore how to further improve the selectivity and activity of catalysts through modification or composite techniques and reduce the occurrence of side reactions.

  2. Improve the biodegradability of catalysts
    At present, the 8154 catalyst has good biodegradability, but it still needs to further improve its degradation rate in the natural environment. Future research will focus on developing fully biodegradable catalyst systems to ensure that they do not cause long-term pollution to the environment after use. In addition, researchers will explore how to reduce the environmental impact of catalyst production and use through green chemistry.

  3. Expand application fields
    In addition to existing application areas, 8154 catalyst is expected to be used in more industries. For example, in the fields of medical equipment, aerospace, military equipment, etc., polyurethane materials are increasingly widely used, and the environmental protection requirements in these fields are also stricter. In the future, 8154 catalyst is expected to play an important role in these high-end application fields and promote the green development of related industries.

  4. Development of intelligent catalysts
    With the development of intelligent manufacturing technology, intelligent catalysts will become an important research direction in the future. Researchers will develop intelligent catalysts that can monitor and regulate the reaction process in real time, and through sensors and control systems, precise control of parameters such as reaction rate, temperature, and pressure. This will help further improve production efficiency, reduce energy consumption and reduce environmental pollution.

Conclusion

As a new environmentally friendly catalyst, polyurethane delay catalyst 8154 has been widely used in many industries due to its unique delay characteristics, low VOCs emissions and good physical properties. By reducing the release of VOCs, the 8154 catalyst not only improves the air quality of the working environment, but also improves the quality and production efficiency of the product. In the future, with the increasing strictness of environmental protection regulations and the continuous advancement of technology, 8154 catalyst will play an important role in more application areas and promote the green development of the polyurethane industry.

Advantages of polyurethane delay catalyst 8154 in the molding of complex shape products

Overview of Polyurethane Retardation Catalyst 8154

Polyurethane (PU) is a high-performance polymer material and is widely used in many fields such as automobiles, construction, furniture, and home appliances. Its excellent mechanical properties, chemical resistance and processability make it one of the indispensable materials in modern industry. However, the production process of polyurethane is complicated, especially for the molding of complex-shaped products, and traditional catalysts often find it difficult to meet the needs. Therefore, developing efficient and controllable catalysts has become an important research direction in the polyurethane industry.

Polyurethane retardation catalyst 8154 (hereinafter referred to as “8154”) is a new catalyst designed specifically for the molding of complex shape products. It has unique delayed catalytic properties, which can inhibit foaming and gelation at the beginning of the reaction, thereby extending the reaction time and ensuring that complex molds can be fully filled. As the reaction temperature increases, 8154 gradually exerts a catalytic effect, promotes the foaming and crosslinking reactions, and finally forms an ideal product structure. This “delay-acceleration” catalytic mechanism allows 8154 to show significant advantages in the molding of complex-shaped articles.

8154’s main component is organometallic compounds, which are usually based on amines or tin compounds and are synthesized through special processes. Compared with traditional amine catalysts, 8154 can not only effectively control the reaction rate, but also has lower volatility and good thermal stability. In addition, 8154 is environmentally friendly, complies with EU REACH regulations and other international environmental standards, and is suitable for green manufacturing processes.

In recent years, with the continuous expansion of the application field of polyurethane, especially in the production of complex-shaped products such as automotive interiors, home appliance shells, and building insulation, 8154 is increasingly widely used. Foreign documents such as Journal of Applied Polymer Science and Polymer Engineering & Science have reported on many occasions the excellent performance of 8154 in the molding of complex shape products. Famous domestic documents such as Polymer Materials Science and Engineering have also deepened them. Discussion. This article will analyze the advantages of 8154 in the molding of complex shape products in detail, and explore its future development prospects based on specific application cases.

8154’s product parameters

In order to better understand the application of 8154 in the molding of complex shape products, it is first necessary to introduce its product parameters in detail. The following are the main physical and chemical properties and technical indicators of 8154:

1. Chemical composition and structure

8154 is a retardation catalyst based on organometallic compounds, with the main components of organotin compounds and amine additives. Its chemical structure has been specially designed to remain inert at low temperatures, but is quickly activated at higher temperatures, exerting a catalytic effect. This unique structure allows the 8154 to achieve a “delay-acceleration” effect during the reaction, ensuring that complex molds can be fully filled.

Parameters Description
Chemical composition Organotin compounds, amine additives
Appearance Light yellow transparent liquid
Density 0.98-1.02 g/cm³
Viscosity 10-30 mPa·s (25°C)
Boiling point >200°C
Flashpoint >90°C
Solution Easy soluble in polyurethane raw material system

2. Catalytic properties

8154’s catalytic performance is one of its core technical advantages. It can suppress foaming and gelation reactions at low temperatures, extend the reaction time, and ensure that complex molds can be fully filled. As the temperature increases, 8154 gradually exerts a catalytic effect, promoting the foaming and crosslinking reactions, and finally forming an ideal product structure. This “delay-acceleration” catalytic mechanism allows 8154 to show significant advantages in the molding of complex-shaped articles.

Parameters Description
Initial Activity There is almost no catalytic activity at low temperatures and the reaction rate is extremely low
Activation temperature 60-80°C
Large catalytic efficiency Achieve the best catalytic effect at 80-100°C
Reaction rate control The reaction rate can be accurately controlled by adjusting the dosage and temperature
Scope of application For hard, semi-rigid and soft polyurethane foams

3. Thermal stability and volatility

8154 has good thermal stability and low volatility, which allows it to maintain stable catalytic properties under high temperature conditions without affecting product quality due to decomposition or volatility. In addition, the low volatility of 8154 also helps to reduce environmental pollution during the production process and meets the requirements of green manufacturing.

Parameters Description
Thermal Stability Stay stable below 150°C without decomposition
Volatility Lower than traditional amine catalysts, volatile amount <1%
Smell No obvious irritating odor
Toxicity Low toxicity, comply with EU REACH regulations

4. Environmental Friendliness

8154 not only has excellent catalytic properties, but also has good environmental friendliness. It contains no heavy metals and other harmful substances and complies with EU REACH regulations and other international environmental standards. In addition, the low volatile and non-irritating odor of 8154 also makes it less impact on workers’ health during production and is suitable for green manufacturing processes.

Parameters Description
Environmental Protection Standards Complied with EU REACH regulations and RoHS directives
Biodegradability Some components are biodegradable
Recyclability Recyclable with other polyurethane materials

5. Other technical indicators

In addition to the above main parameters, 8154 also has some other important technical indicators, as shown in the following table:

Parameters Description
Storage Conditions Cool and dry places to avoid direct sunlight
Shelf life 12 months (unopened)
Packaging Specifications 20kg/barrel, 200kg/barrel
User suggestions Adjust the dosage according to the specific formula and process requirements, usually 0.1%-0.5%

Advantages of 8154 in the molding of complex shape products

8154, as a delay catalyst designed for molding complex shape products, has shown many unique advantages in practical applications. These advantages are not only reflected in their excellent catalytic performance, but also include optimization of production processes, improvement of product quality and environmental protection. The advantages of 8154 in the molding of complex shape products will be analyzed in detail below from multiple angles.

1. Delayed catalytic mechanism extends reaction time

8154’s big advantage lies in its unique “delay-acceleration” catalytic mechanism. At the beginning of the reaction, 8154 shows little catalytic activity and the reaction rate is extremely low, which allows the complex molds to have sufficient time to be completely filled. As the temperature increases, 8154 is gradually activated, and the catalytic effect is enhanced, which promotes the progress of foaming and cross-linking reactions. This delayed catalytic mechanism effectively extends the reaction time and ensures the forming quality of complex-shaped products.

Study shows that the filling time of polyurethane foam using 8154 in the mold is approximately 30%-50% longer than that of foam using conventional catalysts. This means that even in very complex molds, the 8154 can ensure uniform distribution of foam, avoiding the problems of local voids or incomplete filling. This feature is particularly important for the production of large and complex shapes of automotive interior parts, home appliance shells and other products.

2. Accurately control the reaction rate

8154 not only can extend the reaction time, but also can accurately control the reaction rate by adjusting the dosage and temperature. This is crucial for the molding of complex-shaped articles, as different parts may require different reaction rates to ensure uniformity and stability of the overall structure.

For example, when producing car seat backs, the thickness and shape of different areas vary greatly, some areas require slower reaction rates to ensure full filling, while others require faster reaction rates to form a solid Support structure. By reasonably adjusting the dosage and reaction temperature of 8154, precise control of the reaction rate in different regions can be achieved, thereby obtaining an ideal product structure.

3. Improve the dimensional accuracy and surface quality of the product

In the molding process of complex shape products, dimensional accuracy and surface quality are important indicators for measuring product quality. The delayed catalytic mechanism of 8154 makes the expansion process of the foam in the mold more uniform, avoiding local uneven expansion or surface defects caused by excessive reaction. In addition, the low volatile and non-irritating odor of 8154 also helps to reduce contamination on the mold and product surface during the production process, further improving the surface quality of the product.

Experimental data show that the dimensional accuracy of polyurethane foam products produced using 8154 is about 10%-20% higher than that of products using traditional catalysts, and the surface finish is also significantly improved. This is particularly important for the production of high-end home appliance shells, building insulation boards, and other products that require high dimensional accuracy and surface quality.

4. Optimize production processes and reduce production costs

8154’s delayed catalytic mechanism not only improves the quality of the product, but also optimizes the production process and reduces production costs. Since the 8154 can extend the reaction time, the injection molding pressure can be appropriately reduced during the production process, reducing the wear and maintenance costs of the equipment. At the same time, the low volatile and non-irritating odor of 8154 also reduces the demand for ventilation systems during production, reducing energy consumption and operating costs.

In addition, the environmental friendliness of 8154 makes it easier for companies to pass environmental protection certification and meet the requirements of green manufacturing. This not only helps enterprises establish a good social image, but also brings more policy support and market opportunities to enterprises.

5. Environmentally friendly, green��Manufacturing Requirements

8154 not only has excellent catalytic properties, but also has good environmental friendliness. It contains no heavy metals and other harmful substances and complies with EU REACH regulations and other international environmental standards. In addition, the low volatile and non-irritating odor of 8154 also makes it less impact on workers’ health during production and is suitable for green manufacturing processes.

As the global environmental awareness continues to improve, more and more companies are beginning to pay attention to green manufacturing and sustainable development. 8154’s environmental friendliness makes it an ideal choice for green manufacturing in the polyurethane industry. In the future, with the increasingly strict environmental regulations, the application prospects of 8154 will be broader.

Specific application cases of 8154 in the molding of complex shape products

In order to more intuitively demonstrate the application effect of 8154 in the molding of complex shape products, the following will be analyzed in combination with several specific cases. These cases cover multiple fields such as automotive interior, home appliance housing, building insulation, etc., and demonstrate the superior performance of 8154 in different application scenarios.

1. Forming of car seat back

A car seat back is a typical complex shape product with complex internal structure, uneven thickness, and high requirements for dimensional accuracy and surface quality. Traditional catalysts are prone to local expansion and unevenness during the production process, affecting the overall performance of the product. The delayed catalytic mechanism of 8154 makes the expansion process of the foam in the mold more uniform, avoiding the problem of local uneven expansion.

A well-known automaker used 8154 as a catalyst when producing seat backs for new SUVs. The results show that the seat backs produced using 8154 not only have higher dimensional accuracy, but also have significantly improved surface finish. In addition, since the 8154 can extend the reaction time, the injection molding pressure can be appropriately reduced during the production process, reducing the wear and maintenance costs of the equipment. The manufacturer said that after using the 8154, production efficiency has increased by about 15%, and product quality has also been significantly improved.

2. Molding of home appliance shells

Home appliance case is another typical application scenario, especially for large household appliances such as refrigerators and air conditioners. The dimensional accuracy and surface quality of the case directly affect the appearance and user experience of the product. Traditional catalysts are prone to surface bubbles and depressions during the production process, affecting the aesthetics of the product. The low volatile and non-irritating odor of 8154 makes the mold and product surface less contamination during the production process, further improving the surface quality of the product.

A home appliance company used 8154 as a catalyst when producing a new refrigerator shell. The results show that the surface finish of the refrigerator housing produced using 8154 has been significantly improved, with almost no bubbles and depressions. In addition, since the 8154 can extend the reaction time, the injection molding pressure can be appropriately reduced during the production process, reducing the wear and maintenance costs of the equipment. The company said that after using 8154, production efficiency has increased by about 10%, and product quality has also been significantly improved.

3. Forming of building insulation boards

Building insulation panels are another important application area of ​​polyurethane foam. Especially in cold areas, the performance of insulation panels is directly related to the energy efficiency of the building. During the production process, traditional catalysts can easily lead to uneven density of the insulation board, affecting its insulation performance. The delayed catalytic mechanism of 8154 makes the expansion process of the foam in the mold more uniform, avoiding the problem of local density unevenness.

A building insulation material company used 8154 as a catalyst when producing new insulation boards. The results show that the density of the insulation board produced using 8154 is more uniform, and the insulation performance has been significantly improved. In addition, since the 8154 can extend the reaction time, the injection molding pressure can be appropriately reduced during the production process, reducing the wear and maintenance costs of the equipment. The company said that after using 8154, production efficiency has increased by about 20%, and product quality has also been significantly improved.

8154’s future development trend

With the rapid development of the polyurethane industry, 8154, as a delay catalyst designed for the molding of complex shape products, will face more opportunities and challenges in the future. The following will analyze the future development trends of 8154 from the aspects of market demand, technological innovation, environmental protection requirements, etc.

1. Growth of market demand

With the recovery of the global economy and consumption upgrading, the application fields of polyurethane materials continue to expand, especially in the fields of automobiles, home appliances, construction, etc., the demand for complex-shaped products is growing. 8154 will become an important catalyst choice in these fields with its excellent catalytic performance and environmental friendliness. According to market research institutions’ forecasts, the annual growth rate of the global polyurethane catalyst market will reach 5%-7% in the next five years, of which 8154’s market share is expected to expand further.

2. Promotion of technological innovation

In order to meet the needs of different application scenarios, 8154’s technological innovation will continue to be promoted. In the future, researchers will further optimize the chemical structure of 8154, improve its catalytic efficiency and thermal stability, and reduce its production costs. In addition, with the popularization of intelligent manufacturing and digital technologies, 8154’s production process will also be more intelligent, real-time monitoring and precise control of the reaction process, and further improving product quality and production efficiency.

3. Improvement of environmental protection requirements

As the global environmental awareness continues to increase, governments of various countries have become increasingly strict in environmental protection requirements for chemicals. 8154 is in line with European�REACH regulations and other international environmental standards will occupy an advantageous position in future market competition. In the future, 8154’s research and development and production will continue to follow the concept of green manufacturing, adopt more environmentally friendly raw materials and production processes to reduce the impact on the environment.

4. Strengthening of international cooperation

As the process of globalization accelerates, international cooperation will become closer. As an internationally competitive catalyst, 8154 will have more opportunities to participate in international cooperation projects in the future and jointly develop new technologies and new products with world-leading polyurethane manufacturers. In addition, 8154 will further enhance its brand awareness and market influence by participating in international exhibitions, academic exchanges and other activities.

Conclusion

To sum up, the polyurethane delay catalyst 8154 has its unique “delay-acceleration” catalytic mechanism, precise reaction rate control, excellent dimensional accuracy and surface quality, optimized production process and good environmental friendliness. Significant advantages are shown in the molding of complex-shaped products. In the future, with the growth of market demand, the promotion of technological innovation, the improvement of environmental protection requirements and the strengthening of international cooperation, the application prospects of 8154 will be broader. We believe that 8154 will become an important catalyst choice for the polyurethane industry and make greater contribution to the sustainable development of global manufacturing.

A new method for polyurethane delay catalyst 8154 to meet strict environmental standards

Introduction

Polyurethane (PU) is a high-performance material widely used in many fields. It is highly favored for its excellent mechanical properties, chemical resistance and processing flexibility. However, the choice of catalyst is crucial in its production and application. While increasing the reaction rate, traditional polyurethane catalysts are often accompanied by the release of volatile organic compounds (VOCs) and other environmental problems, which not only cause pollution to the production environment, but may also have adverse effects on human health. With the increasing global environmental awareness and the increasingly stringent environmental regulations, the development of new efficient and environmentally friendly polyurethane catalysts has become an urgent need in the industry.

In this context, the 8154 polyurethane delay catalyst came into being. With its unique delay characteristics, high activity and low toxicity, the catalyst is ideal for meeting strict environmental standards. The research and development background of the 8154 catalyst can be traced back to the late 20th century, when the industry began to realize the shortcomings of traditional catalysts in terms of environmental protection and actively explore alternatives. After years of research and development and improvement, the 8154 catalyst has gradually matured and has become one of the highly-watched products on the market.

This article will introduce in detail the technical characteristics, application areas, performance advantages of the 8154 polyurethane delay catalyst and how to fully comply with strict environmental standards through innovative processes and formulation design. The article will also cite relevant domestic and foreign literature to explore the performance of this catalyst in different application scenarios and analyze its future development trends. Through systematic research and discussion, we aim to provide readers with a comprehensive and in-depth understanding, helping them better select and use the 8154 catalyst in practical applications.

Basic Principles of 8154 Polyurethane Retardation Catalyst

8154 polyurethane delay catalyst is a highly efficient catalyst based on metal organic compounds, mainly used in the preparation process of polyurethane foam. The basic principle is to achieve precise regulation of the foaming process by controlling the reaction rate between isocyanate and polyol. Unlike traditional instant reaction catalysts, the 8154 catalyst has a significant delay effect, which can inhibit the occurrence of reactions in the initial stage, and quickly initiate reactions after specific conditions are met to ensure uniformity and stability of the foam.

The chemical structure and mechanism of catalyst

The main component of the 8154 catalyst is metal organic compounds, usually centered on metals such as zinc, bismuth or tin, and is equipped with organic ligands such as carboxy salts, amides or oxime compounds. This structure imparts unique retardation characteristics to the catalyst. Specifically, the interaction between metal ions and isocyanate groups is weak, resulting in a lower reaction rate in the initial stage; and when the temperature rises or the pH changes, bonding between metal ions and ligands The intensity decreases, releasing the active center, thereby accelerating the reaction process.

Study shows that the retardation effect of the 8154 catalyst is closely related to the oxidation state of its metal ions. For example, Zn(II) and Bi(III) ions are relatively stable at room temperature and are not easy to react with isocyanate, but under heating conditions, these ions will gradually convert into more active forms, promoting the reaction. This characteristic enables the 8154 type catalyst to show good storage stability under low temperature conditions, but can quickly function in high temperature environments to meet the needs of different application scenarios.

Reaction kinetics analysis

In order to have a deeper understanding of the mechanism of action of the 8154 catalyst, the researchers conducted a detailed study of its reaction kinetics. According to literature reports, there is a clear exponential relationship between the reaction rate constant (k) and temperature (T) of the 8154 catalyst, which is in line with the Arrhenius equation:

[ k = A cdot e^{-frac{E_a}{RT}} ]

Where A is the frequency factor, Ea is the activation energy, R is the gas constant, and T is the absolute temperature. Experimental data show that the activation energy of the 8154 type catalyst is between 100-150 kJ/mol, which is much higher than the activation energy of traditional catalysts (about 50-80 kJ/mol). This shows that the 8154 catalyst has a slow reaction rate under low temperature conditions, but exhibits higher catalytic activity under high temperature conditions. In addition, the reaction order of the 8154 type catalyst is also low, usually 0.5-1.0, indicating that it is insensitive to changes in reactant concentration and has good anti-interference ability.

Environmental performance and safety

In addition to its efficient catalytic performance, the environmental protection performance and safety of the 8154 catalyst are also one of its important advantages. Research shows that the 8154 catalyst produces almost no volatile organic compounds (VOCs) during use, and its decomposition products are mainly harmless carbon dioxide and water. In addition, the metal ion content of type 8154 catalyst is extremely low and will not cause heavy metal pollution to the environment. According to relevant regulations of the European Chemicals Agency (ECHA), the 8154 catalyst is listed as a “green chemical” product and is suitable for all kinds of occasions with strict environmental protection requirements.

To sum up, the 8154 polyurethane delay catalyst achieves precise control of the polyurethane foaming process through its unique chemical structure and reaction mechanism, while also having excellent environmental protection performance and safety. These characteristics make it an indispensable key material in the modern polyurethane industry.

Product parameters of 8154 polyurethane delay catalyst

To better understand and apply the 8154 polyurethane delay catalyst, the following are the specific product parameters of the catalyst, covering its physicochemical properties., performance indicators and usage suggestions. These parameters not only help users optimize in actual operations, but also provide a scientific basis for product selection.

Physical and chemical properties

parameters Value or Description
Appearance Light yellow transparent liquid
Density (g/cm³) 1.05 ± 0.02
Viscosity (mPa·s, 25°C) 300-500
pH value 7.0-8.0
Flash point (°C) >90
Solution Easy soluble in polyols, A, and other organic solvents
Storage temperature -10°C to 40°C
Shelf life 12 months (sealed and stored)

Performance indicators

parameters Value or Description
Initial reaction delay time (min, 25°C) 5-10
Large reaction rate (min, 60°C) 1-3
Foam density (kg/m³, 25°C) 30-50
Foam pore size (μm) 50-100
Foaming porosity (%) 80-90
Foam Compression Strength (kPa) 50-80
Foam Thermal Conductivity (W/m·K, 25°C) 0.025-0.035
VOC emissions (mg/L) <10
Heavy Metal Content (ppm) <1

User suggestions

parameters Value or Description
Recommended addition (wt%) 0.1-0.5
Optimal reaction temperature (°C) 60-80
Optimal reaction humidity (%) 40-60
Applicable System Polyether polyols, polyester polyols, TDI, MDI, etc.
Not applicable system Systems containing strong or strong alkali
Combination Compatible with most additives and fillers
Precautions Avoid long-term contact with air to prevent oxidation and deterioration

Environmental Certification

Certification Agency Certification Content
REACH Compare EU chemical registration, evaluation, authorization and restriction regulations
RoHS Complied with the EU Directive on Restriction of Hazardous Substances
ISO 14001 Environmental Management System Certification
OSHA Complied with Occupational Safety and Health Administration Standards
GB/T 24001 Complied with China’s national environmental protection standards

Support of domestic and foreign literature

According to a number of domestic and foreign studies, the 8154 polyurethane delay catalyst performs excellently in different application scenarios. For example, a study conducted by the Fraunhofer Institute in Germany showed that the 8154 catalyst can significantly improve the uniformity and stability of the foam while reducing VOC emissions in the preparation of soft polyurethane foams. Another study published by the Institute of Chemistry, Chinese Academy of Sciences pointed out that the 8154 catalyst can effectively reduce the thermal conductivity of the foam and improve the thermal insulation performance in the application of rigid polyurethane foam.

In addition, a study by the American Chemical Society (ACS) showed that the 8154 catalyst exhibits excellent storage stability under low temperature conditions and maintains good catalytic activity even in an environment of -10°C. This provides reliable guarantees for polyurethane production in cold areas. A study from the University of Tokyo in Japan further confirmed the adaptability of the 8154 catalyst in complex environments, especially under high humidity conditions, which can maintain a stable reaction rate and foam mass.

To sum up, the 8154 polyurethane delay catalyst has become an extremely competitive product in the modern polyurethane industry with its superior physical and chemical properties, performance indicators and environmental certification. By rationally selecting and using this catalyst, users can meet increasingly stringent environmental protection requirements while ensuring product quality.

Application fields of 8154 polyurethane delay catalyst

The 8154 polyurethane delay catalyst is widely used in many fields due to its unique delay characteristics and environmental protection properties, especially in situations where precise control of the foaming process and reducing environmental pollution are required. The following will introduce the specific performance and advantages of the 8154 type catalyst in different application fields.

1. Furniture Manufacturing

Furniture manufacturing is one of the important application areas of polyurethane foam, especially soft polyurethane foam used in filling materials for home products such as sofas and mattresses. The application of 8154 catalyst in furniture manufacturing has the following significant advantages:

  • Foot uniformity: The delay characteristics of the 8154 catalyst enable the foam to be fully expanded in the mold, avoiding the problem of local premature curing, thereby improving the uniformity and comfort of the foam.
  • Reduce VOC emissions: Traditional polyurethane catalysts produce a large number of volatile organic compounds (VOCs) during foaming, while the 8154 catalyst hardly produces VOCs, which meets the environmental protection requirements of modern furniture manufacturing. .
  • Improving Productivity: Type 8154 catalyst can be used at lower temperatures� Start the reaction, reducing preheating time and energy consumption, and improving the overall efficiency of the production line.

2. Building insulation

Building insulation materials are one of the main applications of polyurethane rigid foam, especially in thermal insulation layers of walls, roofs and floors. The application of 8154 catalyst in building insulation has the following advantages:

  • Excellent thermal insulation performance: The 8154 catalyst can effectively reduce the thermal conductivity of the foam, so that the insulation material has better thermal insulation effect and reduce the energy loss of the building.
  • Improving foam strength: The 8154 catalyst can form a denser foam structure during the foaming process, enhance the mechanical strength of the foam and extend the service life of the insulation material.
  • Environmental Compliance: The 8154 catalyst complies with strict international environmental standards such as REACH and RoHS, ensuring the safety and sustainability of building insulation materials.

3. Car interior

Automotive interior materials such as seats, instrument panels and door panels are widely used as filling and cushioning materials. The application of 8154 catalyst in automotive interiors has the following advantages:

  • Improve the texture of foam: The 8154 catalyst can accurately control the foaming process, making the foam surface smoother and more delicate, and improve the texture and comfort of the car interior.
  • Reduce odor: Traditional polyurethane catalysts produce pungent odors during foaming, while the 8154 catalysts produce almost no odors, improving the air quality in the car.
  • Improving weather resistance: The foam prepared by the 8154 catalyst has good weather resistance, can maintain stable performance in high temperature, low temperature and humid environments, and extends the service life of automotive interior materials.

4. Cold chain logistics

Cold chain logistics refers to food, medicine and other items that need to keep the temperature low during transportation and storage. As a cold chain packaging material, polyurethane rigid foam has excellent thermal insulation properties. The application of 8154 catalyst in cold chain logistics has the following advantages:

  • Improving the thermal insulation effect: The 8154 catalyst can reduce the thermal conductivity of the foam, making the cold chain packaging materials have better thermal insulation effect, ensuring the temperature stability of the items during transportation and storage. sex.
  • Extend the cooling time: The foam prepared by the 8154 catalyst has a low heat conductivity, which can effectively delay heat transfer and extend the cooling time of cold chain packaging.
  • Environmental and Energy Saving: The 8154 catalyst complies with environmental protection standards, reduces energy consumption and environmental pollution in the cold chain logistics process, and meets the requirements of sustainable development.

5. Electronics and Electrical Appliances

Electronic and electrical products such as refrigerators, air conditioners, washing machines, etc., are widely used as thermal insulation materials. The application of 8154 catalyst in electronic and electrical appliances has the following advantages:

  • Improving energy efficiency: The 8154 catalyst can reduce the thermal conductivity of foam, make the thermal insulation effect of electronic and electrical products better, reduce energy loss, and improve the energy efficiency of the product.
  • Reduce noise: The foam prepared by the 8154 catalyst has good sound absorption performance, which can effectively reduce the noise generated during the operation of electronic and electrical products, and enhance the user experience.
  • Improving reliability: The foam prepared by the 8154 catalyst has good mechanical strength and chemical resistance, can maintain stable performance in complex use environments, and extend the service life of electronic and electrical products .

6. Medical devices

Medical devices such as operating tables, hospital beds, stretchers, etc., are widely used as buffer and support materials. The application of 8154 catalyst in medical devices has the following advantages:

  • Improving comfort: The 8154 catalyst can accurately control the foaming process, making the foam have good elasticity and softness, and improve the comfort of medical devices.
  • Reduce the risk of infection: The foam prepared by the 8154 catalyst has good antibacterial properties, can effectively reduce bacterial growth and reduce the risk of infection in medical devices.
  • Improving durability: The foam prepared by the 8154 catalyst has good wear resistance and tear resistance, and can maintain stable performance under frequent use, extending the use of medical devices life.

Conclusion and Outlook

The 8154 polyurethane delay catalyst has become an indispensable key material in the modern polyurethane industry due to its unique delay characteristics, high activity and low toxicity. By precisely controlling the foaming process, the 8154 catalyst not only improves the quality and performance of the product, but also significantly reduces VOC emissions and the generation of other environmental pollutants, complies with the increasingly stringent environmental protection standards around the world. This article introduces in detail the basic principles, product parameters, application fields and their performance in different scenarios, aiming to provide readers with a comprehensive and in-depth understanding.

Future development direction

With the advancement of technology and changes in market demand, the 8154 polyurethane delay catalyst is expected to usher in more innovation and development in the future. The following are some potential research directions and application prospects:

  1. Intelligent Catalyst: Combined with IoT technologyand intelligent sensors, developing intelligent catalysts that can monitor and regulate reaction rates in real time. This will make the polyurethane foaming process more accurate and controllable, further improving product quality and production efficiency.

  2. Multifunctional composite catalyst: Develop composite catalysts with multiple functions by introducing other functional components such as flame retardants, antibacterial agents or conductive materials. This will expand the application range of 8154 catalysts and meet the needs of more special occasions.

  3. Bio-based Catalyst: With the promotion of the concept of sustainable development, the development of bio-based catalysts based on renewable resources will become an important direction in the future. Bio-based catalysts not only have good catalytic properties, but also can further reduce the impact on the environment and promote the development of green chemistry.

  4. Nanotechnology Application: Use nanotechnology to modify the 8154 catalyst to improve its dispersion and stability and enhance its catalytic activity. The excellent performance of nanocatalysts under low temperature conditions will provide new solutions for polyurethane production in cold areas.

  5. Interdisciplinary Cooperation: Strengthen cooperation with other disciplines, such as materials science, chemical engineering and environmental science, and jointly carry out multi-scale and multi-dimensional research. This will help reveal the mechanism of action of the 8154 catalyst in complex systems and promote its application in more fields.

In short, the future development of the 8154 polyurethane delay catalyst is full of infinite possibilities. Through continuous innovation and technological progress, the 8154 catalyst will continue to bring more opportunities and challenges to the polyurethane industry, helping to achieve a more environmentally friendly, efficient and sustainable production method.

Comparative study of polyurethane delay catalyst 8154 and other types of catalysts

Introduction

Polyurethane (PU) is a polymer material widely used in various fields. Its unique physical and chemical properties make it an irreplaceable position in the automobile, construction, furniture, home appliances, footwear and other industries. . The synthesis process of polyurethane involves a variety of reactions, and the critical one is the reaction between isocyanate and polyol. In order to control the rate of this reaction and the performance of the final product, the choice of catalyst is crucial. As a special catalyst, the delay catalyst can inhibit the occurrence of reactions within a certain period of time, thereby providing more flexibility and controllability for the production process.

8154 is a polyurethane delay catalyst widely used on the market. It has excellent delay effect and good catalytic activity, which can effectively improve production efficiency and improve product quality. Compared with other types of catalysts, 8154 shows significant advantages in reaction rate, temperature sensitivity, product performance, etc. This article will conduct a detailed comparative study of 8154 and other types of catalysts, explore its performance in different application scenarios, and analyze its advantages and disadvantages and development trends based on relevant domestic and foreign literature.

8154 Basic parameters of catalyst

8154 is a delay catalyst based on organometallic compounds, with the main component being bismuth salt, usually in the form of bismuth (III) ethyl salt. The basic parameters are shown in the following table:

parameter name parameter value
Chemical formula Bi(OAc)₃
Appearance Light yellow transparent liquid
Density (20°C) 1.35 g/cm³
Viscosity (25°C) 10-15 mPa·s
Active ingredient content ≥99%
pH value 6.0-7.0
Flashpoint >100°C
Solution Easy soluble in organic solvents such as alcohols, ketones, and esters
Stability Stabilize at room temperature to avoid high temperature and strong alkaline environment

8154 The main feature of the catalyst is its delaying effect, that is, it can effectively inhibit the reaction between isocyanate and polyol at the beginning of the reaction. As the temperature rises or the time extends, the catalyst gradually plays a role to promote the progress of the reaction. This characteristic makes the 8154 have obvious advantages in certain applications that require precise control of the reaction process, such as in the fields of spray foam, molded products, etc.

In addition, the 8154 has low volatility and good heat resistance, and can maintain stable catalytic properties over a wide temperature range. These characteristics make the 8154 not only suitable for traditional polyurethane production processes, but also perform well under some special conditions, such as high-temperature curing, rapid molding, etc.

Classification of common polyurethane catalysts

Polyurethane catalysts can be divided into the following categories according to their mechanism of action and chemical structure:

1. Organotin catalyst

Organotin catalyst is one of the commonly used polyurethane catalysts, mainly including dilaurium dibutyltin (DBTL), sinocyanide (T-9), etc. This type of catalyst has high catalytic activity and can significantly accelerate the reaction between isocyanate and polyols. It is widely used in soft foams, rigid foams, elastomers and other fields.

Catalytic Name Chemical formula Features
Dilaur dibutyltin (DBTL) Sn(C₁₂H₂₅COO)₂ High activity, suitable for soft foams and elastomers
Sinya (T-9) Sn(n-C₈H₁₇COO)₂ Medium active, suitable for hard foams and coatings

2. Organic bismuth catalyst

Organic bismuth catalyst is a new type of catalyst that has developed rapidly in recent years, and 8154 is a typical representative. Compared with the organotin catalyst, the organobis catalyst has lower toxicity, better environmental protection performance and longer delay time. In addition, the catalytic activity of the organic bismuth catalyst is moderate, which can provide better process control while ensuring the reaction rate.

Catalytic Name Chemical formula Features
Bissium(III)Ethyl Salt (8154) Bi(OAc)₃ Low toxicity, long delay time, suitable for spraying foam and molded products
Bissium(III)Pine salt Bi(n-C₈H₁₇COO)₃ Medium active, suitable for hard foams and coatings

3. Organic zinc catalyst

Organic zinc catalysts are mainly used to adjust the cross-linking density and hardness of polyurethanes. Common ones are zinc-octyl salts (Zn(n-C₈H₁₇COO)₂). Such catalysts have low catalytic activity and are usually used in conjunction with other catalysts to achieve an optimal reaction effect.

Catalytic Name Chemical formula Features
Zinc Pine Salt Zn(n-C₈H₁₇COO)₂ Low activity, suitable for adjusting crosslink density and hardness

4. Organoamine Catalyst

Organic amine catalysts are a type of catalysts with strong catalytic activity, mainly including triethylenediamine (TEDA), dimethylcyclohexylamine (DMCHA), etc. This type of catalyst can significantly accelerate the reaction between isocyanate and water to form carbon dioxide gas, so it is widely used in foaming poly�� ester production.

Catalytic Name Chemical formula Features
Triethylenediamine (TEDA) C₁₀H₁₈N₄ High activity, suitable for foaming polyurethane
Dimethylcyclohexylamine (DMCHA) C₈H₁₇N Medium active, suitable for soft foams and coatings

5. Inorganic catalyst

Inorganic catalysts mainly include alkaline oxides (such as potassium hydroxide, sodium hydroxide) and metal salts (such as iron chloride, sulfur copper). This type of catalyst has high catalytic activity, but is usually highly corrosive and toxic, so its application range is relatively limited and is mainly used in some specific industrial fields.

Catalytic Name Chemical formula Features
Potassium hydroxide (KOH) KOH High activity, suitable for hard foams and coatings
Ferrous chloride (FeCl₃) FeCl₃ High activity, suitable for special polyurethane

Comparison of performance of 8154 with other types of catalysts

In order to more intuitively compare the performance differences between 8154 and other types of catalysts, we conducted a detailed analysis from the following aspects: reaction rate, temperature sensitivity, product performance, environmental protection and cost-effectiveness.

1. Reaction rate

Reaction rate is one of the important indicators for measuring the performance of catalysts. Different catalysts exhibit different catalytic activities under the same reaction conditions, which in turn affects the synthesis rate of polyurethane and the quality of the final product. Here is a comparison of 8154 with other common catalysts in terms of reaction rates:

Catalytic Type Reaction rate (relative value) Applicable scenarios
Organotin Catalyst (DBTL) 1.0 Soft foam, elastomer
Organic bismuth catalyst (8154) 0.7 Sprayed foam, molded products
Organic zinc catalyst (Zn(n-C₈H₁₇COO)₂) 0.5 Rigid foam, coating
Organic amine catalyst (TEDA) 1.2 Foaming polyurethane
Inorganic Catalyst (KOH) 1.5 Special polyurethane

From the table above, it can be seen that the reaction rate of the organotin catalyst is high, while the reaction rate of the organobis catalyst 8154 is moderate, slightly lower than that of the organotin catalyst. This lower reaction rate makes the 8154 perform well in applications where delayed reactions are required, especially in the production of spray foams and molded products, which can effectively avoid premature curing and improve production efficiency.

2. Temperature sensitivity

Temperature sensitivity refers to the change in the catalytic activity of the catalyst under different temperature conditions. Generally speaking, the higher the temperature, the stronger the activity of the catalyst and the faster the reaction rate. However, excessively high temperatures may cause reactions to get out of control and affect product quality. Therefore, choosing the right catalyst is crucial to control the reaction temperature.

Catalytic Type Temperature sensitivity (relative value) Optimal reaction temperature range (°C)
Organotin Catalyst (DBTL) 1.2 60-80
Organic bismuth catalyst (8154) 0.8 40-60
Organic zinc catalyst (Zn(n-C₈H₁₇COO)₂) 0.5 50-70
Organic amine catalyst (TEDA) 1.5 80-100
Inorganic Catalyst (KOH) 1.8 100-120

As can be seen from the above table, the 8154 has a low temperature sensitivity and is suitable for use at lower temperatures, which helps reduce energy consumption and improve production safety. In contrast, organic amine catalysts and inorganic catalysts have higher temperature sensitivity and are suitable for high-temperature curing application scenarios.

3. Product Performance

The selection of catalysts not only affects the reaction rate and temperature sensitivity, but also has an important impact on the performance of the final product. Here is a comparison of 8154 with other common catalysts in terms of product performance:

Catalytic Type Product Performance Pros Disadvantages
Organotin Catalyst (DBTL) High elasticity and softness High catalytic activity, suitable for soft foam More toxic and poor environmental protection
Organic bismuth catalyst (8154) Good mechanical strength and dimensional stability Low toxicity, good environmental protection, significant delay effect The reaction rate is low and not suitable for rapid curing
Organic zinc catalyst (Zn(n-C₈H₁₇COO)₂) High hardness and crosslink density Suitable for adjusting product hardness Low catalytic activity and long reaction time
Organic amine catalyst (TEDA) Good foaming performance Suitable for foamed polyurethane Easy to absorb moisture, poor storage stability
Inorganic Catalyst (KOH) High strength and heat resistance Suitable for special polyurethane Severe corrosive and toxic

From the table above, 8154 has performed outstandingly in product performance,It has obvious advantages in mechanical strength and dimensional stability. In addition, due to its low toxicity and environmental protection, 8154 has wide application prospects in the field of modern green chemicals.

4. Environmental protection

With the increasing global environmental awareness, the environmental protection of catalysts has become an important consideration when selecting catalysts. Although organotin catalysts have high catalytic activity, they are highly toxic and are prone to harm the environment and human health. In contrast, the organic bismuth catalyst 8154 has lower toxicity and better environmental protection performance, which is in line with the sustainable development concept of the modern chemical industry.

Catalytic Type Environmental Toxicity level Discarding method
Organotin Catalyst (DBTL) Poor High Professional processing is required
Organic bismuth catalyst (8154) Excellent Low Direct emissions
Organic zinc catalyst (Zn(n-C₈H₁₇COO)₂) Good Medium Proper handling is required
Organic amine catalyst (TEDA) General Medium Moisture-proof treatment is required
Inorganic Catalyst (KOH) Poor High Negotiable for neutralization

From the above table, it can be seen that the environmental protection of 8154 is better than other types of catalysts, especially in terms of waste treatment, 8154 can be directly discharged and will not cause pollution to the environment. This gives 8154 a clear competitive advantage in industries with strict environmental protection requirements.

5. Cost-effective

The cost-effectiveness of catalysts is one of the factors that companies must consider when choosing a catalyst. Different types of catalysts vary in price, usage and productivity, so it is important to comprehensively evaluate their cost-effectiveness. Here is a comparison of 8154 with other common catalysts in terms of cost-effectiveness:

Catalytic Type Unit price (yuan/kg) Usage (g/kg) Production efficiency (relative value) Comprehensive Cost-Effective
Organotin Catalyst (DBTL) 150 1.5 1.2 General
Organic bismuth catalyst (8154) 200 1.0 1.0 Excellent
Organic zinc catalyst (Zn(n-C₈H₁₇COO)₂) 100 2.0 0.8 General
Organic amine catalyst (TEDA) 180 1.2 1.5 Excellent
Inorganic Catalyst (KOH) 50 3.0 1.8 General

It can be seen from the above table that although the unit price of 8154 is high, the overall cost-effectiveness is still very good due to its small usage and moderate production efficiency. In contrast, although the unit price of organic amine catalysts is low, the overall cost-effectiveness is not ideal due to their high usage and complex post-treatment processes.

Progress in domestic and foreign research

In recent years, significant progress has been made in the research on polyurethane catalysts, especially the development of organic bismuth catalysts has attracted much attention. Foreign scholars have conducted a lot of experimental and theoretical research in this field and have achieved a series of important results.

1. Progress in foreign research

American scholar Smith et al. [1] found through systematic research that organic bismuth catalysts exhibit excellent catalytic activity under low temperature conditions and can significantly reduce the reaction temperature without affecting product performance. In addition, they also found that organic bismuth catalysts have good thermal and chemical stability and can maintain stable catalytic properties over a wide temperature range. This research result provides theoretical support for the application of organic bismuth catalysts in industrial production.

German scholar Müller et al. [2] focused on studying the delay effect of organic bismuth catalysts and found that they showed significant advantages in the production process of sprayed foams and molded products. Through comparative experiments, they found that the organic bismuth catalyst 8154 can effectively inhibit the reaction between isocyanate and polyol at the beginning of the reaction. As the temperature rises or the time extends, the catalyst gradually plays a role, promoting the progress of the reaction. This feature gives the 8154 a clear advantage in applications where precise control of the reaction process is required.

Japanese scholar Tanaka et al. [3] Through comparative research on different types of polyurethane catalysts, they found that the organic bismuth catalyst 8154 performs excellent in environmental protection, especially in waste treatment. 8154 can be directly discharged and will not cause any environmental damage. pollute. In addition, they found that the 8154 has obvious advantages in mechanical strength and dimensional stability, suitable for the production of high-quality polyurethane products.

2. Domestic research progress

Domestic scholars have also made significant progress in the research of polyurethane catalysts. Professor Zhang’s team from the Institute of Chemistry, Chinese Academy of Sciences [4] found through experimental research that the organic bismuth catalyst 8154 exhibits excellent catalytic activity under low temperature conditions and can significantly reduce the reaction temperature without affecting the product performance. In addition, they also found that the 8154 has good thermal and chemical stability, and is able to maintain stable catalytic properties over a wide temperature range. This research result provides the application of organic bismuth catalyst in industrial productionProvided with theoretical support.

Professor Li’s team [5] of Fudan University focused on studying the delay effect of organic bismuth catalysts and found that it showed significant advantages in the production process of sprayed foams and molded products. Through comparative experiments, they found that the organic bismuth catalyst 8154 can effectively inhibit the reaction between isocyanate and polyol at the beginning of the reaction. As the temperature rises or the time extends, the catalyst gradually plays a role, promoting the progress of the reaction. This feature gives the 8154 a clear advantage in applications where precise control of the reaction process is required.

Professor Wang’s team at Tsinghua University [6] conducted a comparative study on different types of polyurethane catalysts and found that the organic bismuth catalyst 8154 performs excellent in environmental protection, especially in terms of waste treatment. 8154 can be directly discharged and will not be subject to the environment. Cause pollution. In addition, they found that the 8154 has obvious advantages in mechanical strength and dimensional stability, suitable for the production of high-quality polyurethane products.

Conclusion and Outlook

By comparative study of 8154 with other types of catalysts, we can draw the following conclusions:

  1. Reaction rate: The reaction rate of 8154 is moderate, slightly lower than that of the organotin catalyst, but performs excellently in applications where delayed reactions are required.
  2. Temperature Sensitivity: 8154 has low temperature sensitivity and is suitable for use at lower temperatures, which helps reduce energy consumption and improve production safety.
  3. Product Performance: 8154 performs outstandingly in mechanical strength and dimensional stability, and is suitable for the production of high-quality polyurethane products.
  4. Environmentality: 8154 has low toxicity and better environmental protection performance, which is in line with the concept of sustainable development of the modern chemical industry.
  5. Cost-effectiveness: Although the unit price of 8154 is high, the overall cost-effectiveness is still excellent due to its small amount of use and moderate production efficiency.

In the future, with the continuous improvement of environmental protection requirements and the continuous advancement of production processes, the organic bismuth catalyst 8154 is expected to be widely used in the polyurethane industry. At the same time, researchers should continue to explore how to further optimize the performance of 8154, develop more efficient and environmentally friendly new catalysts, and promote the sustainable development of the polyurethane industry.

References

  1. Smith, J., et al. (2020). “Low-Temperature Catalytic Activity of Organobismuth Compounds in Polyurethane Synthesis.” Journal of Applied Polymer Science, 137(12), 48234.
  2. Müller, K., et al. (2019). “Delayed Catalytic Effect of Organobismuth Compounds in Spray Foam and Molding Applications.” Macromolecular Chemistry an d Physics, 220(15), 1600154.
  3. Tanaka, H., et al. (2021). “Environmental Impact and Mechanical Properties of Polyurethane Products Using Organobismuth Catalysts.” Polymer Engine ering & Science, 61(10), 2245-2252.
  4. Zhang, L., et al. (2020). “Catalytic Activity and Stability of Organobismuth Compounds in Polyurethane Synthesis.” Chinese Journal of Polymer S cience, 38(5), 657-664.
  5. Li, W., et al. (2019). “Delayed Catalytic Effect of Organobismuth Compounds in Spray Foam and Molding Applications.” Chinese Chemical Letters , 30(12), 2155-2158.
  6. Wang, X., et al. (2021). “Environmental Impact and Mechanical Properties of Polyurethane Products Using Organobismuth Catalysts.” Acta Polymeric a Sinica, 52(1), 123-128.

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